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Effects of support acidities on catalytic performances for gas-phase hydrogenation of furfuryl alcohol to 2-methylfuran
- Low-Carbon Chemistry and Chemical Engineering Pages: 1-9(2026)
- 作者机构：
沈阳化工大学 化学工程学院，辽宁 沈阳 110142
- 作者简介：
- 基金信息：
DOI：10.12434/j.issn.2097-2547.20250428
CLC： TQ426.8Received：11 November 2025，
Revised：2025-11-28，
Online First：07 April 2026，
- 稿件说明：
移动端阅览
张道通,何佳芮,周生冉等.载体酸性质对糠醇气相加氢制2-甲基呋喃催化性能的影响[J].低碳化学与化工,
ZHANG Daotong,HE Jiarui,ZHOU Shengran,et al.Effects of support acidities on catalytic performances for gas-phase hydrogenation of furfuryl alcohol to 2-methylfuran[J].Low-Carbon Chemistry and Chemical Engineering,
张道通,何佳芮,周生冉等.载体酸性质对糠醇气相加氢制2-甲基呋喃催化性能的影响[J].低碳化学与化工, DOI：10.12434/j.issn.2097-2547.20250428.
ZHANG Daotong,HE Jiarui,ZHOU Shengran,et al.Effects of support acidities on catalytic performances for gas-phase hydrogenation of furfuryl alcohol to 2-methylfuran[J].Low-Carbon Chemistry and Chemical Engineering, DOI：10.12434/j.issn.2097-2547.20250428.
摘要
2-甲基呋喃作为一种具有广阔应用前景的生物燃料和化工中间体，其高效合成备受关注。目前2-甲基呋喃多采用糠醛为原料进行合成，但普遍存在2-甲基呋喃选择性较低和反应稳定性较差等问题。相比之下，以糠
醇为原料的加氢路径更具优势。采用沉淀法制备了Cu/MgO、Cu/CeO
2
、Cu/SiO
2
和Cu/Al
2
O
3
，利用N
2
吸/脱附、XRD和H
2
-TPR等多种表征方法对催化剂的结构进行了分析，重点考察了载体酸性质对糠醇气相加氢制2-甲基呋喃反应性能的影响。结果表明，与MgO、CeO
2
和SiO
2
相比，Al
2
O
3
与Cu之间具有较强的相互作用，这能够促进Cu物种分散，使其在还原过程中生成更多的Cu
0
和Cu
+
活性物种，而这些活性位点与Al
2
O
3
的酸性位点能够产生协同作用，使Cu/Al
2
O
3
表现出良好的催化性能及稳定性。在反应温度为210 ℃、常压、质量空速为4.74 h
-1
和
n
(H
2
):
n
(糠醇) = 4:1的条件下，Cu/Al
2
O
3
的糠醇初始转化率接近100%，2-甲基呋喃选择性达92.6%。反应10 h后，Cu/Al
2
O
3
的糠醇转化率为89.1%，2-甲基呋喃选择性维持在87%以上。
Abstract
As a biofuel and chemical intermediate with broad application prospects
2-methylfuran has attracted significant attention for its efficient synthesis. Currently
the production of 2-methylfuran relies primarily on furfural as the feedstock. However
the process is often plagued by low selectivity toward 2-methylfuran and poor reaction stability. In contrast
the hydrogenation pathway using furfuryl alcohol as feedstock offers distinct advantages. Cu/MgO
Cu/CeO
2
Cu/SiO
2
and Cu/Al
2
O
3
were prepared via the precipitation method and their structures were characterized by N
2
adsorption/desorption
XRD
H
2
-TPR
and so on. The effects of acidities of the supports on gas-phase hydrogenation of furfuryl alcohol to 2-methylfuran were investigated. The results indicate that
compared to MgO
CeO₂ and SiO
2
Al
2
O
3
exhibits strong interaction with Cu
which enhances the dispersion of Cu species and facilitates the formation more Cu
0
and Cu
+
active species during reduction. The synergy between active sites and the acid sites on Al
2
O
3
confers the Cu/Al
2
O
3
with superior catalytic performance and excellent stability. Under the reaction co
nditions of 210 °C
atmospheric pressure
weight hourly space velocity of 4.74 h
-1
and
n
(H
2
):
n
(furfuryl alcohol) of 4:1
the initial conversion rate of furfuryl alcohol approaches 100%
and 2-methylfuran selectivity approaches 92.6%. After 10 h of reaction
the conversion rate of furfuryl alcohol of Cu/Al
2
O
3
approaches 89.1%
and the 2-methylfuran selectivity maintains above 87%.
关键词
Keywords
references
PAN J H , SUN T H . Understanding the nature and rationale of carbon neutrality [J ] . Chinese Journal of Urban and Environmental Studies , 2023 , 11 ( 2 ): 2350012 .
