<italic style="font-style: italic">x</italic>ZnO-CaO催化乙酸甲酯和丙二醇甲醚合成丙二醇甲醚醋酸酯

吴志鹏; 李宇斌; 刘相洋; 闫晓亮

doi:10.12434/j.issn.2097-2547.20240222

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xZnO-CaO催化乙酸甲酯和丙二醇甲醚合成丙二醇甲醚醋酸酯

低碳分子转化合成 | 更新时间：2025-04-27

- xZnO-CaO催化乙酸甲酯和丙二醇甲醚合成丙二醇甲醚醋酸酯
- 暂无标题
- 低碳化学与化工 2025, 50(4): 55-63.
- 作者机构：
  
  1.太原理工大学化学工程与技术学院，山西太原 030024
  2.太原理工大学省部共建煤基能源清洁高效利用国家重点实验室，山西太原 030024
- 作者简介：
  
  吴志鹏（1997—），硕士研究生，研究方向为钙基催化剂，E-mail：2657099471@qq.com。
  闫晓亮（1985—），博士，教授，研究方向为多相催化剂，E-mail：yanxiaoliang@tyut.edu.cn。
- 基金信息：
  
  国家自然科学基金(22278286);中国石油化工集团有限公司项目(122027)
- DOI：10.12434/j.issn.2097-2547.20240222
  中图分类号： TQ203.2
- 收稿日期：2024-05-21，
  
  修回日期：2024-06-03，
  
  纸质出版日期：2025-04-25
- 稿件说明：
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吴志鹏,李宇斌,刘相洋等.xZnO-CaO催化乙酸甲酯和丙二醇甲醚合成丙二醇甲醚醋酸酯[J].低碳化学与化工,2025,50(04):55-63.

WU Zhipeng,LI Yubin,LIU Xiangyang,et al.Synthesis of propylene glycol methyl ether acetate from methyl acetate and propylene glycol methyl ether catalyzed by xZnO-CaO[J].Low-Carbon Chemistry and Chemical Engineering,2025,50(04):55-63.
吴志鹏,李宇斌,刘相洋等.xZnO-CaO催化乙酸甲酯和丙二醇甲醚合成丙二醇甲醚醋酸酯[J].低碳化学与化工,2025,50(04):55-63. DOI： 10.12434/j.issn.2097-2547.20240222.

WU Zhipeng,LI Yubin,LIU Xiangyang,et al.Synthesis of propylene glycol methyl ether acetate from methyl acetate and propylene glycol methyl ether catalyzed by xZnO-CaO[J].Low-Carbon Chemistry and Chemical Engineering,2025,50(04):55-63. DOI： 10.12434/j.issn.2097-2547.20240222.

摘要

调控碱性强度是提高CaO基催化剂酯交换反应催化性能的重要方法之一。采用等体积浸渍法制备了不同ZnO质量分数的ZnO-CaO催化剂（

ZnO-CaO），并应用于乙酸甲酯与丙二醇甲醚酯交换反应。通过XRD和SEM等表征了

ZnO-CaO的物相组成和微观形貌等，利用CO

-TPD研究了ZnO质量分数对

ZnO-CaO碱性强度的影响，采用单因素分析法优化了酯交换反应条件。结果表明，ZnO质量分数为5%的ZnO-CaO催化剂（5ZnO-CaO）具有适宜的碱性强度并表现出较好的催化性能，在

(乙酸甲酯)/

(丙二醇甲醚)为10、反应温度为160 ℃和催化剂用量为0.100 g的条件下反应2 h，其丙二醇甲醚转化率和丙二醇甲醚醋酸酯选择性分别为70.0%和大于98.0%。活性相CaO转化为非活性相Ca(AC)

或Ca(AC)

·0.5H

O是导致催化剂失活的主要原因。失活5ZnO-CaO可通过焙烧获得再生，再生5ZnO-CaO在前述反应条件下的丙二醇甲醚转化率为69.5%。

Abstract

Adjusting alkaline strength is one

of the important methods to improve the transesterification catalytic performances of CaO-based catalysts. ZnO-CaO catalysts with different ZnO mass fractions (

ZnO-CaO) were prepared by equal volume impregnation method and applied to transesterification of methyl acetate and propylene glycol methyl ether. The phase compositions and micro-morphologies of

ZnO-CaO were characterized by XRD and SEM

etc

. The effects of ZnO mass fractions on

ZnO-CaO’s alkaline strengths were studied by CO

-TPD. The transesterification conditions were optimized by single factor analysis method. The results show that the ZnO-CaO catalyst with ZnO mass fraction of 5% (5ZnO-CaO) has suitable alkaline strength and good catalytic performance. Under the conditions of

(methyl acetate)/

(propylene glycol methyl ether) of 10

reaction temperature of 160 °C

catalyst dosage of 0.100 g and reaction time of 2 h

the propylene glycol methyl ether conversion rate and propylene glycol methyl ether acetate selectivity of 5ZnO-CaO are 70.0% and greater than 98.0%

respectively. The conversion of active phase CaO to inactive phase Ca(AC)

or Ca(AC)

·0.5H

O is the main cause of catalyst deactivation. The deactivated 5ZnO-CaO can be regenerated by roasting

and propylene glycol methyl ether conversion rate of the regenerated 5ZnO-CaO is 69.5% under the above-mentioned reaction conditions.

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references

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DOI：10.12434/j.issn.2097-2547.20240222

摘要

Abstract

关键词

Keywords

references