语种选择
- Editorial Board
- Guidance
- Journal Online
- 个人中心
- 退出登录
浏览全部资源
扫码关注微信
- Editorial Board
- Editorial Member
- Youth Member
- Guidance
- Open Access
- Submission Guideline
- Processing Procedure
- Cost Payment
- Journal Online
- Lasted Issue
- Online First
- Archive
您当前的位置：
首页 >
文章列表页 >
Research and industrialization progress of copper-based catalysts for CO2 hydrogenation to methanol
| 更新时间：2026-04-17
|
Research and industrialization progress of copper-based catalysts for CO2 hydrogenation to methanol
- Low-Carbon Chemistry and Chemical Engineering Pages: 1-25(2026)
- 作者机构：
西南化工研究设计院有限公司 多孔材料与分离转化全国重点实验室，国家碳一化学工程技术研究中心， 四川 成都 610225
- 作者简介：
- 基金信息：
DOI：10.12434/j.issn.2097-2547.20250376
CLC： TQ426Received：07 October 2025，
Revised：2025-11-23，
Online First：17 April 2026，
- 稿件说明：
移动端阅览
吴子波,李俊英,郭继奎等.二氧化碳加氢制甲醇铜基催化剂研究及工业化进展[J].低碳化学与化工,
WU Zibo,LI Junying,GUO Jikui,et al.Research and industrialization progress of copper-based catalysts for CO2 hydrogenation to methanol[J].Low-Carbon Chemistry and Chemical Engineering,
吴子波,李俊英,郭继奎等.二氧化碳加氢制甲醇铜基催化剂研究及工业化进展[J].低碳化学与化工, DOI：10.12434/j.issn.2097-2547.20250376.
WU Zibo,LI Junying,GUO Jikui,et al.Research and industrialization progress of copper-based catalysts for CO2 hydrogenation to methanol[J].Low-Carbon Chemistry and Chemical Engineering, DOI：10.12434/j.issn.2097-2547.20250376.
Research and industrialization progress of copper-based catalysts for CO2 hydrogenation to methanol
摘要
二氧化碳（CO
2
）加氢制甲醇技术可以实现对CO
2
的资源化利用，有望从根本上消除其对气候的不利影响。该技术与CO
2
捕集、风-光电制氢集成后，可以切实推动能源结构向低碳清洁能源方向转型。鉴于CO
2
稳定的化学性质，开发高效稳定的催化剂对于实现CO
2
加氢制甲醇技术的工业化突破至关重要。首先，通过对比CO
2
加氢制甲醇技术中不同催化剂的特点，明确了铜基催化剂良好的工业应用前景。然后，以反应机理、活性中心、载体和助剂为切入点，系统综述了国内外铜基催化剂的研究进展，并在此基础上总结了铜基催化剂催化性能的优化方向。最后，基于相关技术的中试及工业化进展，从工艺及技术经济性角度指出了铜基催化剂工业化过程中的技术瓶颈及其应对策略。铜基催化剂研究已进入机理指导下的催化剂设计阶段，尽管多数成果仍处于实验室阶段，但随着理论研究的深入、催化剂制备技术的发展，以及工业化手段的升级，在新的催化体系出现之前，铜基催化剂仍有望作为CO
2
加氢制甲醇技术实现大规模工业化所使用的主要催化剂。
Abstract
The catalytic hydrogenation of carbon dioxide (CO
2
) to methanol enables the resource utilization of CO
2
and has the potential to fundamentally eliminate its adverse impacts on the climate. When integrated with CO
2
capture technologies and wind- and solar-powered hydrogen production
this technology can effectively promote the transformation of the energy structure toward low-carbon and clean energy. Given the chemically stable nature of CO
2
the development of efficient and stable catalysts is crucial for achieving industrial breakthroughs in CO
2
hydrogenation to methanol. First
by comparing the characteristics of different catalysts used in CO
2
hydrogenation to methanol
the favorable prospects of copper-based catalysts for industrial application were clarified. Then
focusing on reaction mechanisms
active sites
supports and promoters
the research progress of copper-based catalysts reported both domestically and internationally was systematically reviewed
and on this basis
the directions for catalytic performance optimization of copper-based catalysts were summarized. Finally
based on the pilot-scale and industrialization progress of the related technologies
the technical bottlenecks encountered in the industrialization of copper-based catalysts and the corresponding countermeasures were identified from the perspectives of process
design and techno-economic analysis. Research on copper-based catalysts has entered a stage of mechanism-guided catalyst design. Although most studies are still at the laboratory scale
with the further advancement of theoretical research
the development of catalyst preparation technologies
and the upgrading of industrialization approaches
copper-based catalysts are still expected to serve as the primary catalysts for the large-scale industrialization of CO
2
hydrogenation to methanol before the emergence of new catalytic systems.
关键词
Keywords
references
JIANG X , NIE X W , GUO X W , et al . Recent advances in carbon dioxide hydrogenation to methanol via heterogeneous catalysis [J ] . Chemical Reviews , 2020 , 120 : 7984 - 8034 .
时永兴 , 林刚 , 孙晓航 , 等 . 二氧化碳加氢制甲醇过程中铜基催化剂活性位点研究进展 [J ] . 化工进展 , 2023 , 42 ( S1 ): 287 - 298 .
SHI Y X , LIN G , SUN X H , et al . Research progress on active sites in Cu-based catalysts for CO 2 hydrogenation to methanol [J ] . Chemical Industry and Engineering Progress , 2023 , 42 ( S1 ): 287 - 298 .
季东 , 王健 , 王可 , 等 . 不同CO 2 捕集技术的CO 2 耦合绿氢制甲醇工艺研究 [J ] . 化工学报 , 2022 , 73 ( 10 ): 4565 - 4575 .
JI D , WANG J , WANG K , et al . Process research of methanol production by CO 2 coupled green hydrogen with different CO 2 capture technologies [J ] . CIESC Journal , 2022 , 73 ( 10 ): 4565 - 4575 .
吴子波 , 蹇守华 , 吴路平 . 不同合成工艺的二氧化碳催化加氢制甲醇装置经济性分析 [J ] . 低碳化学与化工 , 2023 , 48 ( 6 ): 60 - 66 .
WU Z B , JIAN S H , WU L P . Plants economic analysis of catalytic hydrogenation of CO 2 to methanol with different synthesis processes [J ] . Low-Carbon Chemistry and Chemical Engineering , 2023 , 48 ( 6 ): 60 - 66 .
李鹏阳 , 王改荣 , 张彩东 , 等 . CO 2 加氢制甲醇催化剂理化性质对催化性能影响研究进展 [J ] . 低碳化学与化工 , 2024 , 49 ( 11 ): 12 - 20 .
LI P Y , WANG G Y , ZHANG C D , et al . Research progress on impact of physicochemical properties of catalysts on catalytic performances for CO 2 hydrogenation to methanol [J ] . Low-Carbon Chemistry and Chemical Engineering , 2024 , 49 ( 11 ): 12 - 20 .
杨嘉聪 , 程光旭 , 贾彤华 , 等 . 煤制甲醇与绿氢高效耦合新工艺模拟及技术经济分析 [J ] . 化工进展 , 2025 , 44 ( 8 ): 4657 - 4668 .
YANG J C , CHENG G X , JIA T H , et al . Simulation and techno-economic analysis of new efficient coupling processes between coal to methanol and green hydrogen [J ] . Chemical Industry and Engineering Progress , 2025 , 44 ( 8 ): 4657 - 4668 .
闫泽 . 二氧化碳加氢制甲醇经济性及减碳效益测算分析 [J ] . 化学工业 , 2022 , 40 ( 2 ): 36 - 41 .
YAN Z . Economic efficiency and carbon reduction benefit analysis of CO 2 hydrogenation to methanol [J ] . Chemical Industry , 2022 , 40 ( 2 ): 36 - 41 .
