碳基材料在CO<sub>2</sub>捕集中应用的研究进展

孟凡鹏; 董琦; 安永胜; 周元欣; 党红星; 高晓劝; 薛艳阳; 张云蓉; 梅杰琼; 陆诗建

doi:10.12434/j.issn.2097-2547.20240467

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碳基材料在CO₂捕集中应用的研究进展

CCUS技术 | 更新时间：2025-11-25

- 碳基材料在CO₂捕集中应用的研究进展
- Research progress of application of carbon-based materials for CO₂ capture
- 低碳化学与化工 2025, 50(11): 97-109.
- 作者机构：
  
  1.中国石油天然气管道工程有限公司，河北廊坊 065099
  2.中国矿业大学材料与物理学院，江苏徐州 221008
  3.中国矿业大学碳中和研究院，江苏徐州 221008
  4.中国矿业大学化工学院，江苏徐州 221008
- 作者简介：
  
  孟凡鹏（1986—），硕士研究生，高级工程师，研究方向为CO2捕集与资源化利用，E-mail：mengfanpeng86@163.com。
  陆诗建（1984—），博士，研究员，研究方向为CO2捕集、利用与封存，E-mail：lushijian@cumt.edu.cn。
- 基金信息：
  
  国家重点研发计划(2022YFE0115800);中央高校基本科研业务费专项资金(2023KYJD1004);江苏省碳达峰碳中和科技创新专项(BE2023852);浙江省科技计划(2023C03156);宁波市科技计划(2022Z163)
- DOI：10.12434/j.issn.2097-2547.20240467
  中图分类号： TQ426
- 收稿：2024-11-23，
  
  修回：2024-12-25，
  
  纸质出版：2025-11-25
- 稿件说明：
移动端阅览
孟凡鹏,董琦,安永胜等.碳基材料在CO₂捕集中应用的研究进展[J].低碳化学与化工,2025,50(11):97-109.

MENG Fanpeng,DONG Qi,AN Yongsheng,et al.Research progress of application of carbon-based materials for CO₂ capture[J].Low-Carbon Chemistry and Chemical Engineering,2025,50(11):97-109.
孟凡鹏,董琦,安永胜等.碳基材料在CO₂捕集中应用的研究进展[J].低碳化学与化工,2025,50(11):97-109. DOI： 10.12434/j.issn.2097-2547.20240467.

MENG Fanpeng,DONG Qi,AN Yongsheng,et al.Research progress of application of carbon-based materials for CO₂ capture[J].Low-Carbon Chemistry and Chemical Engineering,2025,50(11):97-109. DOI： 10.12434/j.issn.2097-2547.20240467.

摘要

随着全球气候变化问题的日益严重，CO

排放控制成为关注的重点。碳基燃料燃烧过程是CO

排放的主要来源之一，开发高效的CO

捕集技术对减缓温室效应具有重要意义。近年来，基于碳基材料的CO

捕集技术受到越来越多的关注。对CO

捕集（燃烧后捕集）用碳基材料的研究进展进行了综述，重点分析了碳基材料的CO

捕集机理，主要包括物理吸附、化学吸附和气体交换等。总结了不同类型碳基材料的特性及其在CO

捕集中的应用，并分析了不同改性方法对生物炭CO

捕集性能的影响。最后对碳基材料在CO

捕集中存在的技术瓶颈和未来发展方向进行了分析和展望。

Abstract

With the increasing severity of the global climate change problem

emission control has become the focus of attention. Combustion process of carbon-based fuel is one of the main sources of CO

emission

and the development of efficient CO

capture technology is of great significance to mitigate the greenhouse effect. In recent years

capture technologies based on carbon-based materials have received increasing attention. Research progress of carbon-based materials for CO

capture (post-combustion capture) was reviewed

focusing on analyzing the CO

capture mechanisms of carbon-based materials

mainly including physical adsorption

chemical adsorption and gas exchange

etc. The characteristics of different types of carbon-based materials and their applications for CO

capture were summarized

and the effects of different modification methods on the CO

capture performance of biochar were analyzed. Finally

the technical bottlenecks and future development directions of carbon-based materials for CO

capture were analyzed and prospected.