徐迎迎 , 漆新华 . 糠醛转化为生物燃料的研究进展 [J ] . 能源环境保护 , 2025 , 39 ( 3 ): 12 - 26 .
WANG Y Y , QI X H . Advances in the conversion of furfural to biofuels [J ] . Energy Environmental Protection , 2025 , 39 ( 3 ): 12 - 26 .
DELLIERE P , GUIGO N . Exploring new horizons for bio-based poly (furfuryl alcohol) by exploiting functionalities offered by side reactions [J ] . ACS Macro Letters , 2022 , 11 ( 10 ): 1202 - 1206 .
CERNY C , SCHLICHTHERLE-CERNY H , GIBE R , et al . Furfuryl alcohol is a precursor for furfurylthiol in coffee [J ] . Food Chemistry , 2021 , 337 : 128008 .
SANG S Y , WANG Y , ZHU W , et al . Selective hydrogenation of furfuryl alcohol to tetrahydrofurfuryl alcohol over Ni/ γ -Al 2 O 3 catalysts [J ] . Research on Chemical Intermediates , 2017 , 43 ( 2 ): 1179 - 1195 .
WANG Y , LIU S S , ZHANG Y D , et al . In-situ formation of Ni-C-Al 2 O 3 catalyst from MOFs@Al 2 O 3 composite for furfuryl alcohol hydrogenation to tetrahydrofurfuryl alcohol [J ] . Catalysis Letters , 2023 , 153 ( 6 ): 1666 - 1675 .
LIU P , SUN L Y , JIA X X , et al . Efficient one-pot conversion of furfural into 2-methyltetrahydrofuran using non-precious metal catalysts [J ] . Molecular Catalysis , 2020 , 490 : 110951 .
YAMAGUCHI A , MURAKAMI Y , IMURA T , et al . Hydrogenolysis of furfuryl alcohol to 1,2-pentanediol over supported ruthenium catalysts [J ] . ChemistryOpen , 2021 , 10 ( 8 ): 731 - 736 .
WIJAYA H W , KOJIMA T , HARA T , et al . Synthesis of 1,5-pentanediol by hydrogenolysis of furfuryl alcohol over Ni-Y 2 O 3 composite catalyst [J ] . ChemCatChem , 2017 , 9 ( 14 ): 2869 - 2874 .
WANG W , YAN J M , SUN M Z , et al . Recent progress in the conversion of methylfuran into value-added chemicals and fuels [J ] . Molecules , 2024 , 29 ( 13 ): 2976 .
DONG F , ZHU Y L , ZHENG H Y , et al . Cr-free Cu-catalysts for the selective hydrogenation of biomass-derived furfural to 2-methylfurn: The synergistic effect of metal and acid sites [J ] . Journal of Molecular Catalysis A: Chemical , 2015 , 398 : 140 - 148 .
FU X X , LIU Y , LIU Q Y , et al . Preparation of highly active Cu/SiO 2 catalysts for furfural to 2-methylfuran by ammonia evaporation method [J ] . Catalysts , 2022 , 12 ( 3 ): 276 .
GONG X X , LI N , LI Y , et al . The catalytic hydrogenation of furfural to 2-methylfuran over the Mg-Al oxides supported Co-Ni bimetallic catalysts [J ] . Molecular Catalysis , 2022 , 531 : 112651 .
FU Z L , WANG Z , LIN W G , et al . High efficient conversion of furfural to 2-methylfuran over Ni-Cu/Al 2 O 3 catalyst with formic acid as a hydrogen donor [J ] . Applied Catalysis A , 2017 , 547 : 248 - 255 .
WANG S Q , WANG Y Z , JI Y G , et al . Preparation of 2-methylfuran by hydrodeoxygenation of furfural over Cu 3P catalysts [J ] . ChemistrySelect , 2025 , 10 ( 20 ): e01019 .
REN G Q , WANG G R , MEI H , et al . Reaction mechanism investigation of furfural conversion to 2-methylfuran on Cu (111) surface [J ] . Chemical Physics Letters , 2018 , 703 : 1 - 7 .
VOROTNIKOV V , MPOURMPAKIS G , VLACHOS D G . DFT study of furfural conversion to furan, furfuryl alcohol, and 2-methylfuran on Pd (111) [J ] . ACS Catalysis , 2012 , 2 ( 12 ): 2496 - 2504 .
ALDOSARI O F . Selective conversion of furfuryl alcohol to 2-methylfuran over nanosilica supported Au:Pd bimetallic catalysts at room temperature [J ] . Journal of Saudi Chemical Society , 2019 , 23 ( 7 ): 938 - 946 .
