蒽基长链分子太阳能热燃料的光致储能与放热性能研究

李崇华; 徐兴堂; 荆洁颖; 冯杰; 李文英

doi:10.12434/j.issn.2097-2547.20250095

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蒽基长链分子太阳能热燃料的光致储能与放热性能研究

碳基资源清洁转化与利用 | 更新时间：2025-08-25

- 蒽基长链分子太阳能热燃料的光致储能与放热性能研究
- Study of photo-induced energy storage and heat release performances of anthracene-based long-chain molecular solar thermal fuels
- 低碳化学与化工 2025, 50(8): 79-91.
- 作者机构：
  
  太原理工大学省部共建煤基能源清洁高效利用国家重点实验室，山西太原 030024
- 作者简介：
  
  李崇华（2000—），硕士研究生，研究方向为能源化工，E-mail：lichonghua1020@link.tyut.edu.cn。
  徐兴堂（1993—），博士，副教授，研究方向为能源化工，E-mail：xuxingtang@tyut.edu.cn。
- 基金信息：
  
  国家自然科学基金青年科学基金(22308241);山西省基础研究计划（自由探索类）青年项目(202303021212037)
- DOI：10.12434/j.issn.2097-2547.20250095
  中图分类号： TB34;TQ522.6
- 收稿日期：2025-03-10，
  
  修回日期：2025-04-02，
  
  纸质出版日期：2025-08-25
- 稿件说明：
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李崇华,徐兴堂,荆洁颖等.蒽基长链分子太阳能热燃料的光致储能与放热性能研究[J].低碳化学与化工,2025,50(8):79-91.

LI Chonghua,XU Xingtang,JING Jieying,et al.Study of photo-induced energy storage and heat release performances of anthracene-based long-chain molecular solar thermal fuels[J].Low-Carbon Chemistry and Chemical Engineering,2025,50(8):79-91.
李崇华,徐兴堂,荆洁颖等.蒽基长链分子太阳能热燃料的光致储能与放热性能研究[J].低碳化学与化工,2025,50(8):79-91. DOI： 10.12434/j.issn.2097-2547.20250095.

LI Chonghua,XU Xingtang,JING Jieying,et al.Study of photo-induced energy storage and heat release performances of anthracene-based long-chain molecular solar thermal fuels[J].Low-Carbon Chemistry and Chemical Engineering,2025,50(8):79-91. DOI： 10.12434/j.issn.2097-2547.20250095.

摘要

蒽作为煤焦油中一种高附加值基础化工原料，具有广泛的应用前景。以煤焦油中蒽为原料，基于蒽的光致二聚/解聚反应，通过化学反应成功制备了两种不同烷基链长度的蒽基分子太阳能热（MOST）燃料（ANT-1、ANT-2），研究了其光致储能和放热性能，以实现其高值化和多元化利用。采用FT-IR、

H NMR和HRMS对蒽基长链MOST燃料的结构进行了表征，并利用紫外可见吸收光谱和热分析等方法研究了蒽基长链MOST燃料的光致二聚/解聚性能、储能密度以及放热性能。结果表明，与蒽及其衍生物的储能密度（20~30 kJ/mol）相比，ANT-2二聚体的储能密度可提升至89.6 kJ/mol，存储半衰期也可延长至60.96 d，并且其表现出良好的热稳定性和循环稳定性。此外，ANT-2二聚体薄膜在紫外光触发下释放的热量可使自身温度升高5.4 °C，在智能温控领域有一定应用潜力。

Abstract

Anthracene

as a high value-added basic chemical raw material in coal tar

has a wide range of application prospects. Using anthracene from coal tar as the raw material

two kinds of anthracene-based molecular solar thermal (MOST) fuels with different alkyl chain lengths (ANT-1

ANT-2) were successfully prepared by chemical reaction based on the photodimerization/depolymerization of anthracene

and its photo-induced energy storage and heat release performances w

ere studied

in order to realize its high value and diversified utilization. The structures of anthracene-based long-chain MOST fuels were characterized by FT-IR

H NMR and HRMS

and the photodimerization/depolymerization performance

energy storage density and controllable heat release performance of the anthracene-based long-chain MOST fuels were studied by UV-Vis absorption spectroscopy and thermal analysis. The results show that compared with the energy storage density of anthracene and its derivatives (20 kJ/mol to 30 kJ/mol)

the energy storage density of ANT-2 dimer can reach 89.6 kJ/mol

and the energy storage half-life can be extended to 60.96 d

and it exhibits good thermal and cyclic stability. Moreover

the heat released by ANT-2 dimer film triggered by UV light can increase its own temperature by 5.4 ℃

which has some potential for application in the field of intelligent temperature control.