关键词

Keywords

references

水煮花生 . 联合国政府间气候变化专门委员会第六次综合评估报告发布 [J ] . 科学 , 2023 , 75 ( 3 ): 10 .

BOILED PEANUTS . Sixth integrated assessment report of the United Nations Intergovernmental Panel on Climate Change released [J ] . Science , 2023 , 75 ( 3 ): 10 .

陈诗一 . 能源消耗、二氧化碳排放与中国工业的可持续发展 [J ] . 经济研究 , 2009 , 4 ( 4 ): 41 - 55 .

CHEN S Y . Energy consumption,CO 2 emission and sustainable development in Chinese Industry [J ] . Economic Research , 2009 , 4 ( 4 ): 41 - 55 .

向国育 , 申长俊 , 陆诗建 , 等 . 二氧化碳捕集、利用与封存示范工程进展 [J ] . 低碳化学与化工 , 2025 , 50 ( 3 ): 113 - 122 .

XIANG G Y , SHEN C J , LU S J , et al . Progress of carbon dioxide capture, utilization and storage demonstration engineerings [J ] . Low-Carbon Chemistry and Chemical Engineering , 2025 , 50 ( 3 ): 113 - 122 .

WILBERFORCE T , BAROUTAJI A , SOUDAN B , et al . Outlook of carbon capture technology and challenges [J ] . Science of the Total Environment , 2019 , 657 : 56 - 72 .

ZAKER A , BEN-HAMMOUDA S , SUN J , et al . Carbon-based materials for CO 2 capture: Their production, modification and performance [J ] . Journal of Environmental Chemical Engineering , 2023 , 11 ( 3 ): 109741 .

ISAH M , LAWAL R , ONAIZI S A . CO 2 capture and conversion using graphene-based materials: A review on recent progresses and future outlooks [J ] . Green Chemical Engineering , 2024 .

DENG M , PARK H G . Spacer-assisted amine-coiled carbon nanotubes for CO 2 capture [J ] . Langmuir , 2019 , 35 ( 13 ): 4453 - 4459 .

ZHANG Y , GAO J M , FENG D D , et al . Study on regenerative process of the new carbon capture technique based on antisolvent crystallization to strengthen crystallization [J ] . The Canadian Journal of Chemical Engineering , 2017 , 95 ( 10 ): 1979 - 1984 .

CREAMER A E , GAO B . Carbon-based adsorbents for post-combustion CO 2 capture: A critical review [J ] . Environmental Science & Technology , 2016 , 50 ( 14 ): 7276 - 7289 .

WEI H R , DENG S B , HU B Y , et al . Granular bamboo-derived activated carbon for high CO 2 adsorption: The dominant role of narrow micropores [J ] . ChemSusChem , 2012 , 5 ( 12 ): 2354 - 2360 .

ZHOU Y B , TAN P , HE Z Q , et al . CO 2 adsorption performance of nitrogen-doped porous carbon derived from licorice residue by hydrothermal treatment [J ] . Fuel , 2022 , 311 : 122507 .

LIU S , YANG H B , HUANG X , et al . Identifying active sites of nitrogen-doped carbon materials for the CO 2 reduction reaction [J ] . Advanced Functional Materials , 2018 , 28 ( 21 ): 1800499 .

GUNAWARDENE O H P , GUNATHILAKE C A , VIKRANT K , et al . Carbon dioxide capture through physical and chemical adsorption using porous carbon materials: A review [J ] . Atmosphere , 2022 , 13 ( 3 ): 397 .

HONG S M , CHOI S W , KIM S H , et al . Porous carbon based on polyvinylidene fluoride: Enhancement of CO 2 adsorption by physical activation [J ] . Carbon , 2016 , 99 : 354 - 360 .

LIU F Y , WANG Z X , ZHANG H T , et al . Nitrogen, oxygen and sulfur co-doped hierarchical porous carbons toward high-performance supercapacitors by direct pyrolysis of kraft lignin [J ] . Carbon , 2019 , 149 : 105 - 116 .