徐敏杰 , 朱明辉 , 陈天元 , 等 . CO 2 高值化利用: CO 2 加氢制甲醇催化剂研究进展 [J ] . 化工进展 , 2021 , 40 ( 2 ): 565 - 576 .
XU M J , ZHU M H , CHEN T Y , et al . High value utilization of CO 2 : Research progress of catalyst for hydrogenation of CO 2 to methanol [J ] . Chemical Industry and Engineering Progress , 2021 , 40 ( 2 ): 565 - 576 .
王玉琪 , 万寅涛 , 张贵泉 , 等 . 二氧化碳加氢制甲醇研究进展 [J ] . 西华大学学报（自然科学版） , 2025 , 44 ( 1 ): 105 - 120 .
WANG Y Q , WAN Y T , ZHANG G Q , et al . Research progress on carbon dioxide hydrogenation for methanol production [J ] . Journal of Xihua University (Natural Science Edition) , 2025 , 44 ( 1 ): 105 - 120 .
王艳燕 , 刘会贞 , 韩布兴 . 多相催化剂催化二氧化碳加氢合成甲醇的研究进展 [J ] . 高等学校化学学报 , 2020 , 41 ( 11 ): 2393 - 2403 .
WANG Y Y , LIU H Z , HAN B X . Advances in CO 2 hydrogenation to methanol by heterogeneous catalysis [J ] . Chemical Journal of Chinese Universities , 2020 , 41 ( 11 ): 2393 - 2403 .
ZHANG L J , YANG H Y , GAO P . Research progress in copper-based catalysts for methanol synthesis from CO 2 hydrogenation [J ] . Journal of Fuel Chemistry and Technology , 2025 , 52 : 1759 - 1773 .
ZHONG J W , YANG X F , WU Z L , et al . State of the art and perspectives in heterogeneous catalysis of CO 2 hydrogenation to methanol [J ] . Chemical Society Reviews , 2020 , 49 : 1385 - 1413 .
LIU X X , ZHANG H , DU J , et al . Research progress of methanol production via CO 2 hydrogenation: Mechanism and catalysts [J ] . Process Safety and Environmental Protection , 2024 , 189 : 1071 - 1086 .
PAN X Y , XU J C , WANG Y L , et al . A new perspective on hydrogenation of CO 2 into methanol over heterogeneous catalysts [J ] . Progress in Natural Science: Materials International , 2024 , 34 : 482 - 494 .
TEDEEVA M A , KUSTOV A L , BATKIN A M , et al . Catalytic systems for hydrogenation of CO 2 to methanol [J ] . Molecular Catalysis , 2024 , 566 : 114403 .
侯瑞君 , 邱瑞 , 孙克宁 . Cu基CO 2 合成甲醇催化剂载体的研究进展 [J ] . 化工进展 , 2020 , 39 ( 7 ): 2639 - 2647 .
HOU R J , QIU R , SUN K N . Progress in the Cu-based catalyst supports for methanol synthesis from CO 2 [J ] . Chemical Industry and Engineering Progress , 2020 , 39 ( 7 ): 2639 - 2647 .
赵挺 , 高腾飞 , 杨阳 , 等 . 铜基催化剂上CO 2 加氢制甲醇研究现状与展望 [J ] . 洁净煤技术 , 2025 , 31 ( 3 ): 104 - 119 .
ZHAO T , GAO T F , YANG Y , et al . State of the art and perspectives in CO 2 hydrogenation to methanol over Cu based catalysts [J ] . Clean Coal Technology , 2025 , 31 ( 3 ): 104 - 119 .
ZHOU Z X , GAO P . Direct carbon dioxide hydrogenation to produce bulk chemicals and liquid fuels via heterogeneous catalysis [J ] . Chinese Journal of Catalysis , 2022 , 43 : 2045 - 2056 .
叶知远 , 饶娜 , 夏菖佑 , 等 . CO 2 加氢制甲醇催化剂与项目进展 [J ] . 洁净煤技术 , 2024 , 30 ( 8 ): 150 - 161 .
YE Z Y , RAO N , XIA C Y , et al . Advances in catalysts and project progress for CO 2 hydrogenation to methanol [J ] . Clean Coal Technology , 2024 , 30 ( 8 ): 150 - 161 .
吉利创新中心 . 落地阿拉善！吉利创新中心助力绿色低碳经济发展迈向新高度 [EB/OL ] . ( 2024-10-28 )[ 2025-11-21 ] . https://www.ittilab.com/content/details100011_631.html https://www.ittilab.com/content/details100011_631.html .
Geely Innovation Center . Get down on the ground, Aaron!Geely Innovation Centre to help green low carbon economy to a new height [EB/OL ] . ( 2024-10-28 )[ 2025-11-21 ] . https://www.ittilab.com/content/details100011_631.html https://www.ittilab.com/content/details100011_631.html .
张丽君 , 杨海艳 , 高鹏 . CO 2 加氢制甲醇铜基催化剂研究进展 [J ] . 燃料化学学报（中英文） , 2024 , 52 : 1759 - 1773 .
ZHANG L J , YANG H Y , GAO P . Research progress in copper-based catalysts for methanol synthesis from CO 2 hydrogenation [J ] . Journal of Fuel Chemistry and Technology , 2024 , 52 ( 12 ): 1759 - 1773 .
SAN X G , LI X D , JIN Q , et al . Comprehensive insight into Cu-based catalysts for CO 2 hydrogenation to methanol [J ] . Sustainable Materials and Technologies , 2025 , 45 : e01437 .
江洋洋 . CO 2 加氢制甲醇技术现状及其发展趋势 [J ] . 能源化工 , 2024 , 45 : 1 - 8 .
JIANG Y Y . Current status and development trend of CO 2 hydrogenation to methanol technology [J ] . Energy Chemical Industry , 2024 , 45 : 1 - 8 .
苏暐光 , 孔磊 . Cu基催化剂上二氧化碳加氢合成甲醇的研究进展 [J ] . 现代化工 , 2021 , 40 ( 4 ): 26 - 29 .
SU W G , KONG L . Research progress on copper-based catalysts for hydrogenation of carbon dioxide into methanol [J ] . Modern Chemical Industry , 2021 , 41 ( 4 ): 26 - 29 .
XU L J , CHEN X X , DENG C , et al . Hydrogenation of carbon dioxide to methanol over non-noble catalysts: A state-of-the-art review [J ] . Atmosphere , 2023 , 14 : 1208 .
NIU J T , LIU H Y , JIN Y , et al . Comprehensive review of Cu-based CO 2 hydrogenation to CH 3 OH: Insights from experimental work and theoretical analysis [J ] . International Journal of Hydrogen Energy , 2022 , 47 : 9183 - 9200 .
HAN Y , WANG Y L , MA T Z , et al . Mechanistic understanding of Cu-based bimetallic catalysts [J ] . Frontiers of Chemical Science and Engineering , 2020 , 14 : 689 - 748 .
YAN Y , WONG R J , MA ZR , et al . CO 2 hydrogenation to methanol on tungsten-doped Cu/CeO 2 catalysts [J ] . Applied Catalysis B: Environmental , 2022 , 306 : 121098 .
霍凯旋 , 王阳 , 吴明铂 . CO 2 加氢制甲醇用Cu基催化剂研究进展 [J ] . 低碳化学与化工 , 2023 , 48 ( 3 ): 22 - 31 .
HUO K X , WANG Y , WU M B . Research progress on Cu-based catalysts for CO 2 hydrogenation to methanol [J ] . Low-Carbon Chemistry and Chemical Engineering , 2023 , 48 ( 3 ): 22 - 31 .
ARAÚJO T P , MITCHELL S , PÉREZ‐RAMÍREZ J . Design principles of catalytic materials for CO 2 hydrogenation to methanol [J ] . Advanced Materials , 2024 , 36 : 2409322 .
