整体式催化剂在CO-PROX反应中的设计及应用研究进展

王晴; 李维国; 李智; 刘园园; 孙宗壮; 李晓旋; 脱永笑; 冯翔

doi:10.12434/j.issn.2097-2547.20240259

您当前的位置：

首页 >

文章列表页 >

整体式催化剂在CO-PROX反应中的设计及应用研究进展

绿色低碳化工技术 | 更新时间：2025-02-27

- 整体式催化剂在CO-PROX反应中的设计及应用研究进展
- Research progress on designs and applications of monolithic catalysts in CO-PROX reaction
- 低碳化学与化工 2025, 50(2): 100-112.
- 作者机构：
  
  1.中国石油大学（华东）化学化工学院，山东青岛 266580
  2.山东能源集团有限公司大型煤气化及煤基新材料国家工程研究中心，山东济南 273500
  3.中国石油大学（华东）新能源学院，山东青岛 266580
- 作者简介：
  
  王晴（2000—），硕士研究生，研究方向为CO-PROX整体催化剂开发，E-mail：s22030083@s.upc.edu.cn。
  脱永笑（1990—），博士，副教授，研究方向为氢能和工业催化，E-mail：yxtuo@upc.edu.cn；
  冯翔（1988—），博士，教授，研究方向为催化反应工程，E-mail：xiangfeng@upc.edu.cn。
- 基金信息：
  
  国家自然科学基金(22208374);山东能源集团有限公司科技创新项目(SNKJ2021BJ05);中国石油科技创新基金(2022DQ02-0607)
- DOI：10.12434/j.issn.2097-2547.20240259
  中图分类号： TQ03
- 收稿日期：2024-06-13，
  
  修回日期：2024-08-30，
  
  纸质出版日期：2025-02-25
- 稿件说明：
移动端阅览
王晴,李维国,李智等.整体式催化剂在CO-PROX反应中的设计及应用研究进展[J].低碳化学与化工,2025,50(02):100-112.

WANG Qing,LI Weiguo,LI Zhi,et al.Research progress on designs and applications of monolithic catalysts in CO-PROX reaction[J].Low-carbon Chemistry and Chemical Engineering,2025,50(02):100-112.
王晴,李维国,李智等.整体式催化剂在CO-PROX反应中的设计及应用研究进展[J].低碳化学与化工,2025,50(02):100-112. DOI： 10.12434/j.issn.2097-2547.20240259.

WANG Qing,LI Weiguo,LI Zhi,et al.Research progress on designs and applications of monolithic catalysts in CO-PROX reaction[J].Low-carbon Chemistry and Chemical Engineering,2025,50(02):100-112. DOI： 10.12434/j.issn.2097-2547.20240259.

摘要

CO优先氧化（CO-PROX）反应是燃料电池H

净化的关键步骤，对于提高燃料电池效率和减少有害排放具有重要意义。整体式催化剂因具有良好的热稳定性和抗聚集性、较低的压降、较高的机械强度和较好的传质传热特性而逐渐成为研究热点。综述了CO-PROX反应整体式催化剂（金属整体式催化剂、陶瓷整体式催化剂和3D打印聚合物整体式催化剂）的研究进展，重点分析了整体框架和催化剂涂层制备技术等对其催化性能的影响，并对比了不同类型CO-PROX反应整体式催化剂的优缺点。分析了CO-PROX反应整体式催化剂目前面临的挑战，并对其未来研究方向进行了展望。

Abstract

CO preferential oxidation (CO-PROX) reaction is a key step in H

purification of fuel cells

which is of great significance to improve the efficiency of fuel cells and reduce harmful emissions. Monolithic catalysts with good thermal stability and anti-aggregation

low pressure drop

high mechanical strength and good mass and heat transfer characteristics have gradually become the focus of research. Research progress on monolithic catalysts (metal monolithic catalysts

ceramic monolithic catalysts and 3D printed polymer monolithic catalysts) in CO-PROX reaction was reviewed

wit

h the focus on analyzing the effects of monolithic frames and catalyst coating preparation techniques on their catalytic performances. And the advantages and disadvantages of different types of CO-PROX reaction monolithic catalysts were compared. The current challenges faced by CO-PROX reaction monolithic catalysts were analyzed and their future research directions were prospected.

