Study on carbon capture performances of compound alcoholamine solutions enhanced by Ce-Mn-based catalysts

WANG Jingkuan; PI Wenting; YUAN Shitong; FU Dong; LI Liwen; DU Shuming; ZHANG Pan

doi:10.12434/j.issn.2097-2547.20260047

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Study on carbon capture performances of compound alcoholamine solutions enhanced by Ce-Mn-based catalysts

更新时间：2026-07-28

- Study on carbon capture performances of compound alcoholamine solutions enhanced by Ce-Mn-based catalysts
- Pages: 1-12(2026)
- 作者机构：
  
  1.华北电力大学（保定）环境科学与工程系，河北保定 071003
  2.中国大唐集团科技创新有限公司，河北雄安 071799
  3.华北电力大学（保定）河北省燃煤电站烟气多污染物协同控制重点实验室，河北保定 071003
  4.国家能源集团新能源技术研究院有限公司，北京 102211
- 作者简介：
- 基金信息：
- DOI：10.12434/j.issn.2097-2547.20260047
  CLC： TQ426
- Received：29 January 2026，
  
  Revised：2026-03-17，
  
  Online First：28 July 2026，
- 稿件说明：
移动端阅览
王敬宽,邳文婷,袁世通等.铈锰基催化剂强化复配醇胺溶液碳捕集性能研究[J].低碳化学与化工,

WANG Jingkuan,PI Wenting,YUAN Shitong,et al.Study on carbon capture performances of compound alcoholamine solutions enhanced by Ce-Mn-based catalysts[J].Low-Carbon Chemistry and Chemical Engineering,
王敬宽,邳文婷,袁世通等.铈锰基催化剂强化复配醇胺溶液碳捕集性能研究[J].低碳化学与化工, DOI：10.12434/j.issn.2097-2547.20260047.

WANG Jingkuan,PI Wenting,YUAN Shitong,et al.Study on carbon capture performances of compound alcoholamine solutions enhanced by Ce-Mn-based catalysts[J].Low-Carbon Chemistry and Chemical Engineering, DOI：10.12434/j.issn.2097-2547.20260047.

摘要

在烟气CO

捕集领域，醇胺溶液CO

捕集效率和低温高效再生的协同提升是工业应用中亟待解决的关键问题。采用水热法制备了Ce@C（Ce浓度0.2 mol/L）、Mn@C（Mn浓度0.2 mol/L）和

Mn@C（

(Ce):

(Mn)）；以乙醇胺（MEA）和N-甲基二乙醇胺（MDEA）为胺组分构建了复配醇胺吸收剂（总质量40 g）。采用SEM、TEM和XPS等表征了催化剂的表面形貌、微观结构和电子状态等，并研究了催化剂作用下复配醇胺吸收剂的CO

吸收-解吸性能。结果表明，由质量分数分别为10%和20%的MEA和MDEA组成的复配醇胺吸收剂（1E2D）具有较高的CO

吸收-解吸性能，其CO

吸收载荷为8.648 × 10

-2

g/g（吸收温度313.15 K，下同），CO

解吸量为5.867 × 10

-2

g/g（解吸温度363.15 K，下同），解吸效率为67.844%。与1E2D相比，在1E2D中加入质量分数为0.05%的1Ce1Mn@C后，CO

吸收载荷可提高12.26%，CO

解吸量可提高30.74%，解吸能耗可降低14.6%。在连续进行5次循环后，该体系表现出良好的稳定性。

Abstract

In the field of CO

capture from flue gas

the synergistic improvement of CO

capture efficiency of amine solutions and low-temperature efficient regeneration is a key issue that urgently needs to be solved in industrial applications. Ce@C (Ce concentration of 0.2 mol/L)

Mn@C (Mn concentration of 0.2 mol/L) and

Mn@C (

(Ce):