LIU Y X , WANG X G , WANG Z H , et al . Hydrogenation of CO 2 to CH 3 OH on the Cu-ZnO SrTiO 3 catalysts: The electronic metal-support interaction induces oxygen vacancy generation [J ] . ACS Catalysis , 2024 , 14 : 12610 - 12622 .
SHARMA S K , PAUL B , PAL R S , et al . Influence of indium as a promoter on the stability and selectivity of the nanocrystalline Cu/CeO 2 catalyst for CO 2 hydrogenation to methanol [J ] . ACS Applied Materials & Interfaces , 2021 , 13 : 28201 - 28213 .
HIGHAM M D , QUESNE M G , CATLOW C R A . Mechanism of CO 2 conversion to methanol over Cu(110) and Cu(100) surfaces [J ] . Dalton Transactions , 2020 , 49 : 8478 - 8497 .
KANDEMIR T , GIRGSDIES F , HANSEN T C , et al . In situ study of catalytic processes: Neutron diffraction of a methanol synthesis catalyst at industrially relevant pressure [J ] . Angewandte Chemie International Edition , 2013 , 52 : 5166 - 5170 .
DIVINS N J , KORDUS D , TIMOSHENKO J , et al . Operando high-pressure investigation of size-controlled CuZn catalysts for the methanol synthesis reaction [J ] . Nature Communications , 2021 , 12 : 1435 .
李忠林 , 王禹皓 , 郑燕娥 , 等 . Cu-ZnO-ZrO 2 催化剂孔结构调控CO 2 加氢制甲醇性能研究 [J ] . 燃料化学学报（中英文） , 2024 , 52 ( 9 ): 1235 - 1248 .
LI Z L , WANG Y H , ZHENG Y E , et al . Pore structure modulation of Cu-ZnO-ZrO 2 catalysts for methanol production from CO 2 hydrogenation [J ] . Journal of Fuel Chemistry and Technology , 2024 , 52 ( 9 ): 1235 - 1248 .
CUI X J , CHEN S A , YANG H H , et al . Improving methanol selectivity in CO 2 hydrogenation by tuning the distance of Cu on catalyst [J ] . Applied Catalysis B: Environmental , 2021 , 298 : 120590 .
CUI X J , LIU Y Q , YAN W J , et al . Enhancing methanol selectivity of commercial Cu/ZnO/Al 2 O 3 catalyst in CO 2 hydrogenation by surface silylation [J ] . Applied Catalysis B: Environmental , 2023 , 339 : 123099 .
JIANG X Y , KE J C , LI R , et al . Hydrophobically modified Cu-ZnO-Al 2 O 3 catalyst for CO 2 hydrogenation to methanol [J ] . Journal of Environmental Chemical Engineering , 2025 , 13 : 116758 .
DIN I U , SHAHARUN M S , NAEEM A , et al . Revalorization of CO 2 for methanol production via ZnO promoted carbon nanofibers based Cu-ZrO 2 catalytic hydrogenation [J ] . Journal of Energy Chemistry , 2019 , 39 : 68 - 76 .
杨军 , 梁丽烨 , 李华 , 等 . 稀土元素改性CO 2 加氢制甲醇催化剂的研究进展 [J ] . 低碳化学与化工 , 2024 , 49 ( 11 ): 1 - 11 .
YANG J , LIANG L Y , LI H , et al . Research progress on catalysts modified by rare earth elements for CO 2 hydrogenation to methanol [J ] . Low-Carbon Chemistry and Chemical Engineering , 2024 , 49 ( 11 ): 1 - 11 .
JIANG F , JIANG F , WANG S S , et al . Catalytic activity for CO 2 hydrogenation is linearly dependent on generated oxygen vacancies over CeO 2 -supported Pd catalysts [J ] . ChemCatChem , 2022 , 14 : e202200422 .
TIAN G F , WU Y Q , WU S Y , et al . Solid-state synthesis of Pd/In 2 O 3 catalysts for CO 2 hydrogenation to methanol [J ] . Catalysis Letters , 2022 , 153 : 903 - 910 .
XIE G M , JIN R R , REN P J , et al . Boosting CO 2 hydrogenation to methanol by adding trace amount of Au into Cu/ZnO catalysts [J ] . Applied Catalysis B: Environmental , 2023 , 324 : 122233 .
CHOI E J , LEE Y H , LEE D W , et al . Hydrogenation of CO 2 to methanol over Pd-Cu/CeO 2 catalysts [J ] . Molecular Catalysis , 2017 , 434 : 146 - 153 .
张培培 , 辛靖 , 李思漩 , 等 . Pd掺杂方式对Cu/ZnO低温催化CO 2 加氢制甲醇性能的影响 [J ] . 低碳化学与化工 , 2025 , 50 ( 6 ): 16 - 24 .
ZHANG P P , XIN J , LI S X , et al . Effect of Pd doping method on low temperature catalytic performance of Cu/ZnO for CO 2 hydrogenation to methanol [J ] . Low-Carbon Chemistry and Chemical Engineering , 2025 , 50 ( 6 ): 16 - 24 .
XU M Y , LIU F , LIU S K , et al . Atomically dispersed Ru on flower-like In 2 O 3 to boost CO 2 hydrogenation to methanol [J ] . Journal of Materials Science & Technology , 2025 , 221 : 289 - 301 .
生学良 , 李娘修 , 金建飞 , 等 . 金属掺杂对PdM/ZnO催化CO 2 加氢制甲醇性能的影响 [J ] . 贵金属 , 2025 , 46 : 10 - 18+25 .
SHENG X L , LI N X , JIN J F , et al . Effect of metal doping on the performance of PdM/ZnO catalysts for CO 2 hydrogenation to methanol [J ] . Precious Metals , 2025 , 46 ( 1 ): 10 - 18+25 .
RASTEIRO L F , DE SOUSA R A , VIEIRA L H , et al . Insights into the alloy-support synergistic effects for the CO 2 hydrogenation towards methanol on oxide-supported Ni 5 Ga 3 catalysts: An experimental and DFT study [J ] . Applied Catalysis B: Environmental , 2022 , 302 : 120842 .
ALFKE J L , TEJEDA-SERRANO M , PHADKE S , et al . Boundary conditions for promotion versus poisoning in copper-gallium-based CO 2 -to-methanol hydrogenation catalysts [J ] . ACS Catalysis , 2024 , 14 : 9166 - 9175 .
FENG Y F , SHEN L , ZHANG W H , et al . Elucidating the structure-activity relationship of the bimetallic Ni-Cu catalysts for CO 2 hydrogenation [J ] . Journal of CO 2 Utilization , 2024 , 80 : 102683 .
ZHANG X W , XU L K , ZOU R , et al . Experimental studies of the highly active Cu-Ni/In 2 O 3 catalyst for CO 2 hydrogenation to methanol [J ] . Industrial & Engineering Chemistry Research , 2025 , 64 : 8712 - 8721 .
WU Q , LIANG S Y , ZHANG T Y , et al . Current advances in bimetallic catalysts for carbon dioxide hydrogenation to methanol [J ] . Fuel , 2022 , 313 : 122963 .
GAO B , WEN Z , WANG Y F , et al . Recent advances in alloy catalysts for CO 2 hydrogenation to methanol [J ] . ChemCatChem , 2024 , 16 : e202400814 .
周紫璇 , 杨海艳 , 孙予罕 , 等 . 二氧化碳加氢制甲醇多相催化剂研究进展 [J ] . 高等学校化学学报 , 2022 , 43 ( 7 ): 20220235 .
ZHOU Z X , YANG H Y , SUN Y H , et al . Recent progress in heterogeneous catalysts for the hydrogenation of carbon dioxide to methanol [J ] . Chemical Journal of Chinese Universities , 2022 , 43 ( 7 ): 20220235 .
