热催化CO<sub>2</sub>加氢制烯烃催化剂研究进展

李华勇; 邢小芳; 林世源; 王阳; 吴明铂

doi:10.12434/j.issn.2097-2547.20240197

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热催化CO₂加氢制烯烃催化剂研究进展

C1化学与催化转化 | 更新时间：2025-02-27

- 热催化CO₂加氢制烯烃催化剂研究进展
- Research progress on catalysts for thermal catalytic CO₂ hydrogenation to olefins
- 低碳化学与化工 2025, 50(2): 1-14.
- 作者机构：
  
  1.中国石油大学（华东）新能源学院，化学化工学院，山东青岛 266580
  2.贝欧亿（山东）新材料有限公司，山东滨州 256500
- 作者简介：
  
  李华勇（2000—），硕士研究生，研究方向为CO2加氢催化剂设计，E-mail：z22030015@s.upc.edu.cn。
  王阳（1991—），博士，副教授，研究方向为碳基催化材料及碳一小分子转化，E-mail：wangyang@upc.edu.cn；
  吴明铂（1972—），博士，教授，研究方向为新型碳材料开发及应用，E-mail：wumb@upc.edu.cn。
- 基金信息：
  
  国家自然科学基金(22108310);国家重点研发计划(2023YFB4104500);山东能源集团科技创新重大项目(SNKJ2023A03)
- DOI：10.12434/j.issn.2097-2547.20240197
  中图分类号： TQ426.94
- 收稿日期：2024-05-06，
  
  修回日期：2024-06-04，
  
  纸质出版日期：2025-02-25
- 稿件说明：
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李华勇,邢小芳,林世源等.热催化CO₂加氢制烯烃催化剂研究进展[J].低碳化学与化工,2025,50(02):1-14.

LI Huayong,XING Xiaofang,LIN Shiyuan,et al.Research progress on catalysts for thermal catalytic CO₂ hydrogenation to olefins[J].Low-carbon Chemistry and Chemical Engineering,2025,50(02):1-14.
李华勇,邢小芳,林世源等.热催化CO₂加氢制烯烃催化剂研究进展[J].低碳化学与化工,2025,50(02):1-14. DOI： 10.12434/j.issn.2097-2547.20240197.

LI Huayong,XING Xiaofang,LIN Shiyuan,et al.Research progress on catalysts for thermal catalytic CO₂ hydrogenation to olefins[J].Low-carbon Chemistry and Chemical Engineering,2025,50(02):1-14. DOI： 10.12434/j.issn.2097-2547.20240197.

摘要

化石燃料大量消耗造成的碳排放导致大气中CO

浓度剧增，引起了一系列严峻的环境问题。捕集CO

并将其转化为高值化学品是重要的减碳途径之一。热催化CO

加氢制烯烃因其优异的CO

转化效率和产物产率而备受关注。改进费托路径和甲醇中间体路径是目前的主流工艺，前者主要基于Fe基催化剂，后者主要基于金属氧化物/分子筛复合催化剂。首先总结了近年来热催化CO

加氢制烯烃催化剂的研究进展，包括不同反应路径的反应机理、催化剂物化性质的调控策略

，以及影响烯烃合成性能的关键因素。其次对CO

加氢制烯烃工艺的应用前景进行了展望，以期为该领域的研究提供参考。

Abstract

Carbon emissions from the excessive consumption of fossil fuels have led to a significant increase in atmospheric CO

concentrations

causing a series of severe environmental issues. Capturing and converting CO

into high-value chemicals is one of the key pathways for carbon reduction. Thermal catalytic CO

hydrogenation to olefins has attracted considerable attention due to its excellent CO

conversion efficiency and product yield. The modified Fischer-Tropsch route and the methanol intermediate route are the mainstream processes currently

with the former primarily based on Fe-based catalysts and the latter on metal oxide/molecular sieve composite catalysts. First

the recent research progress on catalysts for thermal catalytic CO

hydrogenation to olefins was summarized

including the reaction mechanisms of different routes

the strategies for regulating the physicochemical properties of catalysts and the key factors affecting olefin synthesis performance. Furthermore

the application prospects of CO

hydrogenation to olefins processes were discussed to provide a reference for research in the field.

关键词

Keywords

references

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载体对Fe基催化剂CO₂催化加氢制低碳烯烃性能的影响

铁基催化剂活性相调控及其催化CO₂加氢制线性α-烯烃研究进展

热催化CO2加氢制烯烃催化剂研究进展

Research progress on catalysts for thermal catalytic CO2 hydrogenation to olefins

DOI：10.12434/j.issn.2097-2547.20240197

摘要

Abstract

关键词

Keywords

references

热催化CO₂加氢制烯烃催化剂研究进展

Research progress on catalysts for thermal catalytic CO₂ hydrogenation to olefins