氮掺杂多孔超交联聚合物的二氧化碳吸附性能研究

李继续; 李泽松; 石明娟; 徐立恒

doi:10.12434/j.issn.2097-2547.20250160

您当前的位置：

首页 >

文章列表页 >

氮掺杂多孔超交联聚合物的二氧化碳吸附性能研究

二氧化碳捕集与利用 | 更新时间：2026-03-19

- 氮掺杂多孔超交联聚合物的二氧化碳吸附性能研究
- Study on CO₂ adsorption performances of nitrogen-doped porous hypercrosslinked polymers
- 低碳化学与化工 2026, 51(3): 78-84.
- 作者机构：
  
  1.中国计量大学能源环境与安全工程学院，浙江杭州 310018
  2.宁波市计量测试研究院，浙江宁波 315048
- 作者简介：
  
  李继续（1999—），硕士研究生，研究方向为碳捕集，E-mail：2501095292@qq.com。
  徐立恒（1976—），博士，教授，研究方向为环境污染控制技术，E-mail：xlheng@cjlu.edu.cn。
- 基金信息：
  
  宁波市公益性科技计划重点项目(2022S121)
- DOI：10.12434/j.issn.2097-2547.20250160
  中图分类号： TQ424.3
- 收稿：2025-04-08，
  
  修回：2025-05-17，
  
  纸质出版：2026-03-25
- 稿件说明：
移动端阅览
李继续,李泽松,石明娟等.氮掺杂多孔超交联聚合物的二氧化碳吸附性能研究[J].低碳化学与化工,2026,51(3):78-84.

LI Jixu,LI Zesong,SHI Mingjuan,et al.Study on CO₂ adsorption performances of nitrogen-doped porous hypercrosslinked polymers[J].Low-Carbon Chemistry and Chemical Engineering,2026,51(3):78-84.
李继续,李泽松,石明娟等.氮掺杂多孔超交联聚合物的二氧化碳吸附性能研究[J].低碳化学与化工,2026,51(3):78-84. DOI： 10.12434/j.issn.2097-2547.20250160.

LI Jixu,LI Zesong,SHI Mingjuan,et al.Study on CO₂ adsorption performances of nitrogen-doped porous hypercrosslinked polymers[J].Low-Carbon Chemistry and Chemical Engineering,2026,51(3):78-84. DOI： 10.12434/j.issn.2097-2547.20250160.

摘要

随着全球变暖问题日益严重，基于固体多孔吸附材料的二氧化碳（CO

）捕集技术，作为一种重要的碳减排技术受到了广泛关注。分别以苯并咪唑（BMZ）、咔唑（CBZ）、二苯基咪唑（DMZ）和偶氮苯（ABZ）作为反应单体，制备了系列氮掺杂多孔超交联聚合物（HCPs）。采用SEM、N

吸/脱附、元素分析和FT-IR等表征手段，分析了不同结构单体对HCPs微观形貌和孔隙结构的影响，并开展了CO

静态吸附、动态吸附和循环稳定性测试，评估了HCPs的吸附性能。结果表明，HCPs具有纤维状微观结构，纤维上孔隙结构紧密排列。反应单体尺寸越小，制备的HCPs比表面积和微孔面积越大，其中HCP-ABZ的比表面积达到875.5 m

/g。HCPs具有良好的CO

吸附性能，273 K下HCP-CBZ的CO

静态吸附量达到4.30 mmol/g；CO

动态吸附过程中，HCP-BMZ的饱和吸附量达到1.13 mmol/g。5次吸/脱附循环后，HCP-BMZ的CO

吸附量基本保持不变，表现出良好的循环稳定性。本研究可为开发高效CO

吸附材料提供参考。

Abstract

With the increasingly severe problem of global warming

carbon dioxide (CO

) capture technology based on solid porous adsorption materials has received widespread attention as an important carbon emission reduction strateg

y. A series of nitrogen-doped porous hypercrosslinked polymers (HCPs) were prepared using benzimidazole (BMZ)

carbazole (CBZ)

diphenyl imidazole (DMZ) and azobenzene (ABZ) as reaction monomers. Characterization methods including SEM