王宇 , 李红伟 , 吴玉 , 等 . 铟基催化剂混合晶型调控对CO 2 加氢制甲醇反应的影响 [J ] . 石油学报（石油加工） , 2024 , 40 ( 4 ): 983 - 992 .
WANG Y , LI H W , WU Y , et al . Effect of mixed crystal phase control of indium-based catalyst on the reaction of CO 2 hydrogenation to methanol [ J ] . Acta Petrolei Sinica (Petroleum Processing Section) , 2024 , 40 ( 4 ): 983 - 992 .
YE J Y , LIU C J , MEI D H , et al . Active oxygen vacancy site for methanol synthesis from CO 2 hydrogenation on In 2 O 3 (110): A DFT study [J ] . ACS Catalysis , 2013 , 3 : 1296 - 1306 .
聂小娃 , 于笑妍 , 郭新闻 . 不同表面结构氧化铟催化CO 2 加氢制甲醇的反应机理 [J ] . 石油学报（石油加工） , 2024 , 40 ( 5 ): 1242 - 1253 .
NIE X W , YU X Y , GUO X W . Reaction mechanism of CO 2 hydrogenation to methanol on indium oxide catalyst with different surface structures [J ] . Acta Petrolei Sinica(Petroleum Processing Section) , 2024 , 40 ( 5 ): 1242 - 1253 .
张忠昊 , 颜珂岚 , 周以萌 , 等 . 氧化铟基催化剂用于高选择性二氧化碳催化加氢制甲醇 [J ] . 化学通报（中英文） , 2025 , 88 ( 4 ): 417 - 423, 449 .
ZHANG Z H , YAN K L , ZHOU Y M , et al . Indium oxide catalyst for highly selective carbon dioxide catalytic hydrogenation to methanol [J ] . Chemistry , 2025 , 88 ( 4 ): 417 - 423+449 .
张培培 , 王文波 , 米晓彤 , 等 . ZnO/ZrO 2 固溶体催化剂的合成及其在CO 2 加氢制甲醇中的应用研究 [J ] . 无机盐工业 , 2025 , 57 ( 5 ): 125 - 132 .
ZHANG P P , WANG W B , MI X T , et al . Synthesis of ZnO/ZrO 2 solid solution catalyst and its application in CO 2 hydrogenation to methanol [J ] . Inorganic Chemicals Industry , 2025 , 57 ( 5 ): 125 - 132 .
YANG Y X , WU L L , YAO B Q , et al . Gallium cluster-promoted In 2 O 3 catalyst for CO 2 hydrogenation to methanol [J ] . ACS Catalysis , 2024 , 14 : 13958 - 13972 .
DING X Y , DANG S S , ZHANG W Q , et al . Co promotion of In 2 O 3 for selective hydrogenation of CO 2 to methanol [J ] . Molecular Catalysis , 2025 , 582 : 115206 .
MARTIN O , MARTíN A J , MONDELLI C , et al . Indium oxide as a superior catalyst for methanol synthesis by CO 2 hydrogenation [J ] . Angewandte Chemie , 2016 , 128 : 6369 - 6373 .
ZHANG M H , DOU M B , YU Y Z . Theoretical study of the promotional effect of ZrO 2 on In 2 O 3 catalyzed methanol synthesis from CO 2 hydrogenation [J ] . Applied Surface Science , 2018 , 433 : 780 - 789 .
WANG J J , LI G N , LI Z L , et al . A highly selective and stable ZnO-ZrO 2 solid solution catalyst for CO 2 hydrogenation to methanol [J ] . Science Advances , 2017 , 3 : e1701290 .
SHA F , TANG S , TANG C Z , et al . The role of surface hydroxyls on ZnZrO solid solution catalyst in CO 2 hydrogenation to methanol [J ] . Chinese Journal of Catalysis , 2023 , 45 : 162 - 173 .
LUO Z , TIAN S S , WANG Z . Enhanced activity of Cu/ZnO/C catalysts prepared by cold plasma for CO 2 hydrogenation to methanol [J ] . Industrial & Engineering Chemistry Research , 2020 , 59 : 5657 - 5663 .
CHEN J , ZHANG D J , LIU B , et al . Photoinduced precise synthesis of diatomic Ir 1 Pd 1 ‐In 2 O 3 for CO 2 hydrogenation to methanol via angstrom-scale-distance dependent synergistic cataly sis [J ] . Angewandte Chemie International Edition , 2024 , 63 : e202401168 .
HUANG F , WANG S Q , ZHANG L J . Design and recent advances of novel MoS 2 -based catalysts for methanol from carbon dioxide hydrogenation [J ] . Separation and Purification Technology , 2025 , 365 : 132681 .
HU J T , YU L , DENG J , et al . Sulfur vacancy-rich MoS 2 as a catalyst for the hydrogenation of CO 2 to methanol [J ] . Nature Catalysis , 2021 , 4 : 242 - 250 .
ZHANG G H , MENG X , WANG H , et al . Switching the prod uct selectivity from methane to methanol in CO 2 hydrogenation via Cu-modified vacancy engineering at MoS 2 edge sites [J ] . Journal of Energy Chemistry , 2025 , 108 : 286 - 296 .
ZHANG C J , FOLLANA-BERNÁ J , DRAGOE D , et al . Cobalt tetracationic 3,4-pyridinoporphyrazine for direct CO 2 to methanol conversion escaping the CO intermediate pathway [J ] . Angewandte Chemie International Edition , 2024 , 63 : e202411967 .
申展 , 王怡然 , 潘云翔 , 等 . Cu基CO 2 加氢制甲醇催化剂新型设计策略 [J ] . 化学反应工程与工艺 , 2025 , 41 ( 1 ): 58 - 69 .
SHEN Z , WANG Y R , PAN Y X , et al . Novel design strategies for Cu-based catalysts in CO 2 hydrogenation to methanol [J ] . Chemical Reaction Engineering and Technology , 2025 , 41 ( 1 ): 58 - 69 .
贾晨喜 , 邵敬爱 , 白小薇 , 等 . 二氧化碳加氢制甲醇铜基催化剂性能的研究进展 [J ] . 化工进展 , 2020 , 39 ( 9 ): 3658 - 3668 .
JIA C X , SHAO J A , BAI X W , et al . Review on Cu-based catalysts for CO 2 hydrogenation to methanol [J ] . Chemical Industry Progress , 2020 , 39 ( 9 ): 3658 - 3668 .
何聂燕 , 李学琴 , 刘鹏 , 等 . 二氧化碳加氢合成甲醇技术现状及催化剂研究进展 [J ] . 洁净煤技术 , 2025 , 31 ( 2 ): 198 - 206 .
HE N Y , LI X Q , LIU P , et al . Technical status of carbon dioxide hydrogenation to methanol and research progress of catalysts [J ] . Clean Coal Technology , 2025 , 31 ( 2 ): 198 - 206 .
DU J , ZONG L J , ZHANG S , et al . Numerical investigation on the heterogeneous pulsed dielectric barrier discharge plasma catalysis for CO 2 hydrogenation at atmospheric pressure: Effects of Ni and Cu catalysts on the selectivity conversions to CH 4 and CH 3 OH [J ] . Plasma Processes and Polymers , 2022 , 19 : e2100111 .
WANG Y H , GAO W G , LI K Z , et al . Strong evidence of the role of H 2 O in affecting methanol selectivity from CO 2 hydrogenation over Cu-ZnO-ZrO 2 [J ] . Chem , 2020 , 6 : 419 - 430 .
BEHRENS M , STUDT F , KASATKIN I , et al . The active site of methanol synthesis over Cu/ZnO/Al 2 O 3 industrial catalysts [J ] . Science , 2012 , 336 : 893 - 897 .
