310S不锈钢在高温氨气下腐蚀行为的实验研究

王大彪; 田勇; 李加庆; 滕霖; 周杨; 陈崇启; 罗宇; 江莉龙

doi:10.12434/j.issn.2097-2547.20250260

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310S不锈钢在高温氨气下腐蚀行为的实验研究

绿色氨能关键技术 | 更新时间：2026-02-02

- 310S不锈钢在高温氨气下腐蚀行为的实验研究
- Experimental study on corrosion behaviors of 310S stainless steel under high-temperature ammonia gas
- 低碳化学与化工 2026, 51(1): 150-158.
- 作者机构：
  
  1.福州大学化工学院，福建福州 350001
  2.福大紫金氢能科技股份有限公司，福建福州 350108
- 作者简介：
  
  王大彪（1986—），博士，研究员，研究方向为氨氢能源系统和氨分解反应器，E-mail：wangdb19@fzu.edu.cn。
  江莉龙（1975—），博士，研究员，研究方向为工业催化，E-mail：jll@fzu.edu.cn。
- 基金信息：
  
  国家自然科学基金(22478079);国家重点研发计划(2024YFB3815300)
- DOI：10.12434/j.issn.2097-2547.20250260
  中图分类号： TG172
- 收稿：2025-06-05，
  
  修回：2025-07-16，
  
  纸质出版：2026-01-25
- 稿件说明：
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王大彪,田勇,李加庆等.310S不锈钢在高温氨气下腐蚀行为的实验研究[J].低碳化学与化工,2026,51(1):150-158.

WANG Dabiao,TIAN Yong,LI Jiaqing,et al.Experimental study on corrosion behaviors of 310S stainless steel under high-temperature ammonia gas[J].Low-Carbon Chemistry and Chemical Engineering,2026,51(1):150-158.
王大彪,田勇,李加庆等.310S不锈钢在高温氨气下腐蚀行为的实验研究[J].低碳化学与化工,2026,51(1):150-158. DOI： 10.12434/j.issn.2097-2547.20250260.

WANG Dabiao,TIAN Yong,LI Jiaqing,et al.Experimental study on corrosion behaviors of 310S stainless steel under high-temperature ammonia gas[J].Low-Carbon Chemistry and Chemical Engineering,2026,51(1):150-158. DOI： 10.12434/j.issn.2097-2547.20250260.

摘要

氨气因其无碳富氢特性，在工业与新能源领域的应用日益广泛。然而，高温工况下管路系统的氨气腐蚀问题成为制约氨产业发展的关键瓶颈。选取310S不锈钢为研究对象，通过搭建高温氨气腐蚀实验平台模拟实际工况，综合运用SEM、EDS和XRD等表征技术，研究了310S不锈钢在不同时间、不同温度氨气作用下的腐蚀行为，并对比分析了碳化钨（WC）涂层对其耐蚀性能的影响。结果表明，310S不锈钢在腐蚀初期的年腐蚀速率较高，随后逐渐降低；如310S不锈钢在450 ℃下腐蚀80 h和480 h，其年腐蚀速率分别为1.68 mm/a和0.53 mm/a。温度对310S不锈钢的腐蚀行为有显著影响，其中温度为450 ℃时腐蚀最为剧烈，如腐蚀时间为80 h时，450 ℃下310S不锈钢的年腐蚀速率为1.68 mm/a，明显高于其在300 ℃（0.79 mm/a）和490 ℃（1.09 mm/a）下的年腐蚀速率。当温度为450 ℃时，WC涂层能够有效抑制活性N渗入310S不锈钢基体，但在490 ℃下WC涂层会发生局部剥落，反而加剧了基体腐蚀。

Abstract

Due to the carbon-free and hydrogen-rich characteristics

ammonia gas is increasingly widely used in industrial and new energy fields. However

the ammonia gas corrosion problem in pipeline systems under high-temperature working conditions has become a key bottleneck restricting the development of the ammonia industry. 310S stainless steel was selected as the research object and a high-temperature ammonia corrosion experimental platform was built to simulate the actual conditions

and characterization techniques such as SEM

EDS and XRD were comprehensively applied to study the corrosion behaviors of 310S stainless steel under ammonia gas at different time and temperatures. The influence of tungsten carbide (WC) coating on corrosion resistance of 310S stainless steel was compared and analyzed. The results show that the annual corrosion rate of 310S stainless steel is relatively high in the early stage of corrosion and then gradually decreases. For example

when 310S stainless steel is corroded at 450 ℃ for 80 h and 480 h

its annual corrosion rates are 1.68 mm/a and 0.53 mm/a

respectively. The temperature has significant impact on the corrosion behaviors of 310S stainless steel. Among them

the corrosion is most intense at 450 ℃. For instance

when the corrosion time is 80 h

the annual corrosion rate of 310S stainless steel at 450 ℃ is 1.68 mm/a. It is significantly higher than its annual corrosion rate at 300 ℃ (0.79 mm/a) and 490 ℃ (1.09 mm/a). When the temperature is 450 ℃

the WC coating can effectively inhibit the penetration of active N into substrate of 310S stainless steel. However

at 490 ℃

the WC coating can experience local peeling

which can aggravate the corrosion of the substrate.

关键词

Keywords

references

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