静电纺Pd掺杂TiO<sub>2</sub>-ZrO<sub>2</sub>纳米纤维膜及其催化液化石油气红外燃烧性能研究

赵杞英; 陆建伟; 蒋群辉; 马海乐

doi:10.12434/j.issn.2097-2547.20250178

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静电纺Pd掺杂TiO₂-ZrO₂纳米纤维膜及其催化液化石油气红外燃烧性能研究

绿色低碳化工技术 | 更新时间：2026-03-19

- 静电纺Pd掺杂TiO₂-ZrO₂纳米纤维膜及其催化液化石油气红外燃烧性能研究
- Study on electrospinning Pd-doping TiO₂-ZrO₂ nanofiber membranes and their catalytic performances in infrared combustion of liquefied petroleum gas
- 低碳化学与化工 2026, 51(3): 115-123.
- 作者机构：
  
  1.江苏大学食品与生物工程学院，江苏镇江 212013
  2.江苏大学农业工程学部，江苏镇江 212013
  3.江苏大学材料科学与工程学院，江苏镇江 212013
  4.镇江美博红外科技有限公司，江苏镇江 212013
- 作者简介：
  
  赵杞英（1998—），硕士研究生，研究方向为贵金属催化剂，E-mail：2392780917@qq.com。
  马海乐（1963—），博士，教授，研究方向为食品物理加工及生物质资源利用，E-mail：mhl@ujs.edu.cn。
- 基金信息：
  
  省部共建现代农业装备与技术协同创新中心项目(XTCX1008)
- DOI：10.12434/j.issn.2097-2547.20250178
  中图分类号： TE65;O643
- 收稿：2025-04-12，
  
  修回：2025-06-24，
  
  纸质出版：2026-03-25
- 稿件说明：
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赵杞英,陆建伟,蒋群辉等.静电纺Pd掺杂TiO₂-ZrO₂纳米纤维膜及其催化液化石油气红外燃烧性能研究[J].低碳化学与化工,2026,51(3):115-123.

ZHAO Qiying,LU Jianwei,JIANG Qunhui,et al.Study on electrospinning Pd-doping TiO₂-ZrO₂ nanofiber membranes and their catalytic performances in infrared combustion of liquefied petroleum gas[J].Low-Carbon Chemistry and Chemical Engineering,2026,51(3):115-123.
赵杞英,陆建伟,蒋群辉等.静电纺Pd掺杂TiO₂-ZrO₂纳米纤维膜及其催化液化石油气红外燃烧性能研究[J].低碳化学与化工,2026,51(3):115-123. DOI： 10.12434/j.issn.2097-2547.20250178.

ZHAO Qiying,LU Jianwei,JIANG Qunhui,et al.Study on electrospinning Pd-doping TiO₂-ZrO₂ nanofiber membranes and their catalytic performances in infrared combustion of liquefied petroleum gas[J].Low-Carbon Chemistry and Chemical Engineering,2026,51(3):115-123. DOI： 10.12434/j.issn.2097-2547.20250178.

摘要

液化石油气直接燃烧过程中存在的燃烧不完全现象会造成能源浪费和污染环境，工业领域通常采用催化红外燃烧技术改善液化石油气的燃烧过程。采用静电纺丝法一体化制备了不同Pd掺杂量（

(Pd)/

(总金属元素)）的TiO

-ZrO

纳米纤维膜。使用SEM、XPS等研究了Pd掺杂量对TiO

-ZrO

纳米纤维膜结构的影响，并研究了Pd掺杂量、煅烧温度等因素对TiO

-ZrO

纳米纤维膜催化液化石油气红外燃烧性能的影响。结果表明，Pd掺杂量对TiO

-ZrO

纳米纤维膜的TiO

晶型及织构性质均有明显影响。Pd掺杂量过大（11%）时，TiO

-ZrO

纳米纤维膜的锐钛矿TiO

会转变为金红石TiO

，比表面积及平均孔径减小。在液化石油气流速为27 mL/min、空气流速为0.8 L/min 的条件下，Pd掺杂量为8%、煅烧温度为600 ℃的TiO

-ZrO

纳米纤维膜表现出相对最好的催化性能，其液化石油气转化率最高为99%，燃烧红外温度最高为577 ℃。此外，该纳米纤维膜还具有良好的稳定性和重复使用性。

Abstract

The incomplete combustion phenomenon during direct combustion of liquefied petroleum gas can cause energy waste and pollution of environment

catalytic infrared combustion technology is usually used in the industrial field to improve the combustion process of liquefied petroleum gas. TiO

-ZrO

nanofiber membranes with different Pd doping amounts (

(Pd)/

(total metal elements)) were prepared by electrospinning method. The effects of Pd doping amounts on the structures of TiO

-ZrO

nanofiber membranes were studied by SEM and XPS

and the effects of Pd doping amounts and calcination temperatures on the catalytic infrared combustion performances of liquefied petroleum gas of TiO