关键词

Keywords

references

BAROUTAJI A , ARJUNAN A , ROBINSON J , et al . PEMFC poly-generation systems: Developments, merits, and challenges [J ] . Sustainability , 2021 , 13 ( 21 ): 11696 - 11727 .

LI Y , WANG X , WANG Y , et al . The decisive role of adsorbed OH* in low-potential CO electro-oxidation on single-atom catalytic sites [J ] . Carbon Energy , 2023 , 5 ( 9 ): e310 .

李佩佩 , 翟燕萍 , 王先鹏 , 等 . 浅谈氢气提纯方法的选取 [J ] . 天然气化工—C1化学与化工 , 2020 , 45 ( 3 ): 115 - 119 .

LI P P , ZHAl Y P , WANG X P , et al . Brief discussion on the selection of hydrogen purification methods [J ] . Natural Gas Chemical Industry , 2020 , 45 ( 3 ): 115 - 119 .

LIU H M , LI D Z , GUO J W , et al . Recent advances on catalysts for preferential oxidation of CO [J ] . Nano Research , 2023 , 16 ( 4 ): 4399 - 4410 .

WEI K , WANG X , GE J J . Towards bridging thermo/electrocatalytic CO oxidation: From nanoparticles to single atoms [J ] . Chemical Society Reviews , 2024 , 17 ( 53 ): 8903 - 8948 .

WU D Q , JIANG Y X , ZHANG C H , et al . Synergistic metal-support interaction promoting the formation of oxygen vacancies and their role in CO-PROX over CuO/NiO-CeO 2 catalyst [J ] . Journal of Environmental Chemical Engineering , 2024 , 12 ( 1 ): 111818 .

YU J , YANG Y S , ZHANG M , et al . Highly active MnCoO x catalyst toward CO preferential oxidation [J ] . ACS Catalysis , 2024 , 14 ( 3 ): 1281 - 1291 .

ROSSO I , GALLETTI C , SARACCO G , et al . Development of a zeolites-supported noble-metal catalysts for CO preferential oxidation: H 2 gas purification for fuel cell [J ] . Applied Catalysis B: Environmental , 2004 , 48 ( 3 ): 195 - 203 .

MALWADKAR S , BERA P , SATYANARAYANA C V V . Influence of cobalt on performance of Cu-CeO 2 catalysts for preferential oxidation of CO [J ] . Journal of Rare Earths , 2020 , 38 ( 9 ): 941 - 950 .

CYBULSKI A , MOULIJN J A . Monoliths in heterogeneous catalysis [J ] . Catalysis Reviews , 1994 , 36 ( 2 ): 179 - 270 .

ROY S , BAUER T , AL-DAHHAN M , et al . Monoliths as multiphase reactors: A review [J ] . AIChE Journal , 2004 , 50 ( 11 ): 2918 - 2938 .

GIROUX T , HWANG S , LIU Y , et al . Monolithic structures as alternatives to particulate catalysts for the reforming of hydrocarbons for hydrogen generation [J ] . Applied Catalysis B: Environmental , 2005 , 56 ( 1/2 ): 95 - 110 .

MOULIJN J A , KREUTZER M T , NIJHUIS T A , et al . Monolithic catalysts and reactors [M ] . Netherlands : Elsevier , 2011 .

GOVENDER S , FRIEDRICH H B . Monoliths: A review of the basics, preparation methods and their relevance to oxidation [J ] . Catalysts , 2017 , 7 ( 2 ): 62 - 81 .

LIU X D , LV C , LIU B S , et al . Digital light processing 3D printing of porous ceramics based on multi-materials additive manufacturing [J ] . Chinese Journal of Structural Chemistry , 2023 , 42 ( 7 ): 100106 - 100109 .

ZHU J , WU P W , CHAO Y H , et al . Recent advances in 3D printing for catalytic applications [J ] . Chemical Engineering Journal , 2022 , 433 ( 2 ): 134341 - 134359 .

MARTINS R . Materials as activator of future global science and technology challenges [J ] . Progress in Natural Science: Materials International , 2021 , 31 ( 6 ): 785 - 791 .

张庆生，黄雪松 . 国内外氢能产业政策与技术经济性分析 [J ] . 低碳化学与化工 , 2023 , 48 ( 2 ): 134 - 139 .

ZHANG Q S , HUANG X S . Analysis of domestic and foreign hydrogen energy industrial policies and technical economy [J ] . Low-Carbon Chemistry and Chemical Engineering , 2023 , 48 ( 2 ): 133 - 139 .