TAKEYASU K , SAWAKI Y , IMABAYASHI T , et al . Hydrogenation of formate species using atomic hydrogen on a Cu(111) model catalyst [J ] . Journal of the American Chemical Society , 2022 , 144 : 12158 - 12166 .
CHIANG C L , LIN K S , CHUANG H W . Direct synthesis of formic acid via CO 2 hydrogenation over Cu/ZnO/Al 2 O 3 catalyst [J ] . Journal of Cleaner Production , 2018 , 172 : 1957 - 1977 .
SUN X C , JIN Y F , CHENG Z Z , et al . Dual active sites over Cu-ZnO-ZrO 2 catalysts for carbon dioxide hydrogenation to methanol [J ] . Journal of Environmental Sciences , 2023 , 131 : 162 - 172 .
WANG W W , QU Z P , SONG L X , et al . CO 2 hydrogenation to methanol over Cu/CeO 2 and Cu/ZrO 2 catalysts: Tuning methanol selectivity via metal-support interaction [J ] . Journal of Energy Chemistry , 2020 , 40 : 22 - 30 .
YANG M , YU J F , ZIMINA A , et al . Unlocking a dual-channel pathway in CO 2 hydrogenation to methanol over single-site zirconium on amorphous silica [J ] . Angewandte Chemie International Edition , 2024 , 63 : e202312292 .
KATTEL S , YAN B H , YANG Y X , et al . Optimizing binding energies of key intermediates for CO 2 hydrogenation to methanol over oxide-supported copper [J ] . Journal of the American Chemical Society , 2016 , 138 : 12440 - 12450 .
YANG Y , MIMS C A , DISSELKAMP R S , et al . (Non)formation of methanol by direct hydrogenation of formate on copper catalysts [J ] . The Journal of Physical Chemistry C , 2010 , 114 : 17205 - 17211 .
YANG Y , MIMS C A , MEI D H , et al . Mechanistic studies of methanol synthesis over Cu from CO/CO 2 /H 2 /H 2 O mixtures: The source of C in methanol and the role of water [J ] . Journal of Catalysis , 2013 , 298 : 10 - 17 .
YANG Y , MEI D H , PEDEN C H F , et al . Surface-bound intermediates in low-temperature methanol synthesis on copper: Participants and spectators [J ] . ACS Catalysis , 2015 , 5 : 7328 - 7337 .
WU W L , WANG Y A , LUO L , et al . CO 2 hydrogenation over copper/ZnO single-atom catalysts: Water-promoted transient synthesis of methanol [J ] . Angewandte Chemie International Edition , 2022 , 61 : e202213024 .
XU D , HONG X L , LIU G L . Highly dispersed metal doping to ZnZr oxide catalyst for CO 2 hydrogenation to methanol: Insight into hydrogen spillover [J ] . Journal of Catalysis , 2021 , 393 : 207 - 214 .
SUN Q M , LIU X Y , GU Q Q , et al . Breaking the conversion-selectivity trade-off in methanol synthesis from CO 2 using dual intimate oxide/metal interfaces [J ] . Journal of the American Chemical Society , 2024 , 146 : 28885 - 28894 .
VERGARA T , GÓMEZ D , WARMUTH L , et al . On the structure sensitivity of CO 2 hydrogenation over Cu/ZrO 2 : Insights into the role of the support and the active sites [J ] . ACS Catalysis , 2024 , 14 : 14127 - 14138 .
WEI X Y , SU W G , SHI Y C , et al . Cu 0 at the Cu/ZnO interface efficiently accelerate CO 2 hydrogenation to methanol over Cu/ZnO/C-P catalysts [J ] . International Journal of Hydrogen Energy , 2024 , 58 : 128 - 136 .
ZHU L , LIU Y , GAO Y H , et al . Mechanistic understanding of dissociated hydrogen in Cu/CeO 2 -catalyzed methanol synthesis [J ] . ACS Applied Materials & Interfaces , 2025 , 17 : 7151 - 7163 .
CORED J , MAZARíO J , CERDÁ-MORENO C , et al . Enhanced methanol p roduction over non-promoted Cu-MgO-Al 2 O 3 materials with ex-solved 2 nm Cu particles: Insights from an operando spectroscopic study [J ] . ACS Catalysis , 2022 , 12 : 3845 - 3857 .
FERNÁNDEZ-VILLANUEVA E , LUSTEMBERG P G , ZHAO M J , et al . Water and Cu + synergy in selective CO 2 hydrogenation to methanol over Cu-MgO-Al 2 O 3 catalysts [J ] . Journal of the American Chemical Society , 2024 , 146 : 2024 - 2032 .
LI H B , CUI Y Y , LIU Y X , et al . Copper phyllosilicate-derived ultrafine copper nanoparticles with plenty of Cu 0 and Cu + for the enhanced catalytic performance of ethylene carbonate hydrogenation to methanol [J ] . Nanotechnology , 2022 , 33 : 435703 .
LUNKENBEIN T , SCHUMANN J , BEHRENS M , et al . Formation of a ZnO overlayer in industrial Cu/ZnO/Al 2 O 3 catalysts induced by strong metal-support interactions [J ] . Angewandte Chemie International Edition , 2015 , 54 : 4544 - 4548 .
KATTEL S , RAMÍREZ PEDRO J , CHEN J G , et al . Active sites for CO 2 hydrogenation to methanol on Cu/ZnO catalysts [J ] . Science , 2017 , 355 : 1296 - 1299 .
CHANG X , ZI X H , LI J , et al . An insight into synergistic metal-oxide interaction in CO 2 hydrogenation to methanol over Cu/ZnO/ZrO 2 [J ] . Catalysts , 2023 , 13 : 1337 .
SALMI M A . Active sites of Cu/ZnO-based catalysts for CO 2 hydrogenation to methanol: Part I [J ] . Johnson Matthey Technology Review , 2024 , 68 : 465 - 476 .
SALMI M A . Active sites of Cu/ZnO-Based catalysts for CO 2 hydrogenation to methanol: Part II [J ] . Johnson Matthey Technology Review , 2024 , 68 : 477 - 489 .
JIANG F , YANG Y , WANG L , et al . Dependence of copper particle size and interface on methanol and CO formation in CO 2 hydrogenation over Cu@ZnO catalysts [J ] . Catalysis Science & Technology , 2022 , 12 : 551 - 564 .
ZHENG W , SUN C , DONG Z J , et al . Enhanced CO 2 hydrogenation reaction by tuning interfacial Cu/ZnO x through synergistic interactions in the precursors [J ] . Journal of Catalysis , 2024 , 440 : 115794 .
KIM J , SARMA B B , ANDRÉS E , et al . Surface lewis acidity of periphery oxide species as a general kinetic descriptor for CO 2 hydrogenation to methanol on supported copper nanoparticles [J ] . ACS Catalysis , 2019 , 9 : 10409 - 10417 .
LIU X Y , LUO J , WANG H W , et al . In situ spectroscopic characterization and theoretical calculations identify partially reduced ZnO 1- x /Cu interfaces for methanol synthesis from CO 2 [J ] . Angewandte Chemie International Edition , 2022 , 61 : e202202330 .
HU J , LI Y Y , ZHEN Y P , et al . In situ FTIR and ex situ XPS/HS-LEIS study of supported Cu/Al 2 O 3 and Cu/ZnO catalysts for CO 2 hydrogenation [J ] . Chinese Journal of Catalysis , 2021 , 42 : 367 - 375 .
BRONSATO B J , SOUZA E F , GONZALEZ G G , et al . What role does Al 3+ play in the methanol synthesis from CO 2 hydrogenation using Cu/ZnO/Al catalysts? [J ] . Fuel , 2024 , 375 : 132533 .
CHEN P , ZHU Y F , ZHANG H L , et al . Boosting hydrogenation of CO 2 using cationic Cu atomically dispersed on 2D γ -Al 2 O 3 nanosheets [J ] . Angewandte Chemie International Edition , 2025 , 64 : e202505444 .