-ZrO

nanofiber membranes were studied. The results show that Pd doping amount has significant effect on the TiO

crystal forms and texture properties of TiO

-ZrO

nanofiber membranes. When the Pd doping amount is too large (11%)

the anatase TiO

of the TiO

-ZrO

nanofiber membrane can be converted to rutile TiO

and the specific surface area and average pore size can decrease. Under the conditions of liquefied petroleum gas flow rate of 27 mL/min and air flow rate of 0.8 L/min

the TiO

-ZrO

nanofiber membrane with Pd doping amount of 8% and calcination temperature of 600 ℃ shows relatively best catalytic performance with the highest liquefied petroleum gas conversion rate of 99% and the highest combustion infrared temperature of 577 ℃. In addition

the nanofiber membrane has good stability and reusability.

关键词

Keywords

references

CHEN J N , ABOU-ELWAFA S F , HUANG M . Dynamic changes in the fossil energy use efficiency in crop production: A case study from Hunan province of China [J ] . Journal of Cleaner Production , 2022 , 371 : 133627 .

MA W J , HAN W , LIU Q B , et al . Hydrogen production system with near-zero carbon dioxide emissions enabled by complementary utilization of natural gas and electricity [J ] . Journal of Cleaner Production , 2024 , 447 : 141395 .

MAGAJI S , HUSSAIN I , MALAIBARI Z , et al . Catalytic cracking of liquefied petroleum gas (LPG) to light olefins using zeolite-based materials: Recent advances, trends, challenges and future perspectives [J ] . The Chemical Record , 2024 , 24 ( 11 ): e202400110 .

TLADI B C , TSHABALALA Z P , KROON R E , et al . Influence of reduced graphene oxide layer on sensing characteristics of Co 3 O 4 /rGO nanocomposite towards liquefied petroleum gas (LPG) [J ] . Journal of Alloys and Compounds , 2024 , 1007 : 176464 .

GHOLAMI F , TOMAS M , GHOLAMI Z , et al . Technologies for the nitrogen oxides reduction from flue gas: A review [J ] . Science of the Total Environment , 2020 , 714 : 136712 .

QIN M Y , CHEW B T , YAU Y H , et al . Emergency heater based on gas-fired catalytic combustion infrared technology: Structure, evaluation and thermal response [J ] . Energy , 2023 , 274 : 12742 .

WU B G , MA Y J , GUO Y T , et al . Research progress in the application of catalytic infrared technology in fruit and vegetable processing [J ] . Comprehensive Reviews in Food Science and Food Safety , 2024 , 23 ( 1 ): 1 - 22 .

PARK Y K , KIM B S . Catalytic removal of nitrogen oxides (NO, NO 2 , N 2 O) from ammonia-fueled combustion exhaust: A review of applicable technologies [J ] . Chemical Engineering Journal , 2023 , 461 : 141958 .

STOIAN M , MAURER T , LAMRI S , et al . Techniques of preparation of thin films: Catalytic combustion [J ] . Catalysts , 2021 , 11 ( 12 ): 1530 .

TAO J X , LIN H X , DENG J G , et al . Enhanced low-temperature catalytic activity and stability in methane combustion of Pd-CeO 2 nanowires@ SiO 2 by Pt dispersion [J ] . Applied Catalysis B: Environment and Energy , 2025 , 360 : 124554 .

WANG X Q , HE Y W , ZHAO B H , et al . Bimetallic Ni and Pt single atoms anchored on nitrogen-phosphorus doped porous carbon fibers to achieve significant electrocatalytic hydrogen evolution [J ] . Separation and Purification Technology , 2024 , 349 : 127909 .

ZHANG M Y , YE J , LU N N , et al . Doping Pd 2+ into Ni n CeO x nanofibers promotes low-temperature CO 2 methanation [J ] . Journal of Catalysis , 2024 , 434 : 115535 .

QIANG S Y , ZENG S J , LIU H L , et al . Boosting electrochemical ammonia synthesis via dynamic nitrogen carriers coupled with electron-rich Lewis acidic sites on TiO 2- x nanofiber [J ] . Journal of Colloid and Interface Science , 2025 , 679 : 201 - 208 .

CHEN W , ZHENG J , FANG Y R , et al . Role of the in-situ-formed surface (Pt-S-O)-Ti active structure in SO 2 -promoted C 3 H 8 combustion over a Pt/TiO 2 catalyst [J ] . Environmental Science & Technology , 2024 , 58 ( 6 ): 3041 - 3053 .

FU W , LI Z , XU W , et al . Exceptionally thermal-stable Al 2 O 3 /TiO 2 nanofibers by depressing surface-initiated grain growth as new supports for anti-sintering Pt nanoparticles [J ] . Materials Today Nano , 2020 , 11 : 100088 .

LI J H , LIN J , CHEN X H , et al . Silicon-induced optimization on phase structure and surface property of Pd/ZrO 2 catalysts for enhanced methane combustion [J ] . Applied Surface Science , 2024 , 643 : 158657 .