adsorption/desorption

elemental analysis and FT-IR were employed to analyze the influence of different monomer structures on the microstructure and pore structure of the HCPs. Static adsorption

dynamic adsorption and cyclic stability tests were carried out to evaluate their CO

adsorption performance. The results show that the HCPs exhibit a fibrous microstructure with tightly arranged pore structures on the fibers. The smaller the size of the reaction monomer

the larger the specific surface area and micropore area of the prepared HCPs. Among them

the specific surface area of HCP-ABZ reaches 875.5 m

/g. The HCPs demonstrate excellent CO

adsorption performance. The static CO

adsorption capacity of HCP-CBZ at 273 K reaches 4.30 mmol/g

and the saturation adsorption capacity of HCP-BMZ during the dynamic CO

adsorption process reaches 1.13 mmol/g. After five adsorption/desorption cycles

the CO

adsorption capacity of HCP-BMZ remains basically unchanged

indicating excellent cyclic stability. The study provides a reference for the development of efficient CO

adsorption materials.

关键词

Keywords

references

ZHOU C , CHEN X Y . Forecasting China’s energy consumption and carbon emission based on multiple decomposition strategy [J ] . Energy Strategy Reviews , 2023 , 49 : 101160 .

ZHANG K X , GUO D F , WANG X L , et al . Sustainable CO 2 management through integrated CO 2 capture and conversion [J ] . Journal of CO 2 Utilization , 2023 , 72 : 102493 .

PEREDO-MANCILLA D , MATEI GHIMBEU C , RÉTY B , et al . Surface-modified activated carbon with a superior CH 4 /CO 2 adsorption selectivity for the biogas upgrading process [J ] . Industrial & Engineering Chemistry Research , 2022 , 61 ( 34 ): 12710 - 12727 .

HOSSEINI S T , RAISSI H , PAKDEL M . High-performance carbon dioxide capture and storage by multi-functional sphingosine kinase inhibitors through a CO 2 -philic membrane [J ] . New Journal of Chemistry , 2020 , 44 ( 19 ): 7771 - 7779 .

LEE J W , AHN H , KIM S , et al . Low-concentration CO 2 capture system with liquid-like adsorbent based on monoethanolamine for low energy consumption [J ] . Journal of Cleaner Production , 2023 , 390 : 136141 .

HASAN H F , AL-SUDANI F T , ALBAYATI T M , et al . Solid adsorbent material: A review on trends of post-combustion CO 2 capture [J ] . Process Safety and Environmental Protection , 2024 , 182 : 975 - 988 .

GKOTSIS P , PELEKA E , ZOUBOULIS A . Membrane-based technologies for post-combustion CO 2 capture from flue gases: Recent progress in commonly employed membrane materials [J ] . Membranes , 2023 , 13 ( 12 ) : 898 .

HUSSIN F , AROUA M K . Recent trends in the development of adsorption technologies for carbon dioxide capture: A brief literature and patent reviews (2014—2018) [J ] . Journal of Cleaner Production , 2020 , 253 : 119707 .

MA X C , WU Y , FANG M , et al . In-situ activated ultramicroporous carbon materials derived from waste biomass for CO 2 capture and benzene adsorption [J ] . Biomass and Bioenergy , 2022 , 158 : 106353 .

SERAFIN J , DZIEJARSKI B . Activated carbons—Preparation, characterization and their application in CO 2 capture: A review [J ] . Environmental Science and Pollution Research , 2023 , 31 ( 28 ): 40008 - 40062 .

INDIRA V , ABHITHA K . A review on recent developments in zeolite A synthesis for improved carbon dioxide capture: Implications for the water-energy nexus [J ] . Energy Nexus , 2022 , 7 : 100095 .

ZHENG Y C , CHEN Y Q , NIU J J , et al . Ultramicroporous metal-organic framework for efficient carbon dioxide capture from flue gas and natural gas [J ] . Journal of Solid State Chemistry , 2024 , 338 : 124906 .

黄星晔 , 郭佳 . 离子型多孔有机聚合物的研究进展 [J ] . 功能高分子学报 , 2023 , 36 ( 2 ): 95 - 106 .