AVILA P , MONTES M , MIRÓ E E . Monolithic reactors for environmental applications: A review on preparation technologies [J ] . Chemical Engineering Journal , 2005 , 109 ( 1/2/3 ): 11 - 36 .

MITRA B , KUNZRU D . Washcoating of different zeolites on cordierite monoliths [J ] . Journal of the American Ceramic Society , 2008 , 91 ( 1 ): 64 - 70 .

FARRAUTO R J , LIU Y , RUETTINGER W , et al . Precious metal catalysts supported on ceramic and metal monolithic structures for the hydrogen economy [J ] . Catalysis Reviews , 2007 , 49 ( 2 ): 141 - 196 .

FU K X , SU Y , ZHENG Y F , et al . Novel monolithic catalysts for VOCs removal: A review on preparation, carrier and energy supply [J ] . Chemosphere , 2022 , 308 ( 2 ): 136256 - 1136268 .

张悦 , 高艳珊 , 黎哲 , 等 . VOCs氧化整体式催化剂研究进展 [J ] . 科学通报 , 2024 , 69 ( 16 ): 2185 - 2202 .

ZHANG Y , GAO Y S , LI Z , et al . Research progress of monolithic catalysts for VOCs oxidation [J ] . Chinese Science Bulletin , 2024 , 69 ( 16 ): 2185 - 2202 .

ZENG S H , LIU Y , WANG Y Q . CuO-CeO 2 /Al 2 O 3 /FeCrAl monolithic catalysts prepared by sol-pyrolysis method for preferential oxidation of carbon monoxide [J ] . Catalysis Letters , 2007 , 117 ( 4 ): 119 - 125 .

ZENG S H , SU H Q , LIU Y , et al . CuO-CeO 2 /Al 2 O 3 /FeCrAl monolithic catalysts prepared by in situ combustion synthesis method for preferential oxidation of carbon monoxide [J ] . Journal of Rare Earths , 2011 , 29 ( 1 ): 69 - 73 .

WU D F , ZHANG Y H , LI Y D . Mechanical stability of monolithic catalysts: Improving washcoat adhesion by FeCrAl alloy substrate treatment [J ] . Journal of Industrial and Engineering Chemistry , 2017 , 56 ( 2 ): 175 - 184 .

DOMÍNGUEZ M I , PÉREZ A , CENTENO M A , et al . Metallic structured catalysts: Influence of the substrate on the catalytic activity [J ] . Applied Catalysis A: General , 2014 , 478 ( 2 ): 45 - 57 .

LI H L , YU X H , TU S T , et al . Catalytic performance and characterization of Al 2 O 3 -supported Pt-Co catalyst coatings for preferential CO oxidation in a micro-reactor [J ] . Applied Catalysis A: General , 2010 , 387 ( 1-2 ): 215 - 223 .

YU X H , YU W , LI H L , et al . Preparation, characterization and application of K-PtCo/Al 2 O 3 catalyst coatings for preferential CO oxidation [J ] . Applied Catalysis B: Environmental , 2013 , 140 : 588 - 597 .

YAO X Q , WANG L , LI C D , et al . K-PtCo/Al 2 O 3 via ball milling as an efficient catalyst for preferential oxidation of CO towards hydrogen purification [J ] . Chemical Engineering Journal , 2023 , 477 : 146957 .

CHIN P , SUN X L , ROBERTS G W , et al . Preferential oxidation of carbon monoxide with iron-promoted platinum catalysts supported on metal foams [J ] . Applied Catalysis A: General , 2006 , 302 ( 1 ): 22 - 31 .

PENG P Y , JIN I , YANG T C K , et al . Facile preparation of hierarchical CuO-CeO 2 /Ni metal foam composite for preferential oxidation of CO in hydrogen-rich gas [J ] . Chemical Engineering Journal , 2014 , 251 ( 2 ): 228 - 235 .

YAN C F , HAI H , GUO C Q , et al . Hydrogen production by steam reforming of dimethyl ether and CO-PROX in a metal foam micro-reactor [J ] . International Journal of Hydrogen Energy , 2014 , 39 ( 20 ): 10409 - 10416 .

CHEN G W , YUAN Q , LI H Q , et al . CO selective oxidation in a microchannel reactor for PEM fuel cell [J ] . Chemical Engineering Journal , 2004 , 101 ( 1/2/3 ): 101 - 106 .