ZHANG J N , LIU J , LIU Y M , et al . Design engineering of MOF-derived ZnO porous nanofibers functionalized with Pt clusters: Significantly improved acetone sensing properties [J ] . Sensors and Actuators B: Chemical , 2024 , 400 : 134941 .

LIAO X L , REN H T , SHEN B L , et al . Enhancing mechanical and photocatalytic properties by surface microstructure regulation of TiO 2 nanofiber membranes [J ] . Chemosphere , 2023 , 313 : 137195 .

AMNA T , HASSAN M S , KHIL M S , et al . Interaction of magnetic cobalt based titanium dioxide nanofibers with muscle cells: In vitro cytotoxicity evaluation [J ] . Journal of Sol-Gel Science and Technology , 2014 , 69 : 338 - 344 .

SONG J , WANG X Q , YAN J H , et al . Soft Zr-doped TiO 2 nanofibrous membranes with enhanced photocatalytic activity for water purification [J ] . Scientific Reports , 2017 , 7 ( 1 ): 1636 .

GAO Z Y , ZHOU Z J , WANG M Y , et al . Highly dispersed Pd anchored on heteropolyacid modified ZrO 2 for high efficient hydrodeoxygenation of lignin-derivatives [J ] . Fuel , 2023 , 334 : 126768 .

WANG C Y , TANG Y , GENG Z K , et al . Modulating charge accumulation via electron interaction for photocatalytic hydrogen evolution: A case of fabricating palladium sites on ZnIn 2 S 4 nanosheets [J ] . ACS Catalysis , 2023 , 13 ( 17 ): 11687 - 11696 .

SCHILLER R , WEISS C K , LANDFESTER K . Phase stability and photocatalytic activity of Zr-doped anatase synthesized in miniemulsion [J ] . Nanotechnology , 2010 , 21 ( 40 ): 405603 .

CHANG S M , DOONG R A . Characterization of Zr-doped TiO 2 nanocrystals prepared by a nonhydrolytic sol-gel method at high temperatures [J ] . The Journal of Physical Chemistry B , 2006 , 110 ( 42 ): 20808 - 20814 .

程银兵 , 马建华 , 吴广明 , 等 . 热处理对溶胶-凝胶TiO 2 薄膜的晶相转变和性能影响 [J ] . 功能材料 , 2003 , ( 1 ): 73 - 75 .

CHENG Y B , MA J H , WU G M , et al . Influence of heat treatment on the properties and crystal phase transfer of TiO 2 gel film [J ] . Journal of Functional Materials , 2003 , ( 1 ): 73 - 75 .

王嘉曼 , 熊靖 , 师金鸽 , 等 . TiO 2 催化剂催化CO 2 还原的研究进展 [J ] . 石油化工高等学校学报 , 2024 , 37 ( 4 ): 1 - 11 .

WANG J M , XIONG J , SHI J G , et al . An overview of carbon dioxide catalyzed by titanium dioxide catalyst [J ] . Journal of Petrochemical Universities , 2024 , 37 ( 4 ): 1 - 11 .

FU J W , CAO S W , YU J G , et al . Enhanced photocatalytic CO 2 -reduction activity of electrospun mesoporous TiO 2 nanofibers by solvothermal treatment [J ] . Dalton Transactions , 2014 , 43 ( 24 ): 9158 - 9165 .

YOO S , JANG G H , KIM D H . Effects of dealumination on the methane-combustion activity of Pd/SSZ-13 catalysts [J ] . Applied Catalysis A: General , 2024 , 670 : 119528 .

RYOU Y S , LEE J , KIM Y , et al . Effect of reduction treatments (H 2 vs. CO) on the NO adsorption ability and the physicochemical properties of Pd/SSZ-13 passive NO x adsorber for cold start application [J ] . Applied Catalysis A: General , 2019 , 569 : 28 - 34 .

LETICHEVSKY S , ZONETTI P C , REIS P P P , et al . The role of m -ZrO 2 in the selective oxidation of ethanol to acetic acid employing PdO/ m -ZrO 2 [J ] . Journal of Molecular Catalysis A: Chemical , 2015 , 410 : 177 - 183 .

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静电纺Pd掺杂TiO2-ZrO2纳米纤维膜及其催化液化石油气红外燃烧性能研究

Study on electrospinning Pd-doping TiO2-ZrO2 nanofiber membranes and their catalytic performances in infrared combustion of liquefied petroleum gas

DOI：10.12434/j.issn.2097-2547.20250178

摘要

Abstract

关键词

Keywords

references

静电纺Pd掺杂TiO₂-ZrO₂纳米纤维膜及其催化液化石油气红外燃烧性能研究

Study on electrospinning Pd-doping TiO₂-ZrO₂ nanofiber membranes and their catalytic performances in infrared combustion of liquefied petroleum gas