HUANG X Y , GUO J . Research progress of ionic porous organic polymers [J ] . Journal of Functional Polymers , 2023 , 36 ( 2 ): 95 - 106 .

ALLOUSH A M , ABDULGHANI H , AMASHA H A , et al . Microwave-assisted synthesis of novel porous organic polymers for effective selective capture of CO 2 [J ] . Journal of Industrial and Engineering Chemistry , 2022 , 113 : 215 - 225 .

WANG S T , LI H T , HUANG H N , et al . Porous organic polymers as a platform for sensing applications [J ] . Chemical Society Reviews , 2022 , 51 ( 6 ): 2031 - 2080 .

MASOUMI H , GHAEMI , GILANI H G . Evaluation of hyper-cross-linked polymers performances in the removal of hazardous heavy metal ions: A review [J ] . Separation and Purification Technology , 2021 , 260 : 118221 .

LI B Y , GONG R N , WANG W , et al . A new strategy to microporous polymers: Knitting rigid aromatic building blocks by external cross-linker [J ] . Macromolecules , 2011 , 44 ( 8 ): 2410 - 2414 .

SANG Y F , HUANG J H . Benzimidazole-based hyper-cross-linked poly(ionic liquid)s for efficient CO 2 capture and conversion [J ] . Chemical Engineering Journal , 2020 , 385 : 123973 .

邱玉倩 , 刘千惠 , 韩浩杰 , 等 . 三嗪超交联聚苯乙烯基多孔聚合物的设计与制备 [J ] . 功能高分子学报 , 2020 , 33 ( 6 ): 554 - 562 .

QIU Y Q , LIU Q H , HAN H J , et al . Design and preparation of polystyrene-based polymers with triazine crosslinker [J ] . Journal of Functional Polymers , 2020 , 33 ( 6 ): 554 - 562 .

HUANG J , TURNER S R . Hypercrosslinked polymers: A review [J ] . Polymer Reviews , 2017 , 58 ( 1 ): 1 - 41 .

SHAO L S , LIU M Q , SANG Y F , et al . One-pot synthesis of melamine-based porous polyamides for CO 2 capture [J ] . Microporous and Mesoporous Materials , 2019 , 285 : 105 - 111 .

AROCKIA DOSS M , RAJARAJAN G , DHINESHKUMAR E , et al . Synthesis, spectral characterization (FT-IR, NMR, XRD) and computational studies of chloroacetyl chloride incorporated 3t-butyl-2r,6c-diphenyl/di(thiophen-2-yl)piperidin-4-ones [J ] . Journal of Molecular Structure , 2020 , 1200 : 127076 .

KRISHNAN S , SUJATHA A R , RAJU P D , et al . Hypercrosslinked polymers with hierarchical pores synthesized using biphenyl crosslinker for carbon dioxide capture [J ] . Journal of Solid State Chemistry , 2024 , 334 : 124683 .

JIA D G , MA L , WANG Y , et al . Efficient CO 2 enrichment and fixation by engineering micropores of multifunctional hypercrosslinked ionic polymers [J ] . Chemical Engineering Journal , 2020 , 390 : 124652 .

MANE S , GAO Z Y , LI Y X , et al . Fabrication of microporous polymers for selective CO 2 capture: The significant role of crosslinking and crosslinker length [J ] . Journal of Materials Chemistry A , 2017 , 10 : 1039 .

SADAK A E . A comparative gas sorption study of dicarbazole-derived microporous hyper-crosslinked polymers [J ] . Microporous and Mesoporous Materials , 2021 , 311 : 110727 .

DAS A , PEU S D , HOSSAIN M S , et al . Advancements in adsorption based carbon dioxide capture technologies—A comprehensive review [J ] . Heliyon , 2023 , 9 ( 12 ) : e22341 .

浏览量

170

下载量

CNKI被引量

文章被引用时，请邮件提醒。

提交

工具集

关联资源

改性无定形硅铝对焦化废水COD吸附性能的影响

助剂Fe对Ni/NaY吸附剂脱除氢气中二氯甲烷性能的影响

中国电力行业碳捕集、利用与封存技术应用进展

CO₂直接空气捕集用TVSA与S-TVSA循环的实验研究