ZHOU H G , JIN H , LI Y L , et al . Mechanism of methanol synthesis from CO 2 hydrogenation over Cu/ γ -Al 2 O 3 interface: Influences of surface hydroxylation [J ] . Catalysts , 2023 , 13 : 1244 .
CHANG X , HAN X Y , PAN Y T , et al . Insight into the role of Cu-ZrO 2 interaction in methanol synthesis from CO 2 hydrogenation [J ] . Industrial & Engineering Chemistry Research , 2022 , 61 : 6872 - 6883 .
TADA S , KAYAMORI S , HONMA T , et al . Design of interfacial sites between Cu and amorphous ZrO 2 dedicated to CO 2 -to-methanol hydrogenation [J ] . ACS Catalysis , 2018 , 8 : 7809 - 7819 .
WITOON T , CHALORNGTHAM J , DUMRONGBUNDITKUL P , et al . CO 2 hydrogenation to methanol over Cu/ZrO 2 catalysts: Effects of zirconia phases [J ] . Chemical Engineering Journal , 2016 , 293 : 327 - 336 .
MEUNIER F C , DANSETTE I , PAREDES‐NUNEZ A , et al . Cu-bound formates are main reaction intermediates during CO 2 hydrogenation to methanol over Cu/ZrO 2 [J ] . Angewandte Chemie International Edition , 2023 , 62 : e202303939 .
TADA S , FUJIWARA K , YAMAMURA T , et al . Flame spray pyrolysis makes highly loaded Cu nanoparticles on ZrO 2 for CO 2 -to-methanol hydrogenation [J ] . Chemical Engineering Journal , 2020 , 381 : 122750 .
WU C Y , LIN L L , LIU J J , et al . Inverse ZrO 2 /Cu as a highly efficient methanol synthesis catalyst from CO 2 hydrogenation [J ] . Nature Communications , 2020 , 11 : 5767 .
LI K Z , CHEN J G G . CO 2 hydrogenation to methanol over ZrO 2 -containing catalysts: Insights into ZrO 2 induced synergy [J ] . ACS Catalysis , 2019 , 9 : 7840 - 7861 .
CHANG Y L , LIU W L , CHEN Y , et al . Boosting CO 2 hydrogenation to methanol via ternary Cu-Zn-Zr catalyst: The critical role of interface confinement effect (ICE) [J ] . Molecular Catalysis , 2025 , 584 : 115244 .
WANG W W , ZHANG X Y , LEI B Y , et al . Exploring the nature of copper species: CeO 2 support shape effect and its influence on CO 2 hydrogenation to methanol [J ] . Chemical Engineering Journal , 2024 , 498 : 155636 .
张兰 , 陈标华 , 王宁 . CuZn/CeO 2 催化剂在CO 2 加氢制甲醇中的应用研究 [J ] . 低碳化学与化工 , 2024 , 49 ( 8 ): 100 - 106 .
ZHANG L , CHEN B H , WANG N . Study on application of CuZn/CeO 2 catalysts in CO 2 hydrogenation to methanol [J ] . Low-Carbon Chemistry and Chemical Engineering , 2024 , 49 ( 8 ): 100 - 106 .
ZHANG C C , WANG L T , ETIM U J , et al . Oxygen vacancies in Cu/TiO 2 boost strong metal-support interaction and CO 2 hydrogenation to methanol [J ] . Journal of Catalysis , 2022 , 413 : 284 - 296 .
WANG K , ZHANG F X , CAO N , et al . Unraveling the evolution of oxygen vacancies in TiO 2- x /Cu and its role in CO 2 hydrogenation [J ] . Science China Chemistry , 2024 , 67 : 4125 - 4133 .
CHEN Z Y , TONG H , ZHAO Y , et al . Facet engineering-tailored directional electron transfer from TiO 2 to Cu nanoparticles enhances CO 2 hydrogenation to methanol [J ] . ACS Catalysis , 2025 , 12168 - 12179 .
JEONG S Y , KIM J H , PARK M J , et al . Homogeneously distributed Cu-ZnO(-Al 2 O 3 ) nanoparticles encapsulated with SiO 2 shells for superior CO 2 hydrogenation activity to methanol [J ] . ACS Sustainable Chemistry & Engineering , 2024 , 12 : 4245 - 4254 .
XIA Y G , CHA X W , YAN X , et al . Fine regulation of Cu-ZnO interfaces for enhanced CO 2 hydrogenation to methanol by atomic layer depositing thin ZnO films on copper phyllosilicates [J ] . Applied Catalysis B: Environment and Energy , 2025 , 361 : 124620 .
MENG X L , WANG C Z , CHAE S , et al . CuZnO x active sites anchored on the silanols of hollow silicalite-1 zeolite enhance CO 2 hydrogenation to methanol [J ] . ACS Catalysis , 2025 , 15 : 5412 - 5425 .
KUBOVICS M , TRIGO A , SÁNCHEZ A , et al . Role of graphene oxide aerogel support on the CuZnO catalytic activity: Enhancing methanol selectivity in the hydrogenation reaction of CO 2 [J ] . ChemCatChem , 2022 , 14 : e202200607 .
LI C Y , YANG J , ZHANG C B , et al . Study on catalytic performance in CO 2 hydrogenation to methanol over Au-Cu/C 3 N 4 catalysts [J ] . Catalysts , 2024 , 14 : 470 .
PENG L , JURCA B , GARCIA-BALDOVI A , et al . Nanometric Cu-ZnO particles supported on N-doped graphitic carbon as catalysts for the selective CO 2 hydrogenation to methanol [J ] . Nanomaterials , 2024 , 14 : 476 .
SONG M Y , LIU T K , HONG X L , et al . Coordination environment dependent surface Cu state for CO 2 hydrogenation to methanol [J ] . ACS Sustainable Chemistry & Engineering , 2023 , 11 : 12135 - 12144 .
CHEN F , LIU S Y , HUANG H , et al . Fast synthesis of Cu@zeolitic imidazolate framework-8 (ZIF-8) derived Cu/ZnO catalysts via a facile mechanical grinding method for CO 2 hydrogenation to methanol [J ] . Chemical Science , 2025 , 16 : 2273 - 2286 .
L’HOSPITAL V , ANGELO L , ZIMMERMANN Y , et al . Influence of the Zn/Zr ratio in the support of a copper-based catalyst for the synthesis of methanol from CO 2 [J ] . Catalysis Today , 2021 , 369 : 95 - 104 .
XIAN J J , XU Y T , QU G C , et al . Dual promotion of Cu/ZnO catalysts modified by acetylacetone precursors for CO 2 hydrogenation to methanol [J ] . Química Nova , 2024 , 2 ( 47 ):e-20230094.
SONG X W , YANG C S , LI X H , et al . On the role of hydroxyl groups on Cu/Al 2 O 3 in CO 2 hydrogenation [J ] . ACS Catalysis , 2022 , 12 : 14162 - 14172 .
CHEN C W , KOSARI M , JIANG Z Y , et al . Boosting CO 2 hydrogenation to methanol via enriching the Cu-ZnO interface on layered double oxides [J ] . Small , 2025 , 21 : 2412786 .
YANG M , YU J F , TONG X , et al . Flame-made Cu/ZrO 2 catalysts with metastable phase and strengthened interactions for CO 2 hydrogenation to methanol [J ] . Chemical Communications , 2021 , 57 : 7509 - 7512 .
LI Z Q , DU T , LI Y N , et al . Water- and reduction-free preparation of oxygen vacancy rich Cu-ZnO-ZrO 2 catalysts for promoted methanol synthesis from CO 2 [J ] . Fuel , 2022 , 322 : 124264 .
