浏览全部资源
扫码关注微信
乙醇制含氧化学品和烯烃催化剂研究进展
Research progress on catalysts for production of oxygenated chemicals and olefins from ethanol
- 低碳化学与化工 2026, 51(2): 39-47.
- 作者机构：
西南化工研究设计院有限公司 工业排放气综合利用国家重点实验室，国家碳一化学工程技术研究中心， 四川 成都 610225
- 作者简介：
杜佳奇（1997—），硕士，工程师，研究方向为催化剂开发，E-mail：dujiaqi@swchem.com。
李文龙（1989—），硕士，高级工程师，研究方向为催化剂开发，E-mail：liwenlong@swchem.com。
- 基金信息：
DOI：10.12434/j.issn.2097-2547.20240432
中图分类号： TQ207;TQ426收稿：2024-10-22，
修回：2024-12-18，
纸质出版：2026-02-25
- 稿件说明：
移动端阅览
杜佳奇,李文龙,王佳杰等.乙醇制含氧化学品和烯烃催化剂研究进展[J].低碳化学与化工,2026,51(02):39-47.
DU Jiaqi,LI Wenlong,WANG Jiajie,et al.Research progress on catalysts for production of oxygenated chemicals and olefins from ethanol[J].Low-Carbon Chemistry and Chemical Engineering,2026,51(02):39-47.
杜佳奇,李文龙,王佳杰等.乙醇制含氧化学品和烯烃催化剂研究进展[J].低碳化学与化工,2026,51(02):39-47. DOI： 10.12434/j.issn.2097-2547.20240432.
DU Jiaqi,LI Wenlong,WANG Jiajie,et al.Research progress on catalysts for production of oxygenated chemicals and olefins from ethanol[J].Low-Carbon Chemistry and Chemical Engineering,2026,51(02):39-47. DOI： 10.12434/j.issn.2097-2547.20240432.
摘要
随着乙醇产量的快速增长，将其转化为含氧化学品和烯烃不仅可以减少对石油资源的依赖，还有助于满足日益增长的能源和化工产品需求。催化剂是实现乙醇高效转化为含氧化学品和烯烃的关键。综述了乙醇催化转化制含氧化学品和烯烃的反应机理、催化剂设计策略和催化性能等方面的研究进展，并对未来乙醇催化转化催化剂的设计进行了展望。
Abstract
With the rapid growth of ethanol production
converting it into oxygenated chemicals and olefins can not only reduce dependence on petroleum resources
but also help meet the growing demand for energy and chemical products. Catalysts are the key to achieving efficient conversion of ethanol into oxygenated chemicals and olefins. Research progress on the reaction mechanisms
catalyst design strategies and catalytic performances of ethanol catalytic conversion to oxygenated chemicals and olefins was reviewed. And the future design of ethanol catalytic conversion catalysts was also prospected.
关键词
Keywords
references
MIKA L T , CSÉFALVAY E , NÉMETH Á . Catalytic conversion of carbohydrates to initial platform chemicals: Chemistry and sustainability [J ] . Chemical Reviews , 2018 , 118 ( 2 ): 505 - 613 .
PAMPARARO G , HLAVENKOVÁ Z , STYSKALIK A , et al . Suppressing on-stream deactivation of CuSiO 2 catalysts in the dehydrogenation of bioethanol to acetaldehyde [J ] . Catalysis Science & Technology , 2024 , 14 : 4912 - 4926 .
YAO X L , LI T , CHUNG S H , et al . Advances in the catalytic conversion of ethanol into nonoxygenated added-value chemicals [J ] . Advanced Materials , 2025 , 36 ( 51 ): e2406472 .
HANSEN T W , DELARIVA A T , CHALLA S R , et al . Sintering of catalytic nanoparticles: Particle migration or ostwald ripening? [J ] . Accounts of Chemical Research , 2024 , 46 ( 8 ): 1720 - 1730 .
PANG J F , ZHENG M Y , WANG C , et al . Hierarchical echinus-like Cu-MFI catalysts for ethanol dehydrogenation [J ] . ACS Catalysis , 2022 , 10 ( 22 ): 13624 - 13629 .
