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疏水改性ZSM-5对双功能催化剂NaFe/ZSM-5催化CO2加氢制绿色航空煤油性能的影响
Influence of ZSM-5 after hydrophobic modification on catalytic performances of NaFe/ZSM-5 for CO2 hydrogenation to sustainable aviation fuels
- 低碳化学与化工 2026, 51(1): 16-23.
- 作者机构：
大连理工大学 化工学院，精细化工全国重点实验室，辽宁 大连 116024
- 作者简介：
薛浩强（1999—），硕士研究生，研究方向为二氧化碳加氢制液态燃料，E-mail：17741102076@163.com。
李文慧（1989—），博士，副教授，研究方向为二氧化碳加氢转化，E-mail：liwh@dlut.edu.cn；
郭新闻（1967—），博士，教授，研究方向为新能源催化转化，E-mail：guoxw@dlut.edu.cn。
- 基金信息：国家重点研发计划(2024YFB4105401);国家自然科学基金面上项目(22472017);辽宁滨海实验室联合专项开放创新基金(LBLG-2024-06);中央高校基本科研业务费(DUT24RC(3)071)
DOI：10.12434/j.issn.2097-2547.20250148
中图分类号： TQ426收稿：2025-04-01，
修回：2025-04-11，
纸质出版：2026-01-25
- 稿件说明：
移动端阅览
薛浩强,李文慧,刘炳昱等.疏水改性ZSM-5对双功能催化剂NaFe/ZSM-5催化CO2加氢制绿色航空煤油性能的影响[J].低碳化学与化工,2026,51(1):16-23.
XUE Haoqiang,LI Wenhui,LIU Bingyu,et al.Influence of ZSM-5 after hydrophobic modification on catalytic performances of NaFe/ZSM-5 for CO2 hydrogenation to sustainable aviation fuels[J].Low-Carbon Chemistry and Chemical Engineering,2026,51(1):16-23.
薛浩强,李文慧,刘炳昱等.疏水改性ZSM-5对双功能催化剂NaFe/ZSM-5催化CO2加氢制绿色航空煤油性能的影响[J].低碳化学与化工,2026,51(1):16-23. DOI： 10.12434/j.issn.2097-2547.20250148.
XUE Haoqiang,LI Wenhui,LIU Bingyu,et al.Influence of ZSM-5 after hydrophobic modification on catalytic performances of NaFe/ZSM-5 for CO2 hydrogenation to sustainable aviation fuels[J].Low-Carbon Chemistry and Chemical Engineering,2026,51(1):16-23. DOI： 10.12434/j.issn.2097-2547.20250148.
摘要
CO
2
加氢制绿色航空煤油不仅可以助力实现 “碳中和”，也有利于航空业的可持续发展。但CO
2
为惰性小分子难以活化、C—C耦合定向生成绿色航空煤油组分（C
8
~C
16
烃类）难度较高等问题，给催化剂设计带来了较大挑战。采用丙基三甲氧基硅烷（PTMS）对ZSM-5分子筛进行了疏水改性，成功制备了具有不同水接触角的疏水改性ZSM-5分子筛，并将其与Na-Fe
3
O
4
组合构筑了双功能催化剂用于CO
2
加氢反应。结果表明，丙基三甲氧基硅烷改性不仅能够提高ZSM-5分子筛的疏水性，还可以通过疏水基团对ZSM-5分子筛外表面酸性位点的覆盖作用，抑制长链烃产物在分子筛表面的裂解，提升产物中绿色航空煤油组分选择性。在320 ℃、3 MPa以及
n
(H
2
):
n
(CO
2
) = 3:1反应条件下，NaFe/Z5-0.5PTMS在CO
2
加氢反应中催化性能最佳，CO
2
转化率为32.6%，CO选择性仅为9.9%，绿色航空煤油组分选择性为38.8%。
Abstract
CO
2
hydrogenat
ion to sustainable aviation fuels can not only help achieve “carbon neutrality”
but also support the sustainable development of the aviation industry. However
due to the difficulty in activating CO
2
as an inert molecule and the difficulty in generating sustainable aviation fuels (C
8
~C
16
hydrocarbons) by C—C coupling
catalyst design has faced significant challenges. Propyl trimethoxysilane (PTMS) was used to modify ZSM-5 zeolites
and ZSM-5 zeolites with varying water contact angles were successfully prepared after hydrophobic modification. They were combined with Na-Fe
3
O
4
to construct bifunctional catalysts for CO
2
hydrogenation. The results show that propyl trimethoxysilane modification can not only enhance the hydrophobicity of ZSM-5 zeolites
but also inhibit the cracking of long-chain hydrocarbons on the surface of ZSM-5 zeolites to improve the sustainable aviation fuels selectivity by the acidic sites coverage on the outer surface of ZSM-5 zeolites with hydrophobic groups. Under the reaction conditions of 320 ℃
3 MPa and
n
(H
2
):
n
(CO
2
) = 3:1
NaFe/Z5-0.5PTMS has the best catalytic performance for CO
2
hydrogenation
with the CO
2
conversion rate of 32.6%
CO selectivity of 9.9% and sustainable aviation fuels selectivity of 38.8%.
关键词
Keywords
references
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