西安交通大学 能源与动力工程学院,陕西 西安 710049
陈佳男(1996—),博士研究生,研究方向为非平衡相变理论,E-mail:jn.chen@stu.xjtu.edu.cn。
黄柱(1988—),博士,副教授,博士研究生导师,研究方向为计算流体动力学,E-mail:zhuhuang@xjtu.edu.cn。
收稿:2025-06-26,
修回:2025-07-22,
网络出版:2025-12-01,
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陈佳男,高媛媛,黄柱.壁面粗糙度对超音速喷管内部CO2非平衡凝结的影响[J].低碳化学与化工,
CHEN Jianan,GAO Yuanyuan,HUANG Zhu.Effect of wall roughness on CO2 non-equilibrium condensation in supersonic nozzles[J].Low-Carbon Chemistry and Chemical Engineering,
陈佳男,高媛媛,黄柱.壁面粗糙度对超音速喷管内部CO2非平衡凝结的影响[J].低碳化学与化工, DOI:10.12434/j.issn.2097-2547.20250285.
CHEN Jianan,GAO Yuanyuan,HUANG Zhu.Effect of wall roughness on CO2 non-equilibrium condensation in supersonic nozzles[J].Low-Carbon Chemistry and Chemical Engineering, DOI:10.12434/j.issn.2097-2547.20250285.
超音速分离在清洁能源处理和碳捕集技术等方面具有较大的应用价值,对构建清洁能源体系具有重要作用。为了分析壁面粗糙度对CO
2
非平衡凝结和超音速分离性能的影响,通过数学模型对CO
2
在非平衡态中的传质传热现象进行了预测,并通过修正壁面函数考虑了壁面粗糙度的影响。结果表明,壁面粗糙度会阻碍喷管内部的膨胀进程,进而对CO
2
在喷管中的膨胀性能产生负面影响。此外,膨胀过程受阻会减缓粗糙喷管内部热力学系统向非平衡态移动的进程,进而推迟了凝结核心的形成,导致峰值成核率与液相质量分数均减小。其中,当喷管壁面粗糙度从0.00增大至0.20 mm时,峰值成核率从8.04 × 10
19
m
-3
/s减小至5.73 × 10
19
m
-3
/s,减小幅度为28.7%,同时成核空间减小了10.2%;液相质量分数从0.047减小至0.042,减小幅度为10.6%,同时液相空间减小了13.4%。
Supersonic separation has significant application value in clean energy processing
carbon capture technology and other fields
and plays an important role in building clean energy system. To analyse the effect of wall roughness on CO
2
non-equilibrium condensation and supersonic separation performance
a mathematical model was built to predict the mass and heat transfer phenomena of CO
2
in non-equilibrium state
and considering the wall roughness by modifying the wall function. The results show that the wall roughness hinders the expansion process in the nozzle
thereby weakening the expansion performance of CO
2
. Furthermore
the obstruction of expansion process slows down the process of thermodynamic system moving towards the non-equilibrium state
thereby delaying the formation of condensation nuclei and reducing the peak nucleation rate and liquid fraction. Among them
when the roughness increases from 0.00 to 0.20 mm
the peak nucleation rate decreases
from 8.04 × 10
19
m
-3
/s to 5.73 × 10
19
m
-3
/s
with a decrease of 28.7%
and the nucleation space decreases by 10.2% at the same time. The liquid mass fraction decreases from 0.047 to 0.042
with a reduction of 10.6%
while the liquid phase space decreases by 13.4%.
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