Research progress on heavy oil slurry phase hydrocracking catalysts and their atomic-scale regulation

SUN Guangxun; XUE Peng; TIAN Fengyu; LIU Yunqi; PAN Yuan

doi:10.12434/j.issn.2097-2547.20250371

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Research progress on heavy oil slurry phase hydrocracking catalysts and their atomic-scale regulation

更新时间：2026-04-23

- Research progress on heavy oil slurry phase hydrocracking catalysts and their atomic-scale regulation
- Vol. 51, Issue 4, Pages: 70-80(2026)
- 作者机构：
  
  1.中国石油大学（华东）重质油全国重点实验室，山东青岛 266580
  2.安徽师范大学化学与材料科学学院，安徽芜湖 241002
- 作者简介：
- 基金信息：
- DOI：10.12434/j.issn.2097-2547.20250371
  CLC： TQ426;TK91
- Received：16 September 2025，
  
  Revised：2025-10-28，
  
  Published：25 April 2026
- 稿件说明：
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孙广洵,薛鹏,田丰宇等.重油浆态床加氢裂化催化剂及其原子尺度调控研究进展[J].低碳化学与化工,2026,51(4):70-80.

SUN Guangxun,XUE Peng,TIAN Fengyu,et al.Research progress on heavy oil slurry phase hydrocracking catalysts and their atomic-scale regulation[J].Low-Carbon Chemistry and Chemical Engineering,2026,51(4):70-80.
孙广洵,薛鹏,田丰宇等.重油浆态床加氢裂化催化剂及其原子尺度调控研究进展[J].低碳化学与化工,2026,51(4):70-80. DOI： 10.12434/j.issn.2097-2547.20250371.

SUN Guangxun,XUE Peng,TIAN Fengyu,et al.Research progress on heavy oil slurry phase hydrocracking catalysts and their atomic-scale regulation[J].Low-Carbon Chemistry and Chemical Engineering,2026,51(4):70-80. DOI： 10.12434/j.issn.2097-2547.20250371.

摘要

浆态床加氢裂化催化剂的设计和开发是重油高效转化的关键。传统过渡金属硫化物催化剂在加氢反应过程中易团聚，导致金属原子利用率低和加氢性能下降。单原子催化剂具有最大的金属原子利用率和可调的活性中心结构，表现出优异的加氢性能，为重油浆态床加氢裂化催化剂设计提供了新思路。综述了近年来重油浆态床加氢裂化催化剂的研究进展，重点介绍了纳米催化剂和单原子催化剂的结构特性与催化性能差异，进而从原子尺度提出了配位结构调控、双原子位点协同调控和单原子-硫化物耦合调控的浆态床加氢裂化催化剂的设计策略，并对单原子催化剂在重油浆态床加氢裂化反应体系中存在的问题与挑战进行了展望。

Abstract

The design and development of slurry phase hydrocracking catalysts are key to the efficient conversion of heavy oil. Traditional transition metal sulfide catalysts are prone to agglomerate during hydrogenation reactions

resulting in low metal atom utilization rate and decreased hydrogenation performance. Single-atom catalysts have the highest metal atom utilization rate and adjustable active center structure

which show excellent hydrogenation performance

providing new ideas for the design of heavy oil slurry phase hydrocracking catalysts. Research progress on heavy oil slurry phase hydrocracking catalysts in recent years was reviewed

with particular emphasis on the structural characteristics and catalytic performance differences between nano-scale catalysts and single-atom catalysts. At the atomic scale

design strategies for heavy oil hydrocracking catalysts were then proposed

including coordination structure regulation

dual-atom site cooperative regulation

and single-atom-sulfide coupling regulation. In addition

the issues and challenges of single-atom catalysts in heavy oil slurry phase hydrocracking were prospected.

关键词

Keywords

references

王能全 . “双碳”目标下的中国石油安全风险识别及对策 [J ] . 国际石油经济 , 2025 , 33 ( 3 ): 1 - 10 .

WANG N Q . Risk identification and countermeasures for China’s petroleum security under the “dual carbon goals” [J ] . International Petroleum Economy , 2025 , 33 ( 3 ): 1 - 10 .

PHAM D D , NGUYEN T M , HO T H , et al . Advancing hydrodesulfurization in heavy oil: Recent developments, challenges, and future prospects [J ] . Fuel , 2024 , 372 : 132082 .