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references

韩辉 , 田朋军 , 王乐 , 等 . 中低温煤焦油加工利用现状及发展趋势 [J ] . 煤炭与化工 , 2022 , 45 ( 4 ): 130 - 134 .

HAN H , TIAN P J , WANG L , et al . The present situation and development direction of medium/low temperature coal tar processing and utilization [J ] . Coal and Chemical Industry , 2022 , 45 ( 4 ): 130 - 134 .

马晓迅 , 赵阳坤 , 孙鸣 , 等 . 高温煤焦油利用技术研究进展 [J ] . 煤炭转化 , 2020 , 43 ( 4 ): 1 - 11 .

MA X X , ZHAO Y K , SUN M , et al . Technical review on utilization technology of high temperature coal tar [J ] . Coal Conversion , 2020 , 43 ( 4 ): 1 - 11 .

程俊霞 , 赵雪飞 , 朱亚明 , 等 . 我国煤系针状焦技术发展现状分析 [J ] . 洁净煤技术 , 2022 , 28 : 84 - 93 .

CHENG J X , ZHAO X F , ZHU Y M , et al . Analysis on the technology development status of coal-based needle coke in China [J ] . Clean Coal Technology , 2022 , 28 : 84 - 93 .

MATSUO Y , OKADA H , KONDO Y , et al . Anthracene-based organic small-molecule electron-injecting material for Inverted organic light-emitting diodes [J ] . ACS Applied Materials & Interfaces , 2018 , 10 ( 14 ): 11810 - 11817 .

BISWAS S , SHAULOFF N , BISHT R , et al . Anthraquinone-functionalized polydiacetylene supercapacitors [J ] . Advanced Sustainable Systems , 2023 , 7 ( 6 ): 2300035 - 2300043 .

MA Z H , WEI X Y , LIU G H , et al . Value-added utilization of high-temperature coal tar: A review [J ] . Fuel , 2021 , 292 : 119954 .

BEI P Z , RAJENDRAN A , FENG J , et al . Anthracene separation from analogous polycyclic aromatic hydrocarbons using the naphthalene-based solvents [J ] . Fuel , 2023 , 335 : 127029 .

LIU F , FAN Z X . Defect engineering of two-dimensional materials for advanced energy conversion and storage [J ] . Chemical Society Reviews , 2023 , 52 ( 5 ): 1723 - 1772 .

TAN J , WANG X , CHU W C , et al . Harvesting energy from atmospheric water: Grand challenges in continuous electricity generation [J ] . Advanced Materials , 2023 , 36 ( 12 ): 2211165 - 2211189 .

LV J Q , XIE J F , MOHAMED A G A , et al . Photoelectrochemical energy storage materials: Design principles and functional devices towards direct solar to electrochemical energy storage [J ] . Chemical Society Reviews , 2022 , 51 ( 4 ): 1511 - 1528 .

ABBOTT D . Keeping the energy debate clean: How do we supply the world’s energy needs? [J ] . Proceedings of the IEEE , 2010 , 98 ( 1 ): 42 - 66 .

ZHANG B , FENG Y Y , FENG W . Azobenzene-based solar thermal fuels: A review [J ] . Nano-Micro Letters , 2022 , 14 ( 1 ): 138 - 174 .

ANDERS L , ANNA R , KASPER M P . Designing photoswitches for molecular solar thermal energy storage [J ] . Tetrahedron Letters , 2015 , 56 ( 12 ): 1457 - 1465 .

QIU Q F , SHI Y R , HAN G G D . Solar energy conversion and storage by photoswitchable organic materials in solution, liquid, solid, and changing phases [J ] . Journal of Materials Chemistry C , 2021 , 9 ( 35 ): 11444 - 11463 .

LUTHER R , WEIGERT F . Über umkehrbare photochemische reaktionen im homogenen system: Anthracen und dianthracen [J ] . Zeitschrift für Physikalische Chemie , 1905 , 51 ( 1 ): 297 - 328 .

ZHANG Z Y , HE Y X , WANG Z H , et al . Photochemical phase transitions enable co-harvesting of photon energy and ambient heat for energetic molecular solar thermal batteries that upgrade thermal energy [J ] . Journal of the American Chemical Society , 2020 , 142 ( 28 ): 12256 - 12264 .