MAO D L , ZHANG H , ZHANG J X , et al . The influence of the compositions and structures of Cu-ZrO 2 catalysts on the catalytic performance of CO 2 hydrogenation to CH 3 OH [J ] . Chemical Engineering Journal , 2023 , 471 : 144605 .
ARANDIA A , YIM J H , WARRAICH H , et al . Effect of atomic layer deposited zinc promoter on the activity of copper-on-zirconia catalysts in the hydrogenation of carbon dioxide to methanol [J ] . Applied Catalysis B: Environmental , 2023 , 321 : 122046 .
CHANG H H , GAO F F , LUO A L , et al . Oxygen vacancy promoted carbon dioxide activation over Cu/ZrO 2 for CO 2 -to-methanol conversion [J ] . Chemical Communications , 2023 , 59 : 7647 - 7650 .
WANG S W , YANG J H , ZHOU H L , et al . Performance of Cu-Mn-Zn/ZrO 2 catalysts for methanol synthesis from CO 2 hydrogenation: The effect of Zn content [J ] . Journal of Fuel Chemistry and Technology , 2024 , 52 : 293 - 303 .
SCHULTE M L , CATHARINA SENDER V , BAUMGARTEN L , et al . Tuning flame spray pyrolysis for variation of the crystallite size in Cu/ZnO/ZrO 2 and its influence on the performance in CO 2 ‐to‐methanol synthesis [J ] . European Journal of Inorganic Chemistry , 2024 , 28 : e202400684 .
LUO P C , SHI P X , YAN Z Q , et al . Ternary synergistic interaction of Cu-ZnO-ZrO 2 promoting CO 2 hydrogenation to methanol [J ] . Applied Catalysis A: General , 2025 , 689 : 120006 .
ZHANG D Y , SHAO Y , CHEN H H . Development of a CuInZnZrO x catalyst for sorption-enhanced CO 2 hydrogenation to methanol [J ] . Industrial & Engineering Chemistry Research , 2025 , 64 ( 32 ): 15647 - 15657 .
HAN J , WANG L , YU J , et al . CO 2 hydrogenation to methanol over Cu-CeO 2 -ZrO 2 catalysts: The significant effect of metal-support interaction [J ] . Fuel , 2025 , 381 : 133262 .
LI S Z , GUO L M , ISHIHARA T . Hydrogenation of CO 2 to methanol over Cu/AlCeO catalyst [J ] . Catalysis Today , 2020 , 339 : 352 - 361 .
SINGH R , PANDEY V , PANT K K . Promotional role of oxygen vacancy defects and Cu-Ce interfacial sites on the activity of Cu/CeO 2 catalyst for CO 2 hydrogenation to methanol [J ] . ChemCatChem , 2022 , 14 : e202201053 .
HAN J , YU J , XUE Z T , et al . Highly efficient CO 2 hydrogenation to methanol over Cu-Ce 1- x Zr x O 2 catalysts prepared by an eco-friendly and facile solid-phase grinding method [J ] . Renewable Energy , 2024 , 222 : 119951 .
XABA B S , FRIEDRICH H B , SINGH S , et al . Solution combustion synthesised Cu-CeO 2 catalysts for CO 2 hydrogenation to methanol—The effect of the fuel [J ] . ChemistrySelect , 2024 , 9 : e202400284 .
DJAOUIDA A , SMAIN H , SÉBASTIEN T , et al . Comparative study on the effect of cerina and alumina on the catalytic activity of CuO-ZnO based catalyst in CO 2 hydrogenation to methanol [J ] . Catalysis Letters , 2024 , 154 : 5849 - 5864 .
YU J F , YANG M , ZHANG J X , et al . Stabilizing Cu + in Cu/SiO 2 catalysts with a shattuckite-like structure boosts CO 2 hydrogenation into methanol [J ] . ACS Catalysis , 2020 , 10 : 14694 - 14706 .
DUMA Z G , DYOSIBA X , MOMA J , et al . Thermocatalytic hydrogenation of CO 2 to methanol using Cu-ZnO bimetallic catalysts supported on metal-organic frameworks [J ] . Catalysts , 2022 , 12 : 401 .
VALI S A , MORAL-VICO J , FONT X , et al . Cu/ZnO/CeO 2 Supported on MOF-5 as a novel catalyst for the CO 2 hydrogenation to methanol: A mechanistic study on the effect of CeO 2 and MOF-5 on active sites [J ] . Catalysis Letters , 2024 , 154 : 3157 - 3173 .
杨强 , 王刚 , 李春山 . Cu基催化剂表面改性及其催化二氧化碳加氢制甲醇性能研究 [J ] . 过程工程学报 , 2024 , 24 ( 10 ): 1166 - 1176 .
YANG Q , WANG G , LI C S . Surface modification and catalytic performance study of Cu-based carbon dioxide to methanol hydrogenation catalyst [J ] . The Chinese Journal of Process Engineering , 2024 , 24 ( 10 ): 1166 - 1176 .
GAO P , LI F , ZHAN H J , et al . Influence of Zr on the performance of Cu/Zn/Al/Zr ca talysts via hydrotalcite-like precursors for CO 2 hydrogenation to methanol [J ] . Journal of Catalysis , 2013 , 298 : 51 - 60 .
PASUPULETY N , AL-ZAHRANI A A , DAOUS M A , et al . A study on highly active Cu-Zn-Al-K catalyst for CO 2 hydrogenation to methanol [J ] . Arabian Journal of Chemistry , 2021 , 14 : 102951 .
LI S Z , ZHAO X , LI Y X , et al . CO 2 hydrogenation to methanol on Cu-ZnO/AlLaO with high activity and hydrothermal stability [J ] . Applied Catalysis A: General , 2025 , 692 : 120098 .
CAI Y , WANG Q , WANG D R , et al . A highly selective CuZnY catalyst for CO 2 hydrogenation to methanol [J ] . Catalysis Letters , 2025 , 155 : 216 .
CAI Z G , YU X F , WANG P L , et al . Role of Y 2 O 3 in Cu/ZnO/Y 2 O 3 catalysts for CO 2 hydrogenation to methanol [J ] . Chinese Journal of Catalysis , 2025 , 70 : 410 - 419 .
QIANG Y , GANG W , CHUN S L . Surface modification and catalytic performance study of Cu-based carbon dioxide to methanol hydrogenation catalyst [J ] . The Chinese Journal of Process Engineering , 2024 , 24 : 1166 - 1176 .
WANG X L , ZHENG Y S , ZHANG Y , et al . Facilitation of CO 2 hydrogenation to methanol by spinel ZnGa 2 O 4 in Cu-ZnO Catalysts [J ] . Processes , 2025 , 13 : 1420 .
ZHANG Z Z , CHENG S F , LIU W Q , et al . Unraveling the regulation of Mn in Cu-ZnO x formation during methanol synthesis from syngas over Cu/ZnO/Al 2 O 3 -Mn catalysts [J ] . Applied Catalysis B: Environmental , 2023 , 338 : 122985 .
GUO T , WANG L , ZHAI D D , et al . Systematic Investigation of Cu-ZnO-MnO x catalysts for CO 2 hydrogenation to methanol [J ] . ChemCatChem , 2025 , 17 : e202500103 .
KIM S , CHOI Y , PARK K , et al . Magnesium-promoted catalytic stability of the Cu/ZnO/ZrO 2 /Al 2 O 3 -MgO catalyst in CO 2 hydrogenation to methanol [J ] . Industrial & Engineering Chemistry Research , 2025 , 64 : 5903 - 5911 .
PANDEY V , SINGH P P , PANT K K , et al . Promotional role of methanol and CO 2 in carbon dioxide-rich syngas hydrogenation over slurry reactor utilizing combustion induced Cu-based catalysts [J ] . Materials Today Sustainability , 2025 , 29 : 101082 .
