磷酸铜催化甘油制丙烯醛性能研究

张媛媛; 李双明; 陈峰; 王一雯; 于三三

doi:10.12434/j.issn.2097-2547.20250188

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磷酸铜催化甘油制丙烯醛性能研究

低碳分子转化合成 | 更新时间：2026-03-19

- 磷酸铜催化甘油制丙烯醛性能研究
- Study on performances of glycerol to acrolein catalyzed by copper phosphates
- 低碳化学与化工 2026, 51(3): 60-67.
- 作者机构：
  
  沈阳化工大学化学工程学院，辽宁沈阳 110142
- 作者简介：
  
  张媛媛（2002—），硕士研究生，研究方向为低碳分子催化合成，E-mail：3050691655@qq.com。
  李双明（1982—），博士，教授，研究方向为金属氧化物催化剂构效关系，E-mail：lishuangming@syuct.edu.cn；
  于三三（1971—），博士，教授，研究方向为催化材料，E-mail：ssyu@syuct.edu.cn。
- 基金信息：
  
  辽宁省应用基础研究计划(2023JH2/101300243);辽宁省教育厅基本科研项目(JYTMS20231497);沈阳市中青年科技创新人才支持计划(RC210184)
- DOI：10.12434/j.issn.2097-2547.20250188
  中图分类号： TQ23
- 收稿：2025-04-18，
  
  修回：2025-06-04，
  
  纸质出版：2026-03-25
- 稿件说明：
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张媛媛,李双明,陈峰等.磷酸铜催化甘油制丙烯醛性能研究[J].低碳化学与化工,2026,51(3):60-67.

ZHANG Yuanyuan,LI Shuangming,CHEN Feng,et al.Study on performances of glycerol to acrolein catalyzed by copper phosphates[J].Low-Carbon Chemistry and Chemical Engineering,2026,51(3):60-67.
张媛媛,李双明,陈峰等.磷酸铜催化甘油制丙烯醛性能研究[J].低碳化学与化工,2026,51(3):60-67. DOI： 10.12434/j.issn.2097-2547.20250188.

ZHANG Yuanyuan,LI Shuangming,CHEN Feng,et al.Study on performances of glycerol to acrolein catalyzed by copper phosphates[J].Low-Carbon Chemistry and Chemical Engineering,2026,51(3):60-67. DOI： 10.12434/j.issn.2097-2547.20250188.

摘要

甘油转化为高附加值的丙烯醛是推动化工行业绿色低碳发展的有效途径之一。催化剂是影响甘油制丙烯醛路线产能的关键。采用旋转蒸发法制备了一系列磷酸铜催化剂，并通过XRD、SEM等对催化剂进行了表征。研究了不同

(Cu)/

(P)及Cu源对催化剂构效关系的影响。结果表明，增大

(Cu)/

(P)可增大催化剂的比表面积，进而提高催化剂的催化性能；不同Cu源可影响催化剂的表面形貌，进而影响其丙烯醛选择性。在反应温度为300 ℃、甘油溶液（质量分数为10%）进料流速为4 mL/h的条件下，

(Cu)/

(P) = 1.0、硝酸铜为Cu源制备的催化剂表现出相对最优的催化性能，其甘油转化率、丙烯醛选择性和丙烯醛产率分别为97%、80%和78%。

Abstract

Converting glycerol into high-value-added acrolein is one of the effective ways to promote green and low-carbon development of chemical industry. The catalyst is the key factor influencing the production capacity of the glycerol to acrolein route. A series of copper phosphate catalysts were prepared by rotary evaporation method

and the catalysts were

characterized by XRD

SEM and so on. Effects of different

(Cu)/

(P) and Cu sources on structure-activity relationships of catalysts were studied. The results show that increasing

(Cu)/

(P) can increase the specific surface area of catalyst

thereby improving the catalytic performance of the catalyst. Different Cu sources can affect the surface morphology of the catalyst

and thereby influence its acrolein selectivity. Under the conditions of reaction temperature of 300 ℃ and glycerol solution (mass fraction of 10%) feed flow rate of 4 mL/h

the catalyst prepared with

(Cu)/

(P) of 1.0 and copper nitrate as the Cu source exhibits relatively optimal catalytic performance

with glycerol conversion rate

acrolein selectivity and acrolein yield of 97%

80% and 78%

respectively.

关键词

Keywords

references

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