(Mn)) were prepared by hydrothermal method. Compound alcoholamine absorbents were constructed by monoethanolamine (MEA) and N-methyldiethanolamine (MDEA) as the amine component (total mass of 40 g). The surface morphologies

microstructures and electronic states of the catalysts were characterized by SEM

TEM and XPS

and the CO

absorption-desorption performances for the compound alcoholamine absorbents with the catalysts were studied. The results show that the compound alcoholamine absorbent (1E2D) composed of MEA and MDEA with mass fractions of 10% and 20%

respectively

has relatively high CO

absorption-desorption performance

with the CO

absorption loading amount of 8.648 × 10

-2

g/g (absorption temperature of 313.15 K

same below)

the CO

desorption amount of 5.867 × 10

-2

g/g (desorption temperature of 363.15 K

same below) and the desorption efficiency of 67.844%. Compared with 1E2D

after adding 1Ce1Mn@C with mass fraction of 0.05% to 1E2D

the CO

absorption loading amount can be increased by 12.26%

the CO

desorption amount can be increased by 30.74% and the desorption energy consumption can be reduced by 14.6%. After five continuous cycles

the system exhibits good stability.

关键词

Keywords

references

FENG C , ZHENG C J , SHAN M L . The clarification for the features, temporal variations, and potential factors of global carbon dioxide emissions [J ] . Journal of Cleaner Production , 2020 , 255 : 120250 .

SUN Y , JIANG Y Q , WEI H J , et al . Nano-enabled strategies for greenhouse gases emission mitigation: A comprehensive review [J ] . Nano Today , 2024 , 57 : 102378 .

CHEN Y , WU Y , LIU X , et al . Energy, exergy and economic (3E) analysis of a novel integration process based on coal-fired power plant with CO 2 capture & stor age, CO 2 refrigeration, and waste heat recovery [J ] . Energy , 2024 , 299 : 131443 .

RAHMAN F A , AZIZ M M A , SAIDUR R , et al . Pollution to solution: Capture and sequestration of carbon dioxide (CO 2 ) and its utilization as a renewable energy source for a sustainable future [J ] . Renewable and Sustainable Energy Reviews , 2017 , 71 : 112 - 126 .

李函珂 , 党成雄 , 杨光星 , 等 . 面向二氧化碳捕集的过程强化技术进展 [J ] . 化工进展 , 2020 , 39 ( 12 ): 4919 - 4939 .

LI H K , DANG C X , YANG G X , et al . Process intensification techniques towards carbon dioxide capture: A review [J ] . Chemical Industry and Engineering Progress , 2020 , 39 ( 12 ): 4919 - 4939 .

ZHANG G Y , LIU J S , QIAN J , et al . Review of research progress and stability studies of amine-based biphasic absorbents for CO 2 capture [J ] . Journal of Industrial and Engineering Chemistry , 2024 , 134 : 28 - 50 .

JIANG W F , LI X S , GAO G , et al . Advances in applications of ionic liquids for phase change CO 2 capture [J ] . Chemical Engineering Journal , 2022 , 445 : 136767 .

刘大李 , 王聪 , 刘新伟 , 等 . 用于二氧化碳捕集的化学吸收剂研究进展 [J ] . 低碳化学与化工 , 2024 , 49 ( 1 ): 94 - 104 .

LIU D L , WANG C , LIU X W , et al . Research advances in chemical absorbents for carbon dioxide capture [J ] . Low-Carbon Chemistry and Chemical Engineering , 2024 , 49 ( 1 ): 94 - 104 .

GELLES T , LAWSON S , ROWNAGHI A A , et al . Recent advances in development of amine functionalized adsorbents for CO 2 capture [J ] . Adsorption , 2020 , 26 ( 1 ): 5 - 50 .

WU H L , ZHANG X L , WU Q . Research progress of carbon capture technology based on alcohol amine solution [J ] . Separation and Purification Technology , 2024 , 333 : 125715 .

WANG L D , FANG J , MA H J , et al . Super-low energy consuming CO 2 capture triggered by weak hydrogen bonds in solid-liquid phase separation [J ] . Energy , 2023 , 272 : 127162 .

DEY A , DASH S K , MANDAL B . Equilibrium CO 2 solubility and thermophysical properties of aqueous blends of 1-(2-aminoethyl) piperazine and N-methyldiethanolamine [J ] . Fluid Phase Equilibria , 2018 , 463 : 91 - 105 .

