煤气中硫化氢和羰基硫的干法脱除/转化机理研究进展

张晓芬; 邓一丹; 段新伟; 米杰; 王建成; 武蒙蒙

doi:10.12434/j.issn.2097-2547.20240500

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煤气中硫化氢和羰基硫的干法脱除/转化机理研究进展

分离材料与净化技术 | 更新时间：2025-11-25

- 煤气中硫化氢和羰基硫的干法脱除/转化机理研究进展
- Research progress on dry removal/conversion mechanisms of hydrogen sulfide and carbonyl sulfide in coal gas
- 低碳化学与化工 2025, 50(11): 74-85.
- 作者机构：
  
  1.太原理工大学省部共建煤基能源清洁高效利用国家重点实验室，山西太原 030024
  2.太原理工大学煤科学与技术教育部重点实验室，山西太原 030024
  3.太原理工大学环境与生态学院，山西晋中 030600
- 作者简介：
  
  张晓芬（1999—），硕士研究生，研究方向为气体净化，E-mail：zhangxiaofen1030@163.com。
  武蒙蒙（1985—），博士，副教授，研究方向为气体净化，E-mail：wumengmeng111@126.com。
- 基金信息：
  
  国家自然科学基金(22278294;21978188);山西省自然科学基金(20210302123191);山西省科技创新人才团队项目(202204051002025);山西省环境催化材料技术创新中心项目(202104010911008)
- DOI：10.12434/j.issn.2097-2547.20240500
  中图分类号： TQ546;X701.3
- 收稿：2024-12-18，
  
  修回：2025-01-15，
  
  纸质出版：2025-11-25
- 稿件说明：
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张晓芬,邓一丹,段新伟等.煤气中硫化氢和羰基硫的干法脱除/转化机理研究进展[J].低碳化学与化工,2025,50(11):74-85.

ZHANG Xiaofen,DENG Yidan,DUAN Xinwei,et al.Research progress on dry removal/conversion mechanisms of hydrogen sulfide and carbonyl sulfide in coal gas[J].Low-Carbon Chemistry and Chemical Engineering,2025,50(11):74-85.
张晓芬,邓一丹,段新伟等.煤气中硫化氢和羰基硫的干法脱除/转化机理研究进展[J].低碳化学与化工,2025,50(11):74-85. DOI： 10.12434/j.issn.2097-2547.20240500.

ZHANG Xiaofen,DENG Yidan,DUAN Xinwei,et al.Research progress on dry removal/conversion mechanisms of hydrogen sulfide and carbonyl sulfide in coal gas[J].Low-Carbon Chemistry and Chemical Engineering,2025,50(11):74-85. DOI： 10.12434/j.issn.2097-2547.20240500.

摘要

煤气（包括气化煤气、焦炉煤气及高炉煤气）中所含的硫化氢（H

S）和羰基硫（COS）会导致催化剂中毒、设备腐蚀及环境污染等问题，因此煤气脱硫具有重要意义。以密度泛函理论（DFT）研究方法为线索，综述了煤气干法脱硫机理研究进展。首先，讨论了H

S在不同金属氧化物、金属有机框架材料（MOFs）及活性炭材料表面的吸附机理，并分析了工业应用中常见金属氧化物表面的脱硫反应路径。其次，阐述了脱硫剂再生过程中O

在金属硫化物表面的解离及相关反应机理，进一步揭示了助剂掺杂改性影响金属氧化物脱硫再生行为的微观机理，并分析了脱硫过程中的放硫机理。在COS的催化水解/氢解转化方面，探讨了COS在催化剂表面的吸附与转化机理。最后，总结了现有研究中存在的问题，并对未来该领域的研究提出了建议。

Abstract

The presence of hydrogen sulfide (H

S) and carbonyl sulfide (COS) in coal gas (including gasification gas

coke oven gas and blast furnace gas) can lead to catalyst poisoning

equipment corrosion and environmental pollution

making gas desulfurization crucial. The research progress on the dry gas desulfurization mechanism based on density functional theory (DFT) was summarized. Firstly

the adsorption mechanisms of H

S on the surfaces of various metal oxides

metal-organic framework materials (MOFs) and activated carbon materials were examined

along with an analysis of the desulfurization reaction pathways on commonly used metal oxides in industrial applications. Secondly

the dissociation and reaction mechanisms of O

on the surface of metal sulfides during the regeneration of desulfurizers were elucidated

further revealing the microscopic mechanisms by which dopant modification influences the desulfurization and regeneration behavior of metal oxides. Ad

ditionally

the sulfur release mechanism during desulfurization was analyzed. Regarding the catalytic hydrolysis and hydrogenolysis of COS

the adsorption and transformation mechanisms of COS on catalyst surfaces were explored. Finally

existing challenges in the research field were summarized

and future research directions were proposed.

关键词

Keywords

references

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