SCHNEIDERMANN C , KENSY C , OTTO P , et al . Nitrogen-doped biomass-derived carbon formed by mechanochemical synthesis for lithium-sulfur batteries [J ] . ChemSusChem , 2019 , 12 ( 1 ): 310 - 319 .

QIAN W J , SUN F X , XU Y H , et al . Human hair-derived carbon flakes for electrochemical supercapacitors [J ] . Energy & Environmental Science , 2014 , 7 ( 1 ): 379 - 386 .

FERRERO G A , FUERTES A B , SEVILLA M . From Soybean residue to advanced supercapacitors [J ] . Scientific Reports , 2015 , 5 ( 1 ): 16618 .

RANA M , SUBRAMANI K , SATHISH M , et al . Soya derived heteroatom doped carbon as a promising platform for oxygen reduction, supercapacitor and CO 2 capture [J ] . Carbon , 2017 , 114 : 679 - 689 .

NIE R F , PENG X L , ZHANG H F , et al . Transfer hydrogenation of bio-fuel with formic acid over biomass-derived N-doped carbon supported acid-resistant Pd catalyst [J ] . Catalysis Science & Technology , 2017 , 7 ( 3 ): 627 - 634 .

SHENG W Z , LI Z J , LIU Y H . Surface chemical functional groups modification of porous carbon [J ] . Recent Patents on Chemical Engineering , 2008 , 1 ( 1 ): 27 - 40 .

CUI G K , WANG J J , ZHANG S J . Active chemisorption sites in functionalized ionic liquids for carbon capture [J ] . Chemical Society Reviews , 2016 , 45 ( 15 ): 4307 - 4339 .

BABU D J , BRUNS M , SCHNEIDER R , et al . Understanding the influence of N-doping on the CO 2 adsorption characteristics in carbon nanomaterials [J ] . The Journal of Physical Chemistry C , 2017 , 121 ( 1 ): 616 - 626 .

ZHAO J , DENG S , ZHAO L , et al . Understanding the effect of H 2 O on CO 2 adsorption capture: Mechanism explanation, quantitative approach and application [J ] . Sustainable Energy & Fuels , 2020 , 4 ( 12 ): 5970 - 5986 .

ZHANG Z , CANO Z P , LUO D , et al . Rational design of tailored porous carbon-based materials for CO 2 capture [J ] . Journal of Materials Chemistry A , 2019 , 7 ( 37 ): 20985 - 21003 .

LI L , QUINLIVAN P A , KNAPPE D R U . Effects of activated carbon surface chemistry and pore structure on the adsorption of organic contaminants from aqueous solution [J ] . Carbon , 2002 , 40 ( 12 ): 2085 - 2100 .

SHARIFIAN R , WAGTERVELD R M , DIGDAYA I A , et al . Electrochemical carbon dioxide capture to close the carbon cycle [J ] . Energy & Environmental Science , 2021 , 14 ( 2 ): 781 - 814 .

LOZANO D , CAZORLA D , LINARES A , et al . Activated carbon monoliths for methane storage: Influence of binder [J ] . Carbon , 2002 , 40 ( 15 ): 2817 - 2825 .

QASEM N A , QADIR N U , BEN-MANSOUR R , et al . Synthesis, characterization, and CO 2 breakthrough adsorption of a novel MWCNT/MIL-101(Cr) composite [J ] . Journal of CO 2 Utilization , 2017 , 22 : 238 - 249 .

王芳 , 安晓圣 , 穆金池 , 等 . 低压下碳纳米管用于水合物法捕集烟道气中CO 2 动力学机制研究 [J ] . 低碳化学与化工 , 2025 , 50 ( 2 ): 148 - 156 .

WANG F , AN X S , MU J C , et al . Kinetic mechanism of carbon nanotubes for CO 2 capture in flue gas by hydrate method under low pressures [J ] . Low-Carbon Chemistry and Chemical Engineering , 2025 , 50 ( 2 ): 148 - 156 .

HE M S , ZHANG S C , ZHANG J . Horizontal single-walled carbon nanotube arrays: Controlled synthesis, characterizations, and applications [J ] . Chemical Reviews , 2020 , 120 ( 22 ): 12592 - 12684 .