KIM K Y , NAM S W , HAN J , et al . Development of a multi-layered micro-reactor coated with Pt-Co/Al 2 O 3 catalyst for preferential oxidation of CO [J ] . Journal of Industrial and Engineering Chemistry , 2008 , 14 ( 6 ): 853 - 859 .

KIM K Y , HAN J , NAM S W , et al . Preferential oxidation of CO over CuO/CeO 2 and Pt-Co/Al 2 O 3 catalysts in micro-channel reactors [J ] . Catalysis Today , 2008 , 131 ( 1/2/3/4 ): 431 - 436 .

YU X H , LI H L , TU S T , et al . Pt-Co catalyst-coated channel plate reactor for preferential CO oxidation [J ] . International Journal of Hydrogen Energy , 2011 , 36 ( 5 ): 3778 - 3788 .

GÖRKE O , PFEIFER P . Preferential CO oxidation over a platinum ceria alumina catalyst in a microchannel reactor [J ] . International Journal of Hydrogen Energy , 2011 , 36 ( 8 ): 4673 - 4681 .

ATES A , PFEIFER P , GÖRKE O . Thin-film catalytic coating of a microreactor for preferential CO oxidation over Pt catalysts [J ] . Chemie Ingenieur Technik , 2013 , 85 ( 5 ): 664 - 672 .

SNYTNIKOV P V , POPOVA M M , MEN Y , et al . Preferential CO oxidation over a copper-cerium oxide catalyst in a microchannel reactor [J ] . Applied Catalysis A: General , 2008 , 350 ( 1 ): 53 - 62 .

CRUZ S , SANZ O , POYATO R , et al . Design and testing of a microchannel reactor for the PROX reaction [J ] . Chemical Engineering Journal , 2011 , 167 ( 2/3 ): 634 - 642 .

GALLETTI C , SPECCHIA S , SARACCO G , et al . Development of a lab scale catalytic metal plate-channels reactor for CO preferential oxidation [J ] . Chemical Engineering Journal , 2009 , 154 ( 1/2/3 ): 246 - 250 .

LAGUNA O H , GONZÁLEZ C M , CENTENO M A , et al . Microreactors technology for hydrogen purification: Effect of the catalytic layer thickness on CuO /CeO 2 -coated microchannel reactors for the PROX reaction [J ] . Chemical Engineering Journal , 2015 , 275 ( 2 ): 45 - 52 .

PÉREZ N C , MIRÓ E E , ZAMARO J M . Microreactors based on CuO-CeO 2 /zeolite films synthesized onto brass microgrids for the oxidation of CO [J ] . Applied Catalysis B: Environmental , 2013 , 129 ( 2 ): 416 - 425 .

JING G J , ZHANG X J , ZHANG A A , et al . CeO 2 -CuO/Cu 2 O/Cu monolithic catalysts with three-kind morphologies Cu 2 O layers for preferential CO oxidation [J ] . Applied Surface Science , 2018 , 434 ( 2 ): 445 - 451 .

ZHOU S L , YUAN Z S , WANG S D . Selective CO oxidation with real methanol reformate over monolithic Pt group catalysts: PEMFC applications [J ] . International Journal of Hydrogen Energy , 2006 , 31 ( 7 ): 924 - 933 .

周帅林 , 袁中山 , 王树东 . Pt/Al 2 O 3 整体催化剂上选择性氧化脱除甲醇重整氢源中CO—副反应对CO脱除效果的影响分析 [J ] . 燃料化学学报 , 2005 , 33 ( 5 ): 637 - 640 .

ZHOU S L , YUAN Z S , WANG S D . Selective CO oxidation in hydrogenrich gas from methanol reforming over the Pt/Al 2 O 3 monolithic catalyst—Analysis of the effect of side reactions [J ] . Journal of Fuel Chemistry and Technology , 2005 , 33 ( 5 ): 638 - 640 .

HUANG C Y , CHEN Y Y , SU C C , et al . The cleanup of CO in hydrogen for PEMFC applications using Pt, Ru, Co, and Fe in PROX reaction [J ] . Journal of Power Sources , 2007 , 174 ( 1 ): 294 - 301 .

KOROTKIKH O , FARRAUTO R . Selective catalytic oxidation of CO in H 2 : Fuel cell applications [J ] . Catalysis Today , 2000 , 62 ( 2/3 ): 249 - 254 .