XU X T , FENG J , LI W Y , et al . Azobenzene-containing polymer for solar thermal energy storage and release: Advances, challenges, and opportunities [J ] . Progress in Polymer Science , 2023 , 149 : 101782 .

DONG L Q , FENG Y Y , WANG L , et al . Azobenzene-based solar thermal fuels: Design, properties, and applications [J ] . Chemical Society Reviews , 2018 , 47 ( 19 ): 7339 - 7368 .

SAYDJARI A K , WEIS P , WU S . Spanning the solar spectrum: Azopolymer solar thermal fuels for simultaneous UV and visible light storage [J ] . Advanced Energy Materials , 2016 , 7 ( 3 ): 1601622 - 1601625 .

GAO J , FENG Y Y , FANG W Y , et al . Co-harvest phase-change enthalpy and isomerization energy for high-energy heat output by controlling crystallization of alkyl-grafted azobenzene molecules [J ] . Energy & Environmental Materials , 2023 , 7 ( 3 ): e12607 .

WANG Z H , HÖLZEL H , MOTH POULSEN K . Status and challenges for molecular solar thermal energy storage system based devices [J ] . Chemical Society Reviews , 2022 , 51 ( 17 ): 7313 - 7326 .

DREOS A , WANG Z H , UDMARK J , et al . Liquid norbornadiene photoswitches for solar energy storage [J ] . Advanced Energy Materials , 2018 , 8 ( 18 ): 1703401 - 1703409 .

BÖRJESSON K , DZEBO D , ALBINSSON B , et al . Photon upconversion facilitated molecular solar energy storage [J ] . Journal of Materials Chemistry A , 2013 , 1 ( 30 ): 8521 - 8524 .

DREOS A , BÖRJESSON K , WANG Z H , et al . Exploring the potential of a hybrid device combining solar water heating and molecular solar thermal energy storage [J ] . Energy & Environmental Science , 2017 , 10 ( 3 ): 728 - 734 .

NISHIUCHI T , UNO S Y , HIRAO Y , et al . Intramolecular interaction, photoisomerization, and mechanical C—C bond dissociation of 1,2-di(9-anthryl)benzene and its photoisomer: A fundamental moiety of anthracene-based π-cluster molecules [J ] . The Journal of Organic Chemistry , 2016 , 81 ( 5 ): 2106 - 2112 .

JONES R N . The ultraviolet absorption spectra of anthracene derivatives [J ] . Chemical Reviews , 1947 , 41 ( 2 ): 353 - 371 .

HINO Y , MATSUO T , HAYASHI S . Structural phase transitions in anthracene crystals [J ] . ChemPlusChem , 2022 , 87 ( 9 ): e202200157 .

YAMAMOTO T , YAGYU S , TEZUKA Y . Light- and heat-triggered reversible linear-cyclic topological conversion of telechelic polymers with anthryl end groups [J ] . Journal of the American Chemical Society , 2016 , 138 ( 11 ): 3904 - 3911 .

XU X T , LI C H , CHEN W J , et al . Visible light activated dendrimers for solar thermal energy storage and release below 0 ℃ [J ] . Journal of Materials Chemistry A , 2024 , 12 ( 35 ): 23723 - 23731 .

LIANG R , YUAN B , ZHANG F , et al . Azopyridine polymers in organic phase change materials for high energy density photothermal storage and controlled release [J ] . Angewandte Chemie International Edition , 2025 , 64 ( 7 ): e202419165 .

ZHANG Z Y , DONG D , BÖSKING T , et al . Solar azo-switches for effective E → Z photoisomerization by sunlight [J ] . Angewandte Chemie International Edition , 2024 , 63 ( 31 ): e202404528 .

WU Y D , DONG L Q , TANG S X , et al . An innovative azobenzene-based photothermal fabric with excellent heat release performance for wearable thermal management device [J ] . Small , 2024 , 20 ( 49 ): 2404310 .

KUCHARSKI T J , FERRALIS N , KOLPAK A M , et al . Templated assembly of photoswitches significantly increases the energy-storage capacity of solar thermal fuels [J ] . Nature Chemistry , 2014 , 6 ( 5 ): 441 - 447 .

LIU H , FENG Y Y , FENG W . Alkyl-grafted azobenzene molecules for photo-induced heat storage and release via integration function of phase change and photoisomerization [J ] . Composites Communications , 2020 , 21 : 100402 - 100407 .

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