DDR分子筛的合成与应用研究进展

许翔; 付文华; 李昊坤; 汪玲玲

doi:10.12434/j.issn.2097-2547.20250143

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DDR分子筛的合成与应用研究进展

C1化学与催化转化 | 更新时间：2025-06-23

- DDR分子筛的合成与应用研究进展
- Research progress in synthesis and application of DDR zeolite
- 低碳化学与化工 2025, 50(6): 1-15.
- 作者机构：
  
  1.中石化（上海）石油化工研究院有限公司绿色化工与工业催化全国重点实验室，上海 201208
  2.上海第二工业大学能源与材料学院，上海 201209
  3.中国石油化工集团有限公司，北京 100728
- 作者简介：
  
  许翔（2000—），硕士研究生，研究方向为分子筛合成与催化，E-mail：2637813655@qq.com。
  付文华（1989—），博士，研究员，研究方向为工业催化，E-mail：fuwh.sshy@sinopec.com；
  汪玲玲（1982—），博士，教授，研究方向为绿色功能材料，E-mail：llwang@sspu.edu.cn。
- 基金信息：
  
  国家自然科学基金(22272201;21802168);上海市启明星计划(23QB1406300)
- DOI：10.12434/j.issn.2097-2547.20250143
  中图分类号： TQ203.2;O643.3
- 收稿日期：2025-03-28，
  
  修回日期：2025-04-21，
  
  纸质出版日期：2025-06-25
- 稿件说明：
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许翔,付文华,李昊坤等.DDR分子筛的合成与应用研究进展[J].低碳化学与化工,2025,50(6):1-15.

XU Xiang,FU Wenhua,LI Haokun,et al.Research progress in synthesis and application of DDR zeolite[J].Low-Carbon Chemistry and Chemical Engineering,2025,50(6):1-15.
许翔,付文华,李昊坤等.DDR分子筛的合成与应用研究进展[J].低碳化学与化工,2025,50(6):1-15. DOI： 10.12434/j.issn.2097-2547.20250143.

XU Xiang,FU Wenhua,LI Haokun,et al.Research progress in synthesis and application of DDR zeolite[J].Low-Carbon Chemistry and Chemical Engineering,2025,50(6):1-15. DOI： 10.12434/j.issn.2097-2547.20250143.

摘要

分子筛是一种重要的结晶多孔材料，因其化学组成可调、酸性强、比表面积大和热/水热稳定性高，在化工、能源和环保等多个领域应用广泛。小孔DDR分子筛具有独特的孔道特性，在气体分离和催化反应中展现出巨大的应用潜力。对DDR分子筛的合成及其在气体分离、催化反应中的应用进展进行了综述。介绍了DDR分子筛粉末和膜的合成方法，重点阐述了可用于提升DDR分子筛应用性能的理化性质调控策略。总结了DDR分子筛在气体吸附分离、膜分离以及以甲醇制烯烃为代表的催化反应中的应用进展，重点突出气体分离效果和催化构效关系。最后，指出了DDR分子筛研究开发现状及其面临的挑战，展望了未来研究的重点方向，以期为分子筛材料的合理设计提供思路，推动DDR分子筛实现工业应用。

Abstract

Zeolite is a significant crystalline porous material. Due to its tunable chemical compositions

strong acidity

large specific surface area

strong thermal and hydrothermal stability

it has been widely utilized in various fields

such as chemical engineering

energy and so on. Because of unique porosity characteristics

small-pore DDR zeolite has shown great potential in gas separation and catalysis processes. Research progresses in the synthesis of DDR zeolite and its applications in gas separation and catalysis have been reviewed. The methods for synthesizing DDR zeolite powder and membrane were introduced

focusing on the strategies that have been developed to regulate the physicochemical properties and thus to improve the performance. The application progress in DDR zeolite in gas adsorption separation and membrane separation and catalytic reactions

such as methanol to olefins

was summarized. Gas separation efficiency and catalysis structure-activity relationship were emphasized. Finally

the current status and challenges faced in the research and development of DDR zeolite were pointed out

and the key directions for future research were envisioned

in order to provide ideas for the rational design of zeolite and promote the industrial application of DDR zeolite.

关键词

Keywords

references

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