SAEED I M , ALABA P , MAZARI S A , et al . Opportunities and challenges in the development of monoethanolamine and its blends for post-combustion CO 2 capture [J ] . International Journal of Greenhouse Gas Control , 2018 , 79 : 212 - 233 .

MENG F Z , MENG Y , JU T Y , et al . Research progress of aqueous amine solution for CO 2 capture: A review [J ] . Renewable and Sustainable Energy Reviews , 2022 , 168 : 112902 .

邵亚茹 , 高荣泽 , 吴志强 , 等 . 不同碳捕集场景下MEA/MDEA混合胺溶液的适用性分析 [J ] . 洁净煤技术 , 2024 , 30 ( S1 ): 360 - 369 .

SHAO Y R , GAO R Z , WU Z Q , et al . Applicability analysis of MEA/MDEA blended amine solution under different carbon capture scenarios [J ] . Clean Coal Technology , 2024 , 30 ( S1 ): 360 - 369 .

ZHANG R , LIANG Z W , LIU H L , et al . Study of formation of bicarbonate ions in CO 2 -loaded aqueous single 1DMA2P and MDEA tertiary amines and blended MEA-1DMA2P and MEA-MDEA amines for low heat of regeneration [J ] . Industrial & Engineering Chemistry Research , 2016 , 55 ( 12 ): 3710 - 3717 .

GAO H X , WANG N , DU J G , et al . Comparative kinetics of carbon dioxide (CO 2 ) absorption into EAE, 1DMA2P and their blends in aqueous solution using the stopped-flow technique [J ] . International Journal of Greenhouse Gas Control , 2020 , 94 : 102948 .

LIANG J X , HAN H Y , LI W B , et al . Experimental study on the absorption enhancement of CO 2 by MDEA -MEA based nanofluids [J ] . The Canadian Journal of Chemical Engineering , 2022 , 100 ( 11 ): 3335 - 3344 .

CHATURVEDI K R , NARUKULLA R , SHARMA T . CO 2 capturing evaluation of single-step silica nanofluid through rheological investigation for nanofluid use in carbon utilization applications [J ] . Journal of Molecular Liquids , 2020 , 304 : 112765 .

RASHIDI H , MAMIVAND S . Experimental and numerical mass transfer study of carbon dioxide absorption using Al 2 O 3 /water nanofluid in wetted wall column [J ] . Energy , 2022 , 238 : 121670 .

ZHANG P , GAO Y R , ZHAO Y , et al . Enhanced CO 2 capture and corrosion resistance investigation of tetramethylammonium glycinate-N-methyldiethanolamine aqueous solutions augmented by metal-porous carbon spheres [J ] . Separation and Purification Technology , 2025 , 362 : 131674 .

PASHAEI H , GHAEMI A . CO 2 absorption into aqueous diethanolamine solution with nano heavy metal oxide particles using stirrer bubble column: Hydrodynamics and mass transfer [J ] . Journal of Environmental Chemical Engineering , 2020 , 8 ( 5 ): 104110 .

BHATTI U H , ALIVAND M S , BARZAGLI F , et al . Functionalized carbon spheres for energy-efficient CO 2 capture: Synthesis, application, and reaction mechanism [J ] . ACS Sustainable Chemistry & Engineering , 2023 , 11 ( 32 ): 11955 - 11964 .

KATTA L , SUDARSANAM P , THRIMURTHULU G , et al . Doped nanosized ceria solid solutions for low temperature soot oxidation: Zirconium versus lanthanum promoters [J ] . Applied Catalysis B: Environmental , 2010 , 101 ( 1/2 ): 101 - 108 .

WEN X Y , LI C T , FAN X P , et al . Experimental study of gaseous elemental mercury removal with CeO 2 / γ -Al 2 O 3 [J ] . Energy & Fuels , 2011 , 25 ( 7 ): 2939 - 2944 .

GUO H X , KOU X C , ZHAO Y J , et al . Effect of synergistic interaction between Ce and Mn on the CO 2 capture of calcium-based sorbent: Textural properties, electron donation, and oxygen vacancy [J ] . Chemical Engineering Journal , 2018 , 334 : 237 - 246 .