KELLER L , OHS B , LENHART J , et al . High capacity polyethylenimine impregnated microtubes made of carbon nanotubes for CO 2 capture [J ] . Carbon , 2018 , 126 : 338 - 345 .

LIU Q , SHI Y , ZHENG S D , et al . Amine-functionalized low-cost industrial grade multi-walled carbon nanotubes for the capture of carbon dioxide [J ] . Journal of Energy Chemistry , 2014 , 23 ( 1 ): 111 - 118 .

IRANI M , JACOBSON A T , GASEM K A M , et al . Modified carbon nanotubes/tetrae-hylenepentamine for CO 2 capture [J ] . Fuel , 2017 , 206 : 10 - 18 .

DENG M , PARK H G . Spacer-assisted amine-coiled carbon nanotubes for CO 2 capture [J ] . Langmuir , 2019 , 35 ( 13 ): 4453 - 4459 .

李俊 , 马丹丹 , 邹雅珺 , 等 . 石墨相氮化碳的改性及其在光催化中的应用进展 [J ] . 中国材料进展 , 2024 , 43 ( 7 ): 565 - 578+626 .

LI J , MA D D , ZOU Y J , et al . The modification of graphite carbon nitride and its applications in photocatalysis [J ] . Progress of Materials in China , 2024 , 43 ( 7 ): 565 - 578+626 .

TALAPANENI S N , SINGH G , KIM I Y , et al . Nanostructured carbon nitrides for CO 2 capture and conversion [J ] . Advanced Materials , 2020 , 32 ( 18 ): 1904635 .

PENG H L , ZHONG F Y , ZHANG J B , et al . Graphitic carbon nitride functionalized with polyethylenimine for highly effective capture of carbon dioxide [J ] . Industrial & Engineering Chemistry Research , 2018 , 57 ( 32 ): 11031 - 11038 .

PARK D H , LAKHI K S , RAMADASS K , et al . Energy efficient synthesis of ordered mesoporous carbon nitrides with a high nitrogen content and enhanced CO 2 capture capacity [J ] . Chemistry—A European Journal , 2017 , 23 ( 45 ): 10753 - 10757 .

SREEDHAR I , UPADHYAY U , ROY P , et al . Carbon capture and utilization by graphenes-path covered and ahead [J ] . Journal of Cleaner Production , 2021 , 284 : 124712 .

RAMAR V , BALASUBRAMANIAN K . Reduced graphene oxide/WO 3 nanorod composites for photocatalytic degradation of methylene blue under sunlight irradiation [J ] . ACS Applied Nano Materials , 2021 , 4 ( 5 ): 5512 - 5521 .

SUVARNAPHAET P , PECHPRASARN S . Graphene-based materials for biosensors: A review [J ] . Sensors , 2017 , 17 ( 10 ): 2161 .

MISHRA A K , RAMAPRABHU S . Nanostructured polyaniline decorated graphene sheets for reversible CO 2 capture [J ] . Journal of Materials Chemistry , 2012 , 22 ( 9 ): 3708 - 3712 .

MENG L Y , PARK S J . Effect of exfoliation temperature on carbon dioxide capture of graphene nanoplates [J ] . Journal of Colloid and Interface Science , 2012 , 386 ( 1 ): 285 - 290 .

ZHANG L L , ZHAO X , STOLLER M D , et al . Highly conductive and porous activated reduced graphene oxide films for high-power supercapacitors [J ] . Nano Letters , 2012 , 12 ( 4 ): 1806 - 1812 .

HONG S M , KIM S H , JEONG B G , et al . Development of porous carbon nanofibers from electrospun polyvinylidene fluoride for CO 2 capture [J ] . RSC Advances , 2014 , 4 ( 103 ): 58956 - 58963 .

LI Y , ZOU B , HU C W , et al . Nitrogen-doped porous carbon nanofiber webs for efficient CO 2 capture and conversion [J ] . Carbon , 2016 , 99 : 79 - 89 .

IQBAL N , WANG X , YU J , et al . Robust and flexible carbon nanofibers doped with amine functionalized carbon nanotubes for efficient CO 2 capture [J ] . Advanced Sustainable Systems , 2017 , 1 ( 3/4 ): 1600028 .

