CO<sub>2</sub>加氢制CH<sub>4</sub>/CO的负载型金属催化剂界面调控研究进展

何悦; 李瑞英

doi:10.12434/j.issn.2097-2547.20240494

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CO₂加氢制CH₄/CO的负载型金属催化剂界面调控研究进展

C1化学与催化转化 | 更新时间：2025-04-27

- CO₂加氢制CH₄/CO的负载型金属催化剂界面调控研究进展
- 暂无标题
- 低碳化学与化工 2025, 50(4): 19-28.
- 作者机构：
  
  1.浙江师范大学化学与材料科学学院，浙江金华 321004
  2.中国科学院山西煤炭化学研究所，山西太原 030001
- 作者简介：
  
  何悦（1999—），硕士研究生，研究方向为CO2加氢催化剂设计，E-mail：18903063285@163.com。
  李瑞英（1995—），博士后，研究方向为工业催化，E-mail：liruiying@sxicc.ac.cn。
- 基金信息：
  
  山西省基础研究计划青年项目(202403021222488)
- DOI：10.12434/j.issn.2097-2547.20240494
  中图分类号： TQ426;O643.36
- 收稿日期：2024-12-15，
  
  修回日期：2025-01-17，
  
  纸质出版日期：2025-04-25
- 稿件说明：
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何悦,李瑞英.CO₂加氢制CH₄/CO的负载型金属催化剂界面调控研究进展[J].低碳化学与化工,2025,50(04):19-28.

HE Yue,LI Ruiying.Research progress on interfacial modulation of supported metal catalysts for CO₂ hydrogenation to CH₄/CO[J].Low-Carbon Chemistry and Chemical Engineering,2025,50(04):19-28.
何悦,李瑞英.CO₂加氢制CH₄/CO的负载型金属催化剂界面调控研究进展[J].低碳化学与化工,2025,50(04):19-28. DOI： 10.12434/j.issn.2097-2547.20240494.

HE Yue,LI Ruiying.Research progress on interfacial modulation of supported metal catalysts for CO₂ hydrogenation to CH₄/CO[J].Low-Carbon Chemistry and Chemical Engineering,2025,50(04):19-28. DOI： 10.12434/j.issn.2097-2547.20240494.

摘要

为实现“双碳”目标以及缓解环境污染问题，CO

利用成为了当前研究的热点之一。由于受到CO

分子结构以及复杂的加氢路线限制，开发高活性、高选择性的催化剂是CO

高值化利用的关键。负载型金属催化剂因具有大比表面积和高分散度等优势，在CO

加氢制CH

/CO反应中应用广泛。为提高催化剂的催化活性和产物选择性，需要了解负载型金属催化剂在CO

加氢制CH

/CO反应过程中的界面调控作用。其中，影响界面结构的因素包括金属结构、载体性质和金属-载体相互作用，这些因素共同决定了催化剂催化性能。总结了CO

加氢制CH

/CO反应的热力学和机理，重点综述了负载型金属催化剂的研究进展，并讨论了负载型金属催化剂在CO

加氢制CH

/CO反应中的界面调控作用和催化剂未来的发展方向。

Abstract

To achieve the goal of “dual carbon” and alleviate environmental pollution

utilization of CO

has become a focal point in current research. Due to the limitations of CO

molecular structure and the complexity of hydrogenation routes

the development of highly active and selective catalysts is crucial for achieving high-value utilization of CO

. Supported metal catalysts are widely used in CO

hydrogenation to CH

/CO reaction due to the advantages of large specific surface area and high dispersion. To enhance the catalytic activity and product selectivity of catalysts

it is essential to understand the role of interfacial modulation in supported metal catalysts during CO

hydrogenation to CH

/CO reaction. The interfacial structure is influenced by m

etal structures

carrier properties and metal-carrier interactions

which determine the catalytic performance of catalysts. The thermodynamics and reaction mechanisms of CO

hydrogenation to CH

/CO were summarized

with a focus on the research progress on supported metal catalysts. The interfacial modulation and future development direction of supported metal catalysts for CO

hydrogenation to CH

/CO were discussed.

关键词

Keywords

references

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DOI：10.12434/j.issn.2097-2547.20240494

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CO₂加氢制CH₄/CO的负载型金属催化剂界面调控研究进展