ROBERTS G W , CHIN P , SUN X , et al . Preferential oxidation of carbon monoxide with Pt/Fe monolithic catalysts: Interactions between external transport and the reverse water-gas-shift reaction [J ] . Applied Catalysis B: Environmental , 2003 , 46 ( 3 ): 601 - 611 .

GÓMEZ L E , SOLLIER B M , LACOSTE A M , et al . Hydrogen purification for fuel cells through CO preferential oxidation using PtCu/Al 2 O 3 structured catalysts [J ] . Journal of Environmental Chemical Engineering , 2019 , 7 ( 5 ): 103376 - 103386 .

ZHANG Q L , SHORE L , FARRAUTO R J . Selective CO oxidation over a commercial PROX monolith catalyst for hydrogen fuel cell applications [J ] . International Journal of Hydrogen Energy , 2012 , 37 ( 14 ): 10874 - 10880 .

MAEDA N , MATSUSHIMA T , UCHIDA H , et al . Performance of Pt-Fe/mordenite monolithic catalysts for preferential oxidation of carbon monoxide in a reformate gas for PEFCs [J ] . Applied Catalysis A: General , 2008 , 341 ( 1/2 ): 93 - 97 .

MAEDA N , MATSUSHIMA T , KOTOBUKI M , et al . H 2 O-tolerant monolithic catalysts for preferential oxidation of carbon monoxide in the presence of hydrogen [J ] . Applied Catalysis A: General , 2009 , 370 ( 1 ): 50 - 53 .

NERI G , RIZZO G , CORIGLIANO F , et al . A novel Pt/zeolite-based honeycomb catalyst for selective CO oxidation in a H 2 -rich mixture [J ] . Catalysis Today , 2009 , 147 ( 2 ): S210 - S214 .

MORENO M S , LÓPEZ E , ADROVER M E , et al . CO-PROX over nano-Au/TiO 2 : Monolithic catalyst performance and empirical kinetic model fitting [J ] . International Journal of Hydrogen Energy , 2016 , 41 ( 47 ): 22043 - 22054 .

CIFUENTES B , CIFUENTES A , BUSTAMANTE F , et al . Monoliths washcoated with AuCu catalysts for CO removal in an ethanol fuel processor: Effect of CeO 2 -SiO 2 dual support on the catalytic performance and reactor cost [J ] . International Journal of Hydrogen Energy , 2021 , 46 ( 2 ): 2166 - 2181 .

GÓMEZ L E , TISCORNIA I S , BOIX A V , et al . Co/ZrO 2 catalysts coated on cordierite monoliths for CO preferential oxidation [J ] . Applied Catalysis A: General , 2011 , 401 ( 1/2 ): 124 - 133 .

GÓMEZ L E , TISCORNIA I S , BOIX A V , et al . CO preferential oxidation on cordierite monoliths coated with Co/CeO 2 catalysts [J ] . International Journal of Hydrogen Energy , 2012 , 37 ( 19 ): 14812 - 14819 .

赵福真 , 曾鹏辉 , 季生福 . Cu x Ce 1- x O 2- x /SBA-15/堇青石整体式催化剂及其CO催化氧化性能 [J ] . 无机化学学报 , 2013 , 29 ( 4 ): 753 - 759 .

ZHAO F Z , ZENG P H , JI S F . Preparation, characterization and CO catalytic oxidation performance of Cu x Ce 1- x O 2- x /SBA-15/cordierite monolithic catalysts [J ] . Chinese Journal of Inorganic Chemistry , 2013 , 29 ( 4 ): 753 - 759 .

LACOSTE A M , TISCORNIA I S , BOIX A V . CO preferential oxidation on cordierite monoliths coated with CuO-CeO 2 /SBA-15 catalysts. Further insights into the physico-chemical aspects of the catalytic behavior [J ] . International Journal of Hydrogen Energy , 2018 , 43 ( 31 ): 14238 - 14251 .

TISCORNIA I S , LACOSTE A M , GÓMEZ L E , et al . CuO-CeO 2 /SiO 2 coating on ceramic monolith: Effect of the nature of the catalyst support on CO preferential oxidation in a H 2 -rich stream [J ] . International Journal of Hydrogen Energy , 2020 , 45 ( 11 ): 6636 - 6650 .