DE WAELE J , GALVITA V V , POELMAN H , et al . Formation and stability of an active PdZn nanoparticle catalyst on a hydrotalcite-based support for ethanol dehydrogenation [J ] . Catalysis Science & Technology , 2017 , 7 ( 17 ): 3715 - 3727 .
GIANNAKAKIS G , TRIMPALIS A , SHAN J , et al . NiAu single atom alloys for the non-oxidative dehydrogenation of ethanol to acetaldehyde and hydrogen [J ] . Topics in Catalysis , 2018 , 61 ( 5 ): 475 - 486 .
HUANG X X , WU S L , XIAO Z C , et al . Predicting the optimal chemical composition of functionalized carbon catalysts towards oxidative dehydrogenation of ethanol to acetaldehyde [J ] . Nanotoday , 2022 , 44 : 101508 .
CONESA J M , MORALES M V , LÓPEZ-OLMOS C , et al . Comparative study of Cu, Ag and Ag-Cu catalysts over graphite in the ethanol dehydrogenation reaction: Catalytic activity, deactivation and regeneration [J ] . Applied Catalysis A: General , 2019 , 576 : 54 - 64 .
YU D N , DAI W L , WU G J , et al . Stabilizing copper species using zeolite for ethanol catalytic dehydrogenation to acetaldehyde [J ] . Chinese Journal of Catalysis , 2019 , 40 ( 9 ): 1375 - 1384 .
LI X Q , PANG J F , ZHAO Y J , et al . Ethanol dehydrogenation to acetaldehyde over a Cu δ + -based Cu-MFI catalyst [J ] . Chinese Journal of Catalysis , 2023 , 49 : 91 - 101 .
LIU H L , CHANG Z L , FU J , et al . A CuZn-BTC derived stable Cu/ZnO@SiO 2 catalyst for ethanol dehydrogenation [J ] . Applied Catalysis B: Environmental , 2023 , 324 : 122194 .
ZHANG H W , TAN H R , JAENICKE S , et al . Highly efficient and robust Cu catalyst for non-oxidative dehydrogenation of ethanol to acetaldehyde and hydrogen [J ] . Journal of Catalysis , 2020 , 389 : 19 - 28 .
AMOKRANE S , BOUALOUACHE A , SIMON P , et al . Effect of adding transition metals to copper on the dehydrogenation reaction of ethanol [J ] . Catalysis Letters , 2021 , 151 : 2864 - 2883 .
YIN M , PANG J F , GUO J , et al . Tailoring Ni based catalysts by indium for the dehydrogenative coupling of ethanol into ethyl acetate [J ] . Green Energy & Environment , 2024 , 9 ( 8 ): 1321 - 1331 .
GASPAR A B , ESTEVES A M L , MENDES F M T , et al . Chemicals from ethanol: The ethyl acetate one-pot synthesis [J ] . Applied Catalysis A: General , 2009 , 363 ( 1/2 ): 109 - 114 .
INUI K , KURABAYASHI T , SATO S . Direct synthesis of ethyl acetate from ethanol carried out under pressure [J ] . Journal of Catalysis , 2002 , 212 ( 2 ): 207 - 215 .
COLLEY S W , TABATABAEI J , WAUGH K C , et al . The detailed kinetics and mechanism of ethyl ethanoate synthesis over a Cu/Cr 2 O 3 catalyst [J ] . Journal of Catalysis , 2005 , 236 ( 1 ): 21 - 33 .
ZHANG Y D , WNAG Y H , GUAN X , et al . Ce doping promote the selective conversion of ethanol to ethyl acetate via the dehydrogenation-condensation over CuCeZr catalyst [J ] . Journal of Catalysis , 2023 , 426 : 86 - 95 .
LI S Q , ZHANG Y D , WNAG Y H , et al . Effect of the ZrO 2 crystal phase on performance over a CuCeZrO catalyst for dehydrogenative condensation of ethanol to ethyl acetate [J ] . The Journal of Physical Chemistry Letters , 2024 , 15 ( 41 ): 10278 - 10283 .