FENG D D , ZHAO Y J , ZHANG Y , et al . Effects of H 2 O and CO 2 on the homogeneous conversion and heterogeneous reforming of biomass tar over biochar [J ] . International Journal of Hydrogen Energy , 2017 , 42 ( 18 ): 13070 - 13084 .

CUI S B , ZHAO Y , LIU Y X , et al . Preparation of straw porous biochars by microwave-assisted KOH activation for removal of gaseous H 2 S [J ] . Energy & Fuels , 2021 , 35 ( 22 ): 18592 - 18603 .

SHARMA A , JINDAL J , MITTAL A , et al . Carbon materials as CO 2 adsorbents: A review [J ] . Environmental Chemistry Letters , 2021 , 19 ( 2 ): 875 - 910 .

袁帅 , 赵立欣 , 孟海波 , 等 . 生物炭主要类型, 理化性质及其研究展望 [J ] . 植物营养与肥料学报 , 2016 , 22 ( 5 ): 1402 - 1417 .

YUAN S , ZHAO L X , MENG H B , et al . The main types of biochar and their properties and expectative researches [J ] . Journal of Plant Nutrition and Fertilizer , 2016 , 22 ( 5 ): 1402 - 1417 .

WEDLER C , SPAN R . Micropore analysis of biomass chars by CO 2 adsorption: Comparison of different analysis methods [J ] . Energy & Fuels , 2021 , 35 ( 10 ): 8799 - 8806 .

ZENG Z W , TAN X F , LIU Y G , et al . Comprehensive adsorption studies of doxycycline and ciprofloxacin antibiotics by biochars prepared at different temperatures [J ] . Frontiers in Chemistry , 2018 , 6 : 80 .

JIA Y H , SHI S L , LIU J , et al . Study of the effect of pyrolysis temperature on the Cd 2+ adsorption characteristics of biochar [J ] . Applied Sciences , 2018 , 8 ( 7 ): 1019 .

SEWU D D , WOO S H , LEE D S , et al . Biochar from the co-pyrolysis of Saccharina japonica and goethite as an adsorbent for basic blue 41 removal from aqueous solution [J ] . Science of the Total Environment , 2021 , 797 : 149160 .

LIANG W W , LIU Z W , PENG J J , et al . Enhanced CO 2 adsorption and CO 2 /N 2 /CH 4 selectivity of novel carbon composites CPDA@A-Cs [J ] . Energy & Fuels , 2018 , 33 ( 1 ): 493 - 502 .

王媛 , 高峰 , 李存梅 , 等 . 苛性碱二次活化法制备中孔活性炭 [J ] . 太原理工大学学报 , 2014 , 45 ( 2 ): 215 - 219 .

WANG Y , GAO F , LI C M , et al . Preparation of mesoporous activated carbon by caustic alkali reactivation and its CO 2 adsorption property [J ] . Journal of Taiyuan University of Technology , 2014 , 45 ( 2 ): 215 - 219 .

ZGRZEBNICKI M , MICHAL C E , WROBEL R J . Improving the carbon dioxide uptake efficiency of activated carbons using a secondary activation with potassium hydroxide [J ] . Polish Journal of Chemical Technology , 2018 , 20 ( 3 ): 87 - 94 .

魏建文 , 林志峰 , 何泽瑜 , 等 . 蔗渣活性炭二次活化制备及其吸附CO 2 性能研究 [J ] . 无机材料学报 , 2017 , 32 ( 1 ): 18 - 24 .

WEI J W , LIN Z F , HE Z Y , et al . Bagasse activated carbon reactivation promotes adsorption of CO 2 [J ] . Journal of Inorganic Materials , 2017 , 32 ( 1 ): 18 - 24 .

ZHANG Y , WANG S Z , FENG D D , et al . Functional biochar synergistic solid/liqu id-phase CO 2 capture: A review [J ] . Energy & Fuels , 2022 , 36 ( 6 ): 2945 - 2970 .

WU R P , YE Q , WU K , et al . Highly efficient CO 2 adsorption of corn kernel-derived porous carbon with abundant oxygen functional groups [J ] . Journal of CO 2 Utilization , 2021 , 51 : 101620 .