DAI W H , MENG X , JIN D M , et al . Role of basic sites on Cu/ZrO 2 catalysts modified with citric acid in the hydrogenation of CO 2 to methanol [J ] . Industrial & Engineering Chemistry Research , 2025 , 64 : 5228 - 5242 .
YE R P , MA L X , MAO J N , et al . A Ce-CuZn catalyst with abundant Cu/Zn-O v -Ce active sites for CO 2 hydrogenation to methanol [J ] . Nature Communications , 2024 , 15 : 2159 .
HE Q , LI Z F , LI D , et al . Mg enhanced the performance of Cu/ZnO/ZrO 2 for CO 2 hydrogenation to methanol and the mechanism investigation [J ] . Molecular Catalysis , 2024 , 558 : 114008 .
苏静 , 张宗飞 , 张大洲 . 二氧化碳加氢制甲醇的技术进展及展望 [J ] . 化肥设计 , 2022 , 60 : 6 - 9+14 .
SU J , ZHANG Z F , ZHANG D Z . Technological progress and prospects of carbon dioxide hydrogenation to methanol [J ] . Chemical Fertilizer Design , 2022 , 60 : 6 - 9+14 .
吉利创新中心 . 全球首个十万吨级绿色甲醇项目在安阳投产实现年直接碳减排16万吨 [EB/OL ] . ( 2023-4-21 )[ 2025-11-21 ] . https: //www. ittilab. com/content/details100011_457. html https://www.ittilab.com/content/details100011_457.html .
Geely Innovation Center . The world's first 100 , 000 tons of green methanol project put into operation in anyang to achieve direct carbon emission reduction of 160 thousand tons per year [EB/OL ] . ( 2023-4-21 )[ 2025-11-21 ] . https://www.ittilab.com/content/details100011_457 html https://www.ittilab.com/content/details100011_457html .
国家电投远达环保股份有限公司 . 远达环保首个二氧化碳加氢制甲醇中试装置顺利产出“绿色”甲醇 [EB /OL ] . ( 2024-11-13 )[ 2025-11-21 ] . https://zdydep.com/index/news/info.html?id=770&site=2 https://zdydep.com/index/news/info.html?id=770&site=2 .
SPIC Yuanda Environmental Protection Co. , Ltd . The first pilot-scale CO 2 hydrogenation to methanol unit of Yuanda Environmental Protection successfully produced “green” methanol [EB/OL ] . ( 2024-11-13 )[ 2025-11-21 ] . https://zdydep.com/index/news/info. html?id=770&site=2 https://zdydep.com/index/news/info.html?id=770&site=2 .
SÁNCHEZ A , MARTÍN M . Optimal renewable production of ammonia from water and air [J ] . Journal of Cleaner Production , 2018 , 178 : 325 - 342 .
CHEHADE G , DINCER I . Progress in green ammonia production as potential carbon-free fuel [J ] . Fuel , 2021 , 299 : 120845 .
吉旭 , 林今 , 聂李红 , 等 . 适用可再生能源不确定特性的合成氨多稳态柔性工艺技术 [J ] . 洁净煤技术 , 2024 , 30 : 23 - 35 .
JI X , LIN J , NIE L H , et al . Multistable-flexible ammonia process adapted to renewable energy [J ] . Clean Coal Technology , 2024 , 30 ( 2 ): 23 - 35 .
吉旭 , 周步祥 , 贺革 , 等 . 大规模可再生能源电解水制氢合成氨关键技术与应用研究进展 [J ] . 工程科学与技术 , 2022 , 54 ( 5 ): 1 - 11 .
JI X , ZHOU B X , HE G , et al . Research review of the key technology and application of large-scale water electrolysis powered by renewable energy to hydrogen and ammonia production [J ] . Advanced Engineering Sciences , 2022 , 54 ( 5 ): 1 - 11 .
蹇守华 , 王雪峰 , 吴路平 , 等 . 一种二氧化碳制甲醇精馏系统 : 217119361U [P ] . 2021-12-31 .
JIAN S H , WANG X F , WU L P , et al . A carbon dioxide to methanol distillation system : 217119361U [P ] . 2021-12-31 .
吴子波 , 蹇守华 , 吴路平 , 等 . 一种二氧化碳催化加氢制甲醇的工艺和装置 : 117720397A [P ] . 2023-12-08 .
WU Z B , JIAN S H , WU L P , et al . A process and device for catalytic hydrogenation of carbon dioxide to methanol : 117720397A [P ] . 2023-12-08 .
吴子波 , 吴路平 , 赵杰 , 等 . 一种深远海自给式二氧化碳制甲醇热量耦合系统及调峰工艺 : 119633423A [P ] . 2024-11-21 .
WU Z B , WU L P , ZHAO J , et al . A self-contained carbon dioxide to methanol heat coupling system and peak shaving process for deep-sea and far-sea : 119633423A [P ] . 2024-11-21 .
DU Z Y , WU T W , WANG H . Process-level insights into membrane reactors for renewable methanol synthesis: Evaluation, optimization, and recommendations [J ] . Fuel , 2025 , 400 : 135744 .
赵家源 , 杨伟明 , 杜雄伟 , 等 . 二氧化碳加氢制甲醇的系统及方法 : 119345713A [P ] . 2024-10-14 .
ZHAO J Y , YANG W M , DU X W , et al . System and method for hydrogenation of carbon dioxide to methanol : 119345713A [P ] . 2024-10-14 .
吴子波 , 张敬宇 , 吴路平 , 等 . 不同绿氢耦合生物质气化制绿色甲醇工艺经济性分析 [J ] . 低碳化学与化工 , 2025 , 50 ( 3 ): 97 - 105 .
WU Z B , ZHANG J Y , WU L P , et al . Economic analysis of different processes of green hydrogen coupled with biomass gasification for green methanol production [J ] . Low-Carbon Chemistry and Chemical Engineering , 2025 , 50 ( 3 ): 97 - 10 .
查看原文
0
Views
0
下载量
0
CNKI被引量
Alert me when the article has been cited
文章被引用时，请邮件提醒。
提交
Tools
Download
- L-PDFDownload
- XMLDownload
- Meta-XMLDownload
Export Citation
- BibTeXDownload
- EndnoteDownload
- RefMan Download
- NoteExpressDownload
- NoteFirstDownload
Share
Share with wechat friends or circle of friends
Add to favorites
Add to my album
Publicity Resources
Related Articles
Study on performances of Cu/ZnO/ZrO2 catalysts synthesized by ammonia evaporation method for CO2 hydrogenation to methanol
Effect of Ce-doped CuZnAl catalyst on catalytic performances of CO2 hydrogenation to methanol
Influence of electron interaction between Zn and Zr on performance of ZnZr catalysts for CO2 hydrogenation to methanol
Effect of n (Cu)/n (Zn) on performance of Cu/ZnO/Al2O3 catalyst for CO2 hydrogenation to methanol
Effects of base promoters on catalytic performances of MIL-68(Al)-loaded CuZnAl catalysts for CO2 hydrogenation to methanol
Related Author
CHEN Yongbo
WANG Wenchao
JIN Chuanchuan
WU Fapeng
TANG Chizhou
LI Wenxuan
WANG Bin
LI Jing
Related Institution
Anhui Conch Group Co., Ltd.
Anhui Conch Industrial Technology Research Institute Co., Ltd.
College of Environment and Ecology, Taiyuan University of Technology
State Key Laboratory of Clean and Efficient Coal Utilization, Taiyuan University of Technology
College of Engineering and Physical Sciences and School of Energy Resources, University of Wyoming
选择翻译语言
- Postal code：610225
- Tel：028-85964717 Email：236764603@qq.com
- Technical support is provided by Beijing Founder electronics co., LTD 蜀ICP备12008600号-10
蜀公网安备51012202001533 - It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
- Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.
- Total Visits：414451 Visits Today：377
0
Bulk Citation
Export to
BibTeXEndnoteRefManNoteExpressNoteFirst
TOP