AL-ATTAS T A , ALI S A , ZAHIR M H , et al . Recent advances in heavy oil upgrading using dispersed catalysts [J ] . Energy & Fuels , 2019 , 33 ( 9 ): 7917 - 7949 .

徐广通 , 刘超文 , 邱丽美 . 基于构效关系研究的石油炼制与化工催化剂表征技术进展 [J ] . 石油学报（石油加工） , 2024 , 40 ( 4 ): 841 - 861 .

XU G T , LIU C W , QIU L M . Advances in characterization techniques for petroleum refining and chemical catalysts based on structure-activity relationship studies [J ] . Acta Petrolei Sinica (Petroleum Processing Section) , 2024 , 40 ( 4 ): 841 - 861 .

谢志翔 , 李吉广 . 浆态床渣油加氢技术进展 [J ] . 低碳化学与化工 , 2025 , 50 ( 2 ): 78 - 87 .

XIE Z X , LI J G . Research progress on slurry bed residue hydrocracking technology [J ] . Low-Carbon Chemistry and Chemical Engineering , 2025 , 50 ( 2 ): 78 - 87 .

GAWANDE M B , ARIGA K , YAMAUCHI Y . Single-atom catalysts [J ] . Advanced Materials Interfaces , 2021 , 8 ( 8 ): 2100436 .

PHAM P T H , PHAM C Q , DAM T T , et al . A comprehensive review of catalyst deactivation and regeneration in heavy oil hydroprocessing [J ] . Fuel Processing Technology , 2025 , 267 : 108170 .

AL-MARSHED A , HART A , LEEKE G , et al . Effectiveness of different transition metal dispersed catalysts for in situ heavy oil upgrading [J ] . Industrial & Engineering Chemistry Research , 2015 , 54 ( 43 ): 10645 - 10655 .

WANG X P , MA H J , WANG D G , et al . Slurry-phase hydrogenation of different asphaltenes to liquid fuels on dispersed MoS 2 nanocatalysts [J ] . ACS Omega , 2023 , 8 ( 18 ): 16384 - 16394 .

DUAN Y J , LIU Y L , CHEN Z J , et al . Amorphous molybdenum sulfide nanocatalysts simultaneously realizing efficient upgrading of residue and synergistic synthesis of 2D MoS 2 nanosheets/carbon hierarchical structures [J ] . Green Chemistry , 2020 , 22 ( 1 ): 44 - 53 .

ZHAO R , WANG Q , YAO Y C , et al . Pd single atoms guided proton transfer along an interfacial hydrogen bond network for efficient electrochemical hydrogenation [J ] . Science Advances , 2025 , 11 ( 32 ): eadu1602 .

PAN Y , ZHANG X , SUN G X , et al . Single-atom-alloy catalysts for enhanced hydrogenation reaction process: Mechanism, regulation strategy, and design principle [J ] . ACS Catalysis , 2025 , 15 ( 5 ): 3674 - 3698 .

LU X J , WU J Z , HE X Y , et al . Ordered single active sites for cascade hydrogenation and hydroformylation reactions [J ] . Nature Catalysis , 2025 , 8 ( 6 ): 536 - 547 .

SUN Z X , ZHOU C K , CHEN Z J , et al . Decoupling activity-selectivity trade-off in photothermal catalytic CO 2 hydrogenation: A hydrogen spillover-assisted dual-site synergy mechanism [J ] . Angewandte Chemie International Edition , 2025 , 64 ( 34 ): e202508090 .

LI M , SUN G X , WANG Z D , et al . Structural design of single-atom catalysts for enhancing petrochemical catalytic reaction process [J ] . Advanced Materials , 2024 , 36 ( 25 ): 2313661 .

WANG Y F , LU J M , ZHANG W L , et al . Insights into reaction mechanism of slurry phase hydrocracking of heavy oil via compositional analysis of individual hydrocarbons [J ] . Chemical Engineering Science , 2025 , 314 : 121789 .

FENG W W , QIAN Y G , WANG T H , et al . Impacts of support properties on the vacuum residue slurry-phase hydrocracking performance of Mo catalysts [J ] . Petroleum Science , 2023 , 20 ( 4 ): 2575 - 2584 .

MA Y D , LIANG R G , WU W Q , et al