OGINNI O , SINGH K , OPORTO G , et al . Effect of one-step and two-step H 3 PO 4 activation on activated carbon characteristics [J ] . Bioresource Technology Reports , 2019 , 8 : 100307 .

SHAO J A , ZHANG J J , ZHANG X , et al . Enhance SO 2 adsorption performance of biochar modified by CO 2 activation and amine impregnation [J ] . Fuel , 2018 , 224 : 138 - 146 .

DENG J Q , LI X D , WEI X , et al . Different adsorption behaviors and mechanisms of a novel amino-functionalized hydrothermal biochar for hexavalent chromium and pentavalent antimony [J ] . Bioresource Technology , 2020 , 310 : 123438 .

代祥 , 罗婴棋 , 张文俊 , 等 . 氮掺杂生物炭去除水中六价铬的效果及机理 [J ] . 环境科学学报 , 2023 , 43 ( 11 ): 84 - 93 .

DAI X , LUO Y Q , ZHANG W J , et al . Removal of hexavalent chromium from water using nitrogen-doped biochar:Performance and mechanism [J ] . Journal of Environmental Science , 2023 , 43 ( 11 ): 84 - 93 .

INAGAKI M , TOYODA M , SONEDA Y , et al . Nitrogen-doped carbon materials [J ] . Carbon , 2018 , 132 : 104 - 140 .

GORGULHO H F , GONÇALVES F , PEREIRA M F R , et al . Synthesis and characterization of nitrogen-doped carbon xerogels [J ] . Carbon , 2009 , 47 ( 8 ): 2032 - 2039 .

YU J Y , GUO M Y , MUHAMMAD F , et al . One-pot synthesis of highly ordered nitrogen-containing mesoporous carbon with resorcinol-urea-formaldehyde resi n for CO 2 capture [J ] . Carbon , 2014 , 69 : 502 - 514 .

HE S , CHEN G Y , XIAO H , et al . Facile preparation of N-doped activated carbon produced from rice husk for CO 2 capture [J ] . Journal of Colloid and Interface Science , 2021 , 582 : 90 - 101 .

YANG Z X , ZHANG G J , XU Y , et al . One step N-doping and activation of biomass carbon at low temperature through NaNH 2 : An effective approach to CO 2 adsorbents [J ] . Journal of CO 2 Utilization , 2019 , 33 : 320 - 329 .

KHANDAKER T , HOSSAIN M S , DHAR P K , et al . Efficacies of carbon-based adsorbents for carbon dioxide capture [J ] . Processes , 2020 , 8 ( 6 ): 654 .

SUN H , LI Y J , BIAN Z G , et al . Thermochemical energy storage performances of Ca-based natural and waste materials under high pressure during CaO/CaCO 3 cycles [J ] . Energy Conversion and Management , 2019 , 197 : 111885 .

MA X T , LI Y J , YAN X Y , et al . Preparation of a morph-genetic CaO-based sorbent using paper fiber as a biotemplate for enhanced CO 2 capture [J ] . Chemical Engineering Journal , 2019 , 361 : 235 - 244 .

GUO F Q , JIANG X C , LI X L , et al . Synthesis of MgO/Fe 3 O 4 nanoparticles embedded activated carbon from biomass for high-efficient adsorption of malachite green [J ] . Materials Chemistry and Physics , 2020 , 240 : 122240 .

HE S , CHEN G Y , XIAO H , et al . Facile preparation of N-doped activated carbon produced from rice husk for CO 2 capture [J ] . Journal of Colloid and Interface Science , 2021 , 582 : 90 - 101 .

REHMAN A , PARK S J . Tunable nitrogen-doped microporous carbons: Delineating the role of optimum pore size for enhanced CO 2 adsorption [J ] . Chemical Engineering Journal , 2019 , 362 : 731 - 742 .

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Research progress of application of carbon-based materials for CO2 capture

DOI：10.12434/j.issn.2097-2547.20240467

摘要

Abstract

关键词

Keywords

references

碳基材料在CO₂捕集中应用的研究进展

Research progress of application of carbon-based materials for CO₂ capture