AYASTUY J L , GAMBOA N K , GONZÁLEZ-MARCOS M P , et al . CuO/CeO 2 washcoated ceramic monoliths for CO-PROX reaction [J ] . Chemical Engineering Journal , 2011 , 171 ( 1 ): 224 - 231 .

BARBATO P S , DI BENEDETTO A , LANDI G , et al . CuO/CeO 2 based monoliths for CO preferential oxidation in H 2 -rich streams [J ] . Chemical Engineering Journal , 2015 , 279 ( 2 ): 983 - 993 .

BARBATO P S , DI BENEDETTO A , LANDI G , et al . Structuring CuO/CeO 2 catalyst as option to improve performance towards CO-PROX [J ] . Topics in Catalysis , 2016 , 59 ( 15 ): 1371 - 1382 .

LANDI G , BARBATO P S , DI BENEDETTO A , et al . Optimization of t he preparation method of CuO/CeO 2 structured catalytic monolith for CO preferential oxidation in H 2 -rich streams [J ] . Applied Catalysis B: Environmental , 2016 , 181 ( 2 ): 727 - 737 .

DI BENEDETTO A , LANDI G , LISI L . CO reactive adsorption at low temperature over CuO/CeO 2 structured catalytic monolith [J ] . International Journal of Hydrogen Energy , 2017 , 42 ( 17 ): 12262 - 12275 .

LANDI G , BENEDETTO A D , LISI L . Two-stage strategy for CO removal from H 2 -rich streams over (nano-) CuO/CeO 2 structured catalyst at low temperature [J ] . Applied Sciences , 2018 , 8 ( 5 ): 789 - 812 .

WU D F , KONG S S , ZHANG H , et al . Mechanical stability of monolithic catalysts: Factors affecting washcoat adhesion and cohesion during preparation [J ] . AIChE Journal , 2014 , 60 ( 8 ): 2765 - 2773 .

MEISSNER J , AHRENS L , PASEL J , et al . An improved preparation method for a CuO/CeO 2 -coated monolith for the CO-PROX reaction [J ] . Scientific Reports , 2023 , 13 ( 1 ): 9345 - 9355 .

DAVÓ-QUIÑONERO A , SOROLLA-ROSARIO D , BAILÓN-GARCÍA E , et al . Improved asymmetrical honeycomb monolith catalyst prepared using a 3D printed template [J ] . Journal of Hazardous Materials , 2019 , 368 ( 2 ): 638 - 643 .

CHAPARRO-GARNICA C Y , DAVÓ-QUIÑONERO A , BAILÓN-GARCÍA E , et al . Design of monolithic supports by 3D printing for its application in the preferential oxidation of CO (CO-PROX) [J ] . ACS Applied Materials & Interfaces , 2019 , 11 ( 40 ): 36763 - 36773 .

CHAPARRO-GARNICA C Y , JORDÁ-FAUS P , BAILÓN-GARCÍA E , et al . Customizable heterogeneous catalysts: Nonchanneled advanced monolithic supports manufactured by 3D-printing for improved active phase coating performance [J ] . ACS Applied Materials & Interfaces , 2020 , 12 ( 49 ): 54573 - 54584 .

AGUILAR-MADERA C G , OCAMPO-PÉREZ R , BAILÓN-GARCÍA E , et al . Mathematical modeling of preferential CO oxidation reactions under advection—Diffusion conditions in a 3D-printed reactive monolith [J ] . Industrial & Engineering Chemistry Research , 2021 , 60 ( 31 ): 11689 - 11698 .

CHAPARRO-GARNICA C Y , BAILÓN-GARCÍA E , LOZANO-CASTELLÓ D , et al . Design and fabrication of integral carbon monoliths combining 3D printing and sol-gel polymerization: Effects of the channel morphology on the CO-PROX reaction [J ] . Catalysis Science & Technology , 2021 , 11 ( 19 ): 6490 - 6497 .

CHAPARRO-GARNICA C Y , BAILÓN-GARCÍA E , DAVÓ-QUIÑONERO A , et al . Sponge-like carbon monoliths: Porosity control of 3D-printed carbon supports and its influence on the catalytic performance [J ] . Chemical Engineering Journal , 2022 , 432 ( 2 ): 134218 - 134228 .

浏览量

下载量

CNKI被引量

文章被引用时，请邮件提醒。

提交

工具集

关联资源

暂无数据