费托合成油中含氧化合物的萃取脱除萃取剂及工艺研究进展

褚悦辛; 张先明; 冀国俊

doi:10.12434/j.issn.2097-2547.20240304

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费托合成油中含氧化合物的萃取脱除萃取剂及工艺研究进展

绿色低碳化工技术

- 费托合成油中含氧化合物的萃取脱除萃取剂及工艺研究进展
- Research progress on extractants and processes for removal of oxygenated compounds from Fischer-Tropsch synthetic oil
- 低碳化学与化工 2025, 50(1): 76-86.
- 作者机构：
  
  1.内蒙古工业大学化工学院，内蒙古呼和浩特 010051
  2.鄂尔多斯应用技术学院，内蒙古鄂尔多斯 017000
- 作者简介：
  
  褚悦辛（2001—），硕士研究生，研究方向为煤基新材料，E-mail：2480405808@qq.com。
  张先明（1984—），博士，教授，研究方向为煤基新材料，E-mail：zhangxianming84@163.com。
- 基金信息：
  
  内蒙古自治区自然科学基金(2022QN02008);内蒙古自治区高等学校科学技术研究重点项目(NJZZ21056);鄂尔多斯市科技计划(2022YY034)
- DOI：10.12434/j.issn.2097-2547.20240304
  中图分类号： TQ028.3
- 纸质出版日期：2025-01-25，
  
  收稿日期：2024-07-18，
  
  修回日期：2024-08-06，
- 稿件说明：
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褚悦辛, 张先明, 冀国俊. 费托合成油中含氧化合物的萃取脱除萃取剂及工艺研究进展[J]. 低碳化学与化工, 2025,50(1):76-86.

CHU YUEXIN, ZHANG XIANMING, JI GUOJUN. Research progress on extractants and processes for removal of oxygenated compounds from Fischer-Tropsch synthetic oil. [J]. Low-carbon chemistry and chemical engineering, 2025, 50(1): 76-86.
褚悦辛, 张先明, 冀国俊. 费托合成油中含氧化合物的萃取脱除萃取剂及工艺研究进展[J]. 低碳化学与化工, 2025,50(1):76-86. DOI： 10.12434/j.issn.2097-2547.20240304.

CHU YUEXIN, ZHANG XIANMING, JI GUOJUN. Research progress on extractants and processes for removal of oxygenated compounds from Fischer-Tropsch synthetic oil. [J]. Low-carbon chemistry and chemical engineering, 2025, 50(1): 76-86. DOI： 10.12434/j.issn.2097-2547.20240304.

摘要

脱除含氧化合物是费托合成油高值化利用亟待解决的问题之一。综述了萃取法脱除费托合成油中含氧化合物的研究进展。首先总结了各类萃取剂的萃取性能及可能存在的问题，包括砜类、醇类、胺类和酯类化合物等传统溶剂，以及离子液体和低共熔溶剂等新型溶剂。然后简述了液液萃取和萃取精馏等适用于脱除费托合成油中含氧化合物的工艺流程。最后对萃取脱除费托合成油中含氧化合物进行了总结和展望，以期为相关技术的研究和工业化应用提供参考。

Abstract

The removal of oxygenated compounds is one of the critical challenges for the high-value utilization of Fischer-Tropsch (F-T) synthetic oil. The research progress on the extraction-based removal of oxygenated compounds from F-T synthetic oil was summarized. Firstly

the extraction performance and potential issues of various extractants were discussed

including traditional solvents such as sulfone

alcohol

amine

and ester compounds

as well as novel solvents such as ionic liquids and deep eutectic solvents. Subsequently

process flows suitable for removing oxygenated compounds from F-T synthetic oil

such as liquid-liquid extraction and extractive distillation

were briefly introduced. Finally

a summary and outlook on the extraction-based removal of oxygenated compounds from F-T synthetic oil were provided

aiming to offer insights for research and industrial applications in related technologies.

关键词

费托合成油含氧化合物萃取离子液体低共熔溶剂

Keywords

Fischer-Tropsch synthetic oiloxygenated compoundsextractionionic liquidsdeep eutectic solvents

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