SANTACESARIA E , CAROTENUTO G , TESSER R , et al . Ethanol dehydrogenation to ethyl acetate by using copper and copper chromite catalysts [J ] . Chemical Engineering Journal , 2012 , 179 : 209 - 220 .
LI M , PENG J R , CHENG Y , et al . Dual-objective optimization and energy efficiency enhancement of natural decantation assisted extractive distillation process for n -butanol/isobutanol/water separation [J ] . Separation and Purification Technology , 2024 , 336 : 126336 .
KACHHADIYA D D , MURTHY Z V P . Separation of n -butanol from aqueous mixtures using TiO 2 and h -BN functionalized MIL-101(Cr) incorporated PVDF mixed matrix membranes [J ] . Separation and Purification Technology , 2023 , 306 : 122613 .
KOZLOWSKI J , DAVIS R . Heterogeneous catalysts for the guerbet coupling of alcohols [J ] . ACS Catalysis , 2013 , 3 : 1588 - 1600 .
LARINA O V , VALIHURA K V , KYRIIENKO P I , et al . Successive vapour phase guerbet condensation of ethanol and 1-butanol over Mg-Al oxide catalysts in a flow reactor [J ] . Applied Catalysis A: General , 2019 , 588 : 117265 .
KODA K , MATSU-URA T , OBORA Y , et al . Guerbet reaction of ethanol to n -butanol catalyzed by iridium complexes [J ] . Chemistry Letters , 2009 , 38 ( 8 ): 838 - 839 .
DOWSON G R M , HADDOW M F , LEE J , et al . Catalytic conversion of ethanol into an advanced biofuel: Unprecedented selectivity for n -butanol [J ] . Angewandte Chemie International Edition , 2013 , 52 ( 34 ): 9005 - 9008 .
DIBENEDETTO T A , JONES W D . Upgrading of ethanol to n -butanol via a ruthenium catalyst in aqueous solution [J ] . Organometallics , 2021 , 40 ( 12 ): 1884 - 1888 .
WANG Z N , YIN M , PANG J F . Active and stable Cu doped NiMgAlO catalysts for upgrading ethanol to n -butanol [J ] . Journal of Energy Chemistry , 2022 , 72 : 306 - 317 .
LIU H W , ZHENG T , HUI T L , et al . Synthesis of n -butanol from ethanol over Pt-Y/beta catalyst: Synergistic catalysis of yttrium and platinum site [J ] . Chemical Engineering Journal , 2024 , 481 : 148397 .
CYPHER S M , PAULY M , CASTRO L G , et al . Ethanol upgrading to n -butanol using transition-metal-incorporated poly(triazine)imide frameworks [J ] . ACS Applied Materials & Interfaces , 2023 , 15 ( 30 ): 36384 - 36393 .
LI H K , YU Z Q , ZHANG Z X , et al . In-depth understanding of highly active silicotungstic acid catalysts for ethanol dehydration to ethylene under industrially favorable condition [J ] . Industrial & Engineering Chemistry Research , 2024 , 63 ( 17 ): 7624 - 7635 .
BI J D , GUO X W , LIU M , et al . High effective dehydration of bio-ethanol into ethylene over nanoscale HZSM-5 zeolite catalysts [J ] . Catalysis Today , 2010 , 149 ( 1 ): 143 - 147 .
SHENG Q T , LING K C , LI Z R , et al . Effect of steam treatment on catalytic performance of HSZM-5 catalyst for ethanol dehydration to ethylene [J ] . Fuel Processing Technology , 2013 , 110 : 73 - 78 .
CHEN B H , LU J Z , WU L P , et al . Dehydration of bio-ethanol to ethylene over iron exchanged HZSM-5 [J ] . Chinese Journal of Catalysis , 2016 , 37 ( 11 ): 1941 - 1948 .
孟晓静 , 陈华 , 彭家琴 , 等 . 甲醇制烯烃反应中多级孔ZSM-11基成型催化剂制备及其应用研究 [J ] . 低碳化学与化工 , 2023 , 48 ( 2 ): 62 - 70 .
MENG X J , CHEN H , PENG J Q , et al . Study on preparation and application of hierarchical porous ZSM-11 based shaping catalysts in methanol-to-olefins reaction [J ] . Low-Carbon Chemistry and Chemical Engineering , 2023 , 48 ( 2 ): 62 - 70 .
