甲烷裂解制多壁碳纳米管的Ni基催化剂研究进展

唐文强; 刘晨龙; 杨薪颖; 商晨诗; 徐成华

doi:10.12434/j.issn.2097-2547.20240514

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甲烷裂解制多壁碳纳米管的Ni基催化剂研究进展

C1化学与催化转化 | 更新时间：2025-10-22

- 甲烷裂解制多壁碳纳米管的Ni基催化剂研究进展
- Research progress on Ni-based catalysts for methane cracking to multi-walled carbon nanotubes
- 低碳化学与化工 2025, 50(10): 1-9.
- 作者机构：
  
  1.成都信息工程大学资源环境学院，四川成都 610225
  2.中国石油天然气股份有限公司石油化工研究院大庆化工研究中心，黑龙江大庆 163710
- 作者简介：
  
  唐文强（2003—），硕士研究生，研究方向为生物质制氢、C1转化与利用，E-mail：18383865349@163.com。
  刘晨龙（1992—），博士，副教授，研究方向为生物质制氢、C1转化与利用，E-mail： liucl1992@qq.com。
- 基金信息：
  
  四川省自然科学基金(2022NSFSC1058);成都信息工程大学培育团队(KYTD202346)
- DOI：10.12434/j.issn.2097-2547.20240514
  中图分类号： TQ07
- 收稿：2024-12-26，
  
  修回：2025-03-14，
  
  纸质出版：2025-10-25
- 稿件说明：
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唐文强,刘晨龙,杨薪颖等.甲烷裂解制多壁碳纳米管的Ni基催化剂研究进展[J].低碳化学与化工,2025,50(10):1-9.

TANG Wenqiang,LIU Chenlong,YANG Xinying,et al.Research progress on Ni-based catalysts for methane cracking to multi-walled carbon nanotubes[J].Low-Carbon Chemistry and Chemical Engineering,2025,50(10):1-9.
唐文强,刘晨龙,杨薪颖等.甲烷裂解制多壁碳纳米管的Ni基催化剂研究进展[J].低碳化学与化工,2025,50(10):1-9. DOI： 10.12434/j.issn.2097-2547.20240514.

TANG Wenqiang,LIU Chenlong,YANG Xinying,et al.Research progress on Ni-based catalysts for methane cracking to multi-walled carbon nanotubes[J].Low-Carbon Chemistry and Chemical Engineering,2025,50(10):1-9. DOI： 10.12434/j.issn.2097-2547.20240514.

摘要

碳纳米管是一种由层状石墨卷曲形成的独特管状纳米材料，具备机械强度高、导电性优异、生物相容性良好、化学性能稳定和比表面积较大等优点，被广泛应用于众多领域。化学气相沉积（CVD）法是合成碳纳米管的关键技术之一，凭借其可控性好和产率高的优点，成为大规模合成高性能碳纳米管的主流技术。Ni基催化剂因具有高催化活性和产物选择性，被广泛用于催化甲烷裂解。对Ni基催化剂催化甲烷裂解下的多壁碳纳米管（MWCNTs）生长机理以及不同类型Ni基催化剂对MWCNTs结构的调控进行了总结，并进一步对Ni基催化剂催化甲烷裂解可控生长MWCNTs进行了展望，以期为甲烷裂解制备MWCNTs的相关研究提供指引。

Abstract

Carbon nanotubes are tubular nanomaterials formed by the coiling of layered graphite

which are widely used in many fields because of high mechanical strength

excellent conductivity

good biocompatibility

stable chemical property and large specific surface area. Chemical vapor deposition (CVD) method is one of the key technologies for the synthesis of carbon nanotubes

and has become the mainstream technology for large-scale synthesis of high-performance carbon nanotubes due to its controllability and high yield. Ni-based catalysts are widely used for methane cracking due to their high catalytic activity and product selectivity. The growth mechanisms of multi-walled carbon nanotubes (MWCNTs) catalyzed by Ni-based catalysts for methane cracking and the regulation of MWCNTs structures by different types of Ni-based catalysts were summarized. Furthermore

the controllable growth of MWCNTs catalyzed by Ni-based catalysts for methane cracking was prospected

in order to provide guidance for the relevant research on methane cracking to prepare MWCNTs.

关键词

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references

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