VENKATASWAMY P , RAO K N , JAMPAIAH D , et al . Nanostructured manganese doped ceria solid solutions for CO oxidation at lower temperatures [J ] . Applied Catalysis B: Environmental , 2015 , 162 : 122 - 132 .

WU C L , WANG Q , WANG X M , et al . Al 2 O 3 nanoparticles integration for comprehensive enhancement of eutectic salt thermal performance: Experimental design, molecular dynamics calculations, and system simulation studies [J ] . Energy , 2024 , 292 : 130567 .

GAO Y , ZHANG F , HUANG K , et al . Absorption of CO 2 in amino acid ionic liquid (AAIL) activated MDEA solutions [J ] . International Journal of Greenhouse Gas Control , 2013 , 19 : 379 - 386 .

BARZAGLI F , LAI S , MANI F . A new class of single-component absorbents for reversible carbon dioxide capture under mild conditions [J ] . ChemSusChem , 2015 , 8 ( 1 ): 184 - 191 .

黄斌 , 许世森 , 郜时旺 , 等 . 华能北京热电厂 CO 2 捕集工业试验研究 [J ] . 中国电机工程学报 , 2009 , 29 ( 17 ): 14 - 20 .

HUANG B , XU S S , GAO S W , et al . Industrial test of CO 2 capture in Huaneng Beijing coal-fired power station [J ] . Proceedings of the CSEE , 2009 , 29 ( 17 ): 14 - 20 .

王蕾 , 郑珩 , 张向辉 , 等 . 耐硫耐水低温脱硝催化剂制备 [J ] . 天然气化工—C1化学与化工 , 2019 , 44 ( 2 ): 50 - 55 .

WANG L , ZHENG H , ZHANG X H , et al . Preparation of sulfur- and water-resistant low-temperature denitration catalysts [J ] . Natural Gas Chemical Industry , 2019 , 44 ( 2 ): 50 - 55 .

杨孜素 , 黄琼 , 童熙 , 等 . ZSM-5担载CuCeO x 催化剂催化降解丙烯腈及高N 2 选择性 [J/OL ] . 环境工程 : 1 - 18 [ 2026-07-10 ] . https://link.cnki.net/urlid/11.2097.X.20260126.1146.002 https://link.cnki.net/urlid/11.2097.X.20260126.1146.002 .

YANG Z S , HUANG Q , TONG X , et al . Catalytic degradation of acrylonitrile and high N 2 selectivity over CuCeO x catalyst supported on ZSM-5 [J/OL ] . Environmental Engineering : 1 - 18 [ 2026-07-10 ] . https://link.cnki.net/urlid/11.2097.X.20260126.1146.002 https://link.cnki.net/urlid/11.2097.X.20260126.1146.002 .

ASTARITA G , SAVAGE D , LONGO J . Promotion of CO 2 mass transfer in carbonate solutions [J ] . Chemical Engineering Science , 1982 , 37 ( 10 ): 1593 - 1593 .

WEN S Y , WU H Z , ZHANG X M , et al . Novel amino acid ionic liquids as messenger of multi-tertiary-amines solutions for highly efficient capture of CO 2 [J ] . Chemical Engineering Science , 2024 , 284 : 119530 .

CHEN M S , LI M J , ZHANG L , et al . Intensification of amino acid ionic liquids with different additives for CO 2 capture [J ] . ACS Sustainable Chemistry & Engineering , 2022 , 10 ( 37 ): 12082 - 12089 .

LV B H , JING G H , QIAN Y H , et al . An efficient absorbent of amine-based amino acid-functionalized ionic liquids for CO 2 capture: High capacity and regeneration ability [J ] . Chemical Engineering Journal , 2016 , 289 : 212 - 218 .

TORRES-MENDIETA R , MONDRAG R . Fabrication of high stable gold nanofluid by pulsed laser ablation in liquids [J ] . Advanced Materials Letters , 2015 , 6 ( 12 ): 1037 - 1042 .

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