李晚秋 , 李玉峰 , 刘冰 , 等 . ZSM-5分子筛形貌与尺寸对己烯催化裂解制丙烯的影响 [J ] . 天然气化工—C1化学与化工 , 2022 , 47 ( 4 ): 113 - 119 .
LI W Q , LI Y F , LIU B , et al . Effect of morphology and size of ZSM-5 zeolites on catalytic cracking of hexene to propylene [J ] . Natural Gas Chemical Industry , 2022 , 47 ( 4 ) : 113 - 119 .
BORGHT K V , BATCHU R , GALVITA V V , et al . Insights into the reaction mechanism of ethanol conversion into hydrocarbons on H-ZSM-5 [J ] . Angewandte Chemie International Edition , 2016 , 55 ( 41 ): 12817 - 12821 .
IWAMOTO M . Selective catalytic conversion of bio-ethanol to propene: A review of catalysts and reaction pathways [J ] . Catalysis Today , 2015 , 242 : 243 - 248 .
FURUMOTO Y , HARADA Y , TSUNOJI N , et al . Effect of acidity of ZSM-5 zeolite on conversion of ethanol to propylene [J ] . Applied Catalysis A: General , 2011 , 399 ( 1 ): 262 - 267 .
XIA W , WANG F F , MU X C , et al . Transformation of ethanol to propylene on ZrO 2 catalysts: Effect of reaction conditions on the catalytic performance [J ] . Reaction Kinetics, Mechanisms and Catalysis , 2017 , 122 : 1 - 10 .
XIA W , WANG X , LI S S , et al . Multiple synergistic roles of Zr modification on ZSM-5 in performant and stable catalyst for ethanol conversion to propene [J ] . Energy , 2024 , 288 : 129910 .
陈全鑫 , 窦洪鑫 , 闫冰 , 等 . CO 2 氧化1-丁烯脱氢制1,3-丁二烯活性炭负载铁基催化剂的研究 [J ] . 天然气化工—C1化学与化工 , 2021 , 46 ( 1 ): 38 - 45 .
CHEN Q X , DOU H X , YAN B , et al . Study on activated carbon supported iron-based catalysts for oxidative dehydrogenation of 1-butene to 1,3-butadiene with CO 2 [J ] . Natural Gas Chemical Industry , 2021 , 46 ( 1 ): 38 - 45 .
WANG K Z , CHEN C , GAO W Z , et al . Green and rapid synthesis of hierarchical nano-sized pure Si-Beta zeolite supported with Zn and Y for effective synthesis of butadiene from aqueous ethanol [J ] . Chemical Engineering Journal , 2024 , 479 : 147780 .
HUANG X X , MEN Y , WANG J G , et al . Highly active and selective binary MgO-SiO 2 catalysts for the production of 1,3-butadiene from ethanol [J ] . Catalysis Science & Technology , 2017 , 7 ( 1 ): 168 - 180 .
CHUNG S H , MIGUEL J C N , LI T , et al . Core-shell structured magnesia-silica as a next generation catalyst for one-step ethanol-to-butadiene Lebedev process [J ] . Applied Catalysis B: Environment and Energy , 2024 , 344 : 123628 .
0
浏览量
0
下载量
0
CNKI被引量
- 网络PDF下载
- XML下载
- Meta-XML下载
- BibTeX下载
- Endnote下载
- RefMan 下载
- NoteExpress下载
- NoteFirst下载
关联资源
相关文章
相关作者
相关机构
- 地址：四川省成都市双流区西航港机场路近都段393号 邮编：610225
- 联系电话：028-85964717 Email：236764603@qq.com
- 技术支持由北京北大方正电子有限公司提供 蜀ICP备12008600号-10
蜀公网安备51012202001533 - 本系统建议在Chrome、 IE9+ 以上版本浏览器阅读本站内容，360浏览器请切换至极速模式
- Cookies帮助我们提供服务并提供个性化体验。使用本网站，即表示您同意我们使用Cookies
- 总访问量：378882 今日访问量：30
