含氧烃类尾气脱氧催化剂研究进展

王甜; 卜婷婷; 杨淑萍; 周金波; 孙世林; 马艳捷; 苟文甲

doi:10.12434/j.issn.2097-2547.20240439

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含氧烃类尾气脱氧催化剂研究进展

分离材料与净化技术 | 更新时间：2025-09-26

- 含氧烃类尾气脱氧催化剂研究进展
- Research progress on deoxidation catalysts for oxygen-containing hydrocarbon tail gases
- 低碳化学与化工 2025, 50(9): 36-47.
- 作者机构：
  
  中国石油石油化工研究院兰州化工研究中心，甘肃兰州 730060
- 作者简介：
  
  王甜（1998—），硕士，助理工程师，研究方向为催化剂开发，E-mail：wangtian123@petrochina.com.cn。
  孙世林（1977—），硕士，高级工程师，研究方向为炼油化工，E-mail：sunshilin@petrochina.com.cn。
- 基金信息：
- DOI：10.12434/j.issn.2097-2547.20240439
  中图分类号： TQ028.2
- 收稿日期：2024-10-29，
  
  修回日期：2024-12-30，
  
  纸质出版日期：2025-09-25
- 稿件说明：
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王甜,卜婷婷,杨淑萍等.含氧烃类尾气脱氧催化剂研究进展[J].低碳化学与化工,2025,50(09):36-47.

WANG Tian,BU Tingting,YANG Shuping,et al.Research progress on deoxidation catalysts for oxygen-containing hydrocarbon tail gases[J].Low-Carbon Chemistry and Chemical Engineering,2025,50(09):36-47.
王甜,卜婷婷,杨淑萍等.含氧烃类尾气脱氧催化剂研究进展[J].低碳化学与化工,2025,50(09):36-47. DOI： 10.12434/j.issn.2097-2547.20240439.

WANG Tian,BU Tingting,YANG Shuping,et al.Research progress on deoxidation catalysts for oxygen-containing hydrocarbon tail gases[J].Low-Carbon Chemistry and Chemical Engineering,2025,50(09):36-47. DOI： 10.12434/j.issn.2097-2547.20240439.

摘要

工业生产中含氧烃类尾气因含氧量高，通常无法循环利用。常见的脱氧技术主要包括化学吸附脱氧、焦炭燃烧脱氧、催化脱氧和物理变压吸附脱氧等。贵金属（Pt、Pd和Ag）和非贵金属（Cu、Mn、Ni、Mo和Fe）催化剂在含氧烃类尾气脱氧领域被广泛研究。介绍了多种含氧烃类尾气脱氧方法，综述了贵金属和非贵金属脱氧催化剂的研究进展，并展望了脱氧催化剂发展面临的挑战与趋势。贵金属脱氧催化剂工业应用成熟，但存在催化剂成本高、原料气组分含量要求严格，以及污染环境等问题。由于高效且绿色环保的特点，非贵金属脱氧催化剂已逐渐成为研究热点，并有望成为未来脱氧催化剂的发展方向。

Abstract

Oxygen-containing hydrocarbon tail gases in industrial production often cannot be recycled due to their high oxygen contents. Common deoxidation technologies include chemical adsorption deoxidation

coke combustion deoxidation

catalytic deoxidation and physical pressure swing adsorption deoxidation. Precious metal (Pt

Pd and Ag) and non-precious metal (Cu

Mo and Fe) catalysts have been widely studied in the field of oxygen-containing hydrocarbon tail gases deoxidation. Various deoxidation methods for oxygen-containing hydrocarbon tail gases were introduced

and the research progress on both precious and non-precious metal deoxidation catalysts was reviewed

and the challenges and trends in the development of deoxidation catalysts were anticipated. While precious metal deoxidation catalysts are mature for industrial applications

they face challenges such as high catalyst costs

strict feed gas composition requirements and environmental pollution. Due to their efficiency and environmentally friendly characteristics

non-precious metal deoxidation catalysts have gradually become a research hotspot and are expected to be the future direction for the development of deoxidation catalysts.

关键词

Keywords

references

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