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烷烃催化裂解制低碳烯烃催化剂研究进展
Research progress of catalysts in catalytic cracking of alkanes to light olefins
- 低碳化学与化工 2025, 50(4): 46-54.
- 作者机构：
1.伊犁新天煤化工有限责任公司，新疆 伊犁 835100
2.浙江省白马湖实验室有限公司，浙江 杭州 310051
- 作者简介：
杨卫红（1986—），本科，工程师，研究方向为煤制合成气产业发展与规划、煤化工废水处理，以及二氧化碳减量化和资源化利用，E-mail：2474496551@qq.com。
周林（1992—），博士，副研究员，研究方向为多孔材料制备与应用，E-mail：zhoulin1@zju.edu.cn。
- 基金信息：浙江省“尖兵领雁+X”研发攻关计划(2024SSYS0067);浙江省能源集团有限公司科学技术项目(ZNKJ-2023-118)
DOI：10.12434/j.issn.2097-2547.20240331
中图分类号： TQ426收稿：2024-08-12，
修回：2024-09-04，
纸质出版：2025-04-25
- 稿件说明：
移动端阅览
杨卫红,赖颖峰,段金娣等.烷烃催化裂解制低碳烯烃催化剂研究进展[J].低碳化学与化工,2025,50(04):46-54.
YANG Weihong,LAI Yingfeng,DUAN Jindi,et al.Research progress of catalysts in catalytic cracking of alkanes to light olefins[J].Low-Carbon Chemistry and Chemical Engineering,2025,50(04):46-54.
杨卫红,赖颖峰,段金娣等.烷烃催化裂解制低碳烯烃催化剂研究进展[J].低碳化学与化工,2025,50(04):46-54. DOI： 10.12434/j.issn.2097-2547.20240331.
YANG Weihong,LAI Yingfeng,DUAN Jindi,et al.Research progress of catalysts in catalytic cracking of alkanes to light olefins[J].Low-Carbon Chemistry and Chemical Engineering,2025,50(04):46-54. DOI： 10.12434/j.issn.2097-2547.20240331.
摘要
低碳烯烃作为重要的基础化工原料，其需求日益增长。烷烃催化裂解是制备低碳烯烃的主要途径之一。对烷烃催化裂解制备低碳烯烃的反应机理（碳正离子机理和自由基机理）进行了总结，对该反应使用的催化剂（分子筛、金属氧化物和双功能催化剂）的研究进展进行了分析，并对烷烃催化裂解制低碳烯烃催化剂未来发展和优化方向进行了展望。
Abstract
As essential feedstocks in the chemical industry
the demand for light olefins is steadily increasing. Cracking of alkanes is one of the main routes to obtain light olefins. The reaction mechanisms (carbocation and free radical mechanisms) involved in the catalytic cracking of alkanes to light olefins were summarized. The research progress of catalysts (molecular sieves
metal oxides
and bifunctional catalysts) utilized for the reaction were analyzed. Furthermore
future directions for the development and optimization of catalysts for alkane catalytic cracking to light olefins were prospected.
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Keywords
references
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