CO<sub>2</sub>电还原制C<sub>2+</sub>产物选择性影响因素研究进展

赵淅灵; 廉红蕾

doi:10.12434/j.issn.2097-2547.20250149

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CO₂电还原制C₂₊产物选择性影响因素研究进展

C1化学与催化转化 | 更新时间：2026-02-13

- CO₂电还原制C₂₊产物选择性影响因素研究进展
- Research progress on factors influencing selectivity of C₂₊ products in electrochemical CO₂ reduction
- 低碳化学与化工 2026, 51(2): 1-10.
- 作者机构：
  
  1.郑州大学炼焦煤资源绿色开发全国重点实验室，河南郑州 450001
  2.郑州大学化工学院先进功能材料制造教育部工程研究中心，河南郑州 450001
- 作者简介：
  
  赵淅灵（2001—），硕士研究生，研究方向为电催化CO2还原，E-mail：17513090375@163.com。
  廉红蕾（1977—），博士，讲师，硕士研究生导师，研究方向为多相催化材料合成及原位光谱表征技术，E-mail：hongleilian@zzu.edu.cn。
- 基金信息：
  
  煤基生态精细化工河南省工程实验室开放课题(C202003)
- DOI：10.12434/j.issn.2097-2547.20250149
  中图分类号： TQ032.4
- 收稿：2025-04-01，
  
  修回：2025-05-26，
  
  纸质出版：2026-02-25
- 稿件说明：
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赵淅灵,廉红蕾.CO₂电还原制C₂₊产物选择性影响因素研究进展[J].低碳化学与化工,2026,51(2):1-10.

ZHAO Xiling,LIAN Honglei.Research progress on factors influencing selectivity of C₂₊ products in electrochemical CO₂ reduction[J].Low-Carbon Chemistry and Chemical Engineering,2026,51(2):1-10.
赵淅灵,廉红蕾.CO₂电还原制C₂₊产物选择性影响因素研究进展[J].低碳化学与化工,2026,51(2):1-10. DOI： 10.12434/j.issn.2097-2547.20250149.

ZHAO Xiling,LIAN Honglei.Research progress on factors influencing selectivity of C₂₊ products in electrochemical CO₂ reduction[J].Low-Carbon Chemistry and Chemical Engineering,2026,51(2):1-10. DOI： 10.12434/j.issn.2097-2547.20250149.

摘要

电催化CO

还原反应（CO

RR）为CO

转化为高附加值的化学品和燃料提供了有效途径。在CO

RR研究中，对催化剂组成和结构的精准调控是实现高产物选择性的关键。金属Cu是目前促进CO

RR生成C

产物的最有效活性金属组分。为深入理解Cu基催化剂上CO

RR制C

产物的影响因素，总结并分析了CO

RR制C

产物的大量研究。从Cu基催化剂表面CO

吸附机理出发，深入探讨了催化剂的Cu金属晶面、Cu低核原子团簇、Cu物种价态及形貌等因素对CO

RR反应性能的影响，重点阐述了其对C

产物选择性的影响机制，指出了CO

RR制C

产物所面临的挑战及发展方向，以期为高效CO

RR催化剂的理性设计提供思路。

Abstract

Electrocatalytic CO

reduction reaction (CO

RR) provides an effective approach for converting CO

into high value-added chemicals and fuels. In CO

RR research

precise modulation of the catalyst’s composition and structure is crucial for achieving high product selectivity. Cu is currently the most effective active metal component for driving CO

RR toward C

products. To gain a comprehensive understanding of the factors governing C

product formation on Cu-based catalysts

studies about CO

RR to C

products have been comprehensively analyzed and summarized. Starting from the adsorption mechanisms of CO

on Cu-based catalyst surfaces

the effects of critical parameters such as Cu crystal facets

low-nuclearity Cu atomic clusters

Cu species valence states

and catalyst morphologies on CO

RR performance were thoroughly explored

with emphasis on their roles in regulating C

products selectivity. Furthermore

current challenges and future research directions for C

products by CO

RR were outlined

aiming to provide guidance for the rational design of high-efficiency catalysts for CO

RR.

关键词

Keywords

references

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DOI：10.12434/j.issn.2097-2547.20250149

摘要

Abstract

关键词

Keywords

references

CO₂电还原制C₂₊产物选择性影响因素研究进展

Research progress on factors influencing selectivity of C₂₊ products in electrochemical CO₂ reduction