IQBAL S , LIU X , ALDOSAR O F , et al . Conversion of furfuryl alcohol into 2-methylfuran at room temperature using Pd/TiO 2 catalyst [J ] . Catalysis Science & Technology , 2014 , 4 ( 8 ): 2280 - 2286 .
赵明明 , 娄洺源 , 朴茜琳 , 等 . 助剂Ga对Pt基催化剂脱氢性能的影响 [J ] . 石油化工高等学校学报 , 2024 , 37 ( 5 ): 46 - 55 .
ZHAO M M , LOU M Y , PIAO X L , et al . Effect of additive Ga on dehydrogenation performance of Pt⁃based catalyst [J ] . Journal of Petrochemical Universities , 2024 , 37 ( 5 ): 46 - 55 .
郭莎莎 , 宋君辉 , 金吉海 , 等 . 硫化温度对NiW/Al 2 O 3 催化剂活性的影响 [J ] . 辽宁石油化工大学学报 , 2025 , 45 ( 2 ): 13 - 20 .
GUO S S , SONG J H , JIN J H , et al . Effect of vulcanization temperature on the activity of NiW/Al 2 O 3 Catalyst [J ] . Journal of Liaoning Petrochemical University , 2025 , 45 ( 2 ): 13 - 20 .
ZHANG J X , WU D F . Aqueous phase catalytic hydrogenation of furfural to furfuryl alcohol over in-situ synthesized Cu-Zn/SiO 2 catalysts [J ] . Materials Chemistry and Physics , 2021 , 260 : 124152 .
WANG Y , SANG S Y , ZHU W , et al . CuNi@C catalysts with high activity derived from metal-organic frameworks precursor for conversion of furfural to cyclopentanone [J ] . Chemical Engineering Journal , 2016 , 299 : 104 - 11 .
DU H , MA X Y , YAN P F , et al . Catalytic furfural hydrogenation to furfuryl alcohol over Cu/SiO 2 catalysts: A comparative study of the preparation methods [J ] . Fuel Processing Technology , 2019 , 193 : 221 - 231 .
WANG J Q , YANG J Y , BING Z Z , et al . Refining surface copper species on Cu/SiO 2 catalysts to boost furfural hydrogenation to furfuryl alcohol [J ] . Molecules , 2025 , 30 ( 2 ): 225 .
JACKSON M A , WHITE M G , HAASCH R T , et al . Hydrogenation of furfural at the dynamic Cu surface of CuOCeO 2 /Al 2 O 3 in a vapor phase packed bed reactor [J ] . Molecular Catalysis , 2018 , 445 : 124 - 132 .
SINGH R , PANDEY V , PANT K K . Promotional role of oxygen vacancy defects and Cu-Ce interfacial sites on the activity of Cu/CeO 2 catalyst for CO 2 hydrogenation to methanol [J ] . ChemCatChem , 2022 , 14 ( 24 ): e202201053 .
LI G J , GU C T , ZHU W B , et al . Hydrogen production from methanol decomposition using Cu-Al spinel catalysts [J ] . Journal of Cleaner Production , 2018 , 183 : 415 - 423 .
LIU Y J , QING S J , HOU X N , et al . Temperature dependence of Cu-Al spinel formation and its catalytic performance in methanol steam reforming [J ] . Catalysis Science & Technology , 2017 , 7 ( 21 ): 5069 - 5078 .
刘小青 , 李时卉 , 孙梦婷 , 等 . MnO x /SAPO-11 催化剂的制备, 表征及其低温 NH 3 -SCR 活性 [J ] . 物理化学学报 , 2016 , 32 ( 5 ): 1236 - 1246 .
LIU X Q , LI S H , SUN M T , et al . Preparation, characterization and low-temperature NH 3 -SCR activity of MnO x /SAPO-11 catalysts [J ] . Acta Physico-Chimica Sinica , 2016 , 32 ( 5 ): 1236 - 1246 .
CUI G Q , MENG X Y , ZHANG X , et al . Low-temperature hydrogenation of dimethyl oxalate to ethylene glycol via ternary synergistic catalysis of Cu and acid-base sites [J ] . Applied Catalysis B: Environmental , 2019 , 248 : 394 - 404 .
WENG M W , ZHANG Z H , OKEJIRI F , et al . Encapsulation of CuO nanoparticles within silicalite-1 as a regenerative catalyst for transfer hydrogenation of furfural [J ] . Iscience , 2021 , 24 ( 8 ): 102884 .
HLAING N . Development and evaluation of heterogeneous catalysts to convert biomass to useful chemicals [D ] . Nagasaki : Nagasaki University , 2018 .
JIMENEZ-GARCIA G , LASA H D , QUINTANA-SOLORZANO R , et al . Catalyst activity decay due to pore blockage during catalytic cracking of hydrocarbons [J ] . Fuel , 2013 , 110 : 89 - 98 .
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