MOFs膜在氢氦甲烷分离和纯化工艺中的应用进展

张怡婷; 巨永林

doi:10.12434/j.issn.2097-2547.20240066

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MOFs膜在氢氦甲烷分离和纯化工艺中的应用进展

分离材料与净化技术

- MOFs膜在氢氦甲烷分离和纯化工艺中的应用进展
- Application progress of MOFs membranes in hydrogen helium methane separation and purification processes
- 低碳化学与化工 2024, 49(12): 68-78.
- 作者机构：
  
  上海交通大学制冷与低温工程研究所，上海 200240
- 作者简介：
  
  张怡婷（1999—），硕士研究生，研究方向为基于MOFs材料和低温精馏的高效氢氦甲烷提纯工艺，E-mail：zoeccrw@sjtu.edu.cn。
  巨永林（1970—），博士，教授，博士研究生导师，研究方向为新型低温制冷技术及液化天然气技术，E-mail：yju@sjtu.edu.cn。
- 基金信息：
- DOI：10.12434/j.issn.2097-2547.20240066
  中图分类号： TE645;TQ051.8
- 纸质出版日期：2024-12-25，
  
  收稿日期：2024-02-23，
  
  修回日期：2024-04-25，
- 稿件说明：
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张怡婷,巨永林.MOFs膜在氢氦甲烷分离和纯化工艺中的应用进展[J].低碳化学与化工,2024,49(12):68-78.

ZHANG Yiting,JU Yonglin.Application progress of MOFs membranes in hydrogen helium methane separation and purification processes[J].Low-carbon Chemistry and Chemical Engineering,2024,49(12):68-78.
张怡婷,巨永林.MOFs膜在氢氦甲烷分离和纯化工艺中的应用进展[J].低碳化学与化工,2024,49(12):68-78. DOI： 10.12434/j.issn.2097-2547.20240066.

ZHANG Yiting,JU Yonglin.Application progress of MOFs membranes in hydrogen helium methane separation and purification processes[J].Low-carbon Chemistry and Chemical Engineering,2024,49(12):68-78. DOI： 10.12434/j.issn.2097-2547.20240066.

摘要

金属有机框架（MOFs）材料具有高比表面积、可调孔隙性和高稳定性等良好特性，使得MOFs膜在气体吸附和分离领域具有良好的应用前景。然而，MOFs膜的工艺研究面临设计路线不明确和商业化落地难等问题，因此综述MOFs膜在氢气、氦气和甲烷分离和纯化技术中的研究进展及潜在应用具有重要意义。首先，介绍了MOFs材料的结构性质，以及分子模拟在MOFs材料筛选及性能预测中的应用；总结了实验制备的MOFs膜对氢气、氦气和甲烷的分离性能，包括材料的内部结构、分离机制、稳定性和适用工况。其次，鉴于MOFs膜在工业中的应用尚处起步阶段，探讨了其在含膜分离单元工艺中的可能应用，以及相关挑战和限制因素。再次，从MOFs膜对传统分离材料的替代，以及整体工艺向含膜工艺升级两方面，结合相关案例开展了经济性讨论，发现膜分离技术的引用升级具有可观的经济效益。最后，结合MOFs材料的优良特性，对未来该领域的研究工作进行了展望，旨在为MOFs膜在氢氦甲烷分离和纯化工艺中的应用提供参考。

Abstract

Metal-organic frameworks (MOFs) materials have great properties such as high specific surface area

adjustable porosity and high stability

so the MOFs membranes have excellent gas adsorption and desorption properties. However

current research on MOFs membrane processes faces challenges such as unclear design routes and difficulties in commercialization. Therefore

reviewing the research progress and potential applications of MOFs membranes in hydrogen

helium and methane separation and purification technologies are of significant importance. Firstly

the structural properties of MOFs materials and the application of molecular simulation in the selection and performance prediction of MOFs materials were introduced. Separation performances of MOFs membranes prepared experimentally for hydrogen

helium and methane were summarized

including the internal structure of the materials

separation mechanisms

stability

and applicable conditions. Secondly

considering that the industrial application of MOFs membranes is still in its early stages

the possible applications of these membranes in processes involving membrane separation units as well as related challenges and limiting factors

were discussed. Furthermore

an economic analysis was conducted based on case studies

exploring the replacement of traditional separation materials with MOFs membranes and the upgrading of entire processes to membrane separation technologies

revealing considerable economic benefits of adopting membrane separation technologies. Finally

in light of the excellent properties of MOFs materials

future research directions in this field were anticipated

aiming to provide a reference for the application of MOFs membranes in hydrogen

helium and methane separation and purification processes.

关键词

MOFs膜氢氦甲烷分离膜分离法氢气纯化氦气提取

Keywords

MOFs membraneshydrogen helium methane separationmembrane separation methodhydrogen purificationhelium extraction

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