醇氧化反应中非均相催化剂的界面调控研究进展

孟同欣; 武世平; 赵金仙; 樊惠玲; 杨超

doi:10.12434/j.issn.2097-2547.20250123

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醇氧化反应中非均相催化剂的界面调控研究进展

低碳分子转化合成 | 更新时间：2026-03-19

- 醇氧化反应中非均相催化剂的界面调控研究进展
- Research advances in interface modulation of heterogeneous catalysts for alcohol oxidation reactions
- 低碳化学与化工 2026, 51(3): 41-52.
- 作者机构：
  
  1.太原理工大学化学与化工学院省部共建煤基能源清洁高效利用国家重点实验室，山西太原 030024
  2.太原理工大学环境与生态学院，山西太原 030024
- 作者简介：
  
  孟同欣（1999—），硕士研究生，研究方向为一碳化学与化工，E-mail：mengtongxin@yeah.net。
  赵金仙（1987—），博士，副教授，研究方向为一碳化学与化工，E-mail：zhaojinxian@tyut.edu.cn。
- 基金信息：
  
  国家自然科学基金青年基金(22208233);国家自然科学基金(22078223)
- DOI：10.12434/j.issn.2097-2547.20250123
  中图分类号： TQ032.4;TQ426
- 收稿：2025-03-19，
  
  修回：2025-05-20，
  
  纸质出版：2026-03-25
- 稿件说明：
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孟同欣,武世平,赵金仙等.醇氧化反应中非均相催化剂的界面调控研究进展[J].低碳化学与化工,2026,51(3):41-52.

MENG Tongxin,WU Shiping,ZHAO Jinxian,et al.Research advances in interface modulation of heterogeneous catalysts for alcohol oxidation reactions[J].Low-Carbon Chemistry and Chemical Engineering,2026,51(3):41-52.
孟同欣,武世平,赵金仙等.醇氧化反应中非均相催化剂的界面调控研究进展[J].低碳化学与化工,2026,51(3):41-52. DOI： 10.12434/j.issn.2097-2547.20250123.

MENG Tongxin,WU Shiping,ZHAO Jinxian,et al.Research advances in interface modulation of heterogeneous catalysts for alcohol oxidation reactions[J].Low-Carbon Chemistry and Chemical Engineering,2026,51(3):41-52. DOI： 10.12434/j.issn.2097-2547.20250123.

摘要

羰基化合物被广泛应用于制药和精细化工行业。醇类的选择性氧化是合成羰基化合物的重要途径之一，但传统热催化方法存在反应条件苛刻、目标产物选择性低和环境污染等问题。非均相催化剂在醇类高效选择性氧化中表现出独特优势，其催化性能依赖于催化剂的电子和几何结构。通过界面工程，可调控催化剂的界面活性位点，定向优化醇类的吸附与活化过程。综述了热催化醇氧化反应中非均相催化剂界面的调控机制及手段，探讨了电子效应和几何效应等非均相催化剂的界面调控机制，并对基于界面工程的调控手段进行了分析。此外，简述了人工智能辅助技术对催化剂设计的影响，并展望了未来借助界面工程设计醇氧化反应催化剂界面活性位点的发展方向。

Abstract

Carbonyl compounds are extensively utilized in pharmaceutical and fine chemical industries. The selective oxidation of alcohols serves as an important pathway for synthesizing carbonyl compounds. However

conventional thermal catalytic methods suffer from harsh reaction conditions

low target product selectivities and environmental concerns. Heterogeneous catalysts have demonstrated unique advantages in high-efficiency selective oxidation of alcohols

and their catalytic performances depend on geometric and electronic configurations of the catalyst. Interface engineering enables precise optimization of alcohol adsorption and activation processes through modulation of interfacial active sites. The regulatory mechanisms and strategies of interface engineering in thermocatalytic heterogeneous alcohol oxidation reactions were reviewed. The mechanisms of interfacial modulation of non-homogeneous catalysts by electronic and geometrical effects were discussed and the interface-based modulation methodologies were analyzed. In addition

a brief discussion of the impact of artificial intelligence-assisted approaches on catalyst design was provided and the future development direction of designing interfacial active sites in alcohol oxidation reactions via interface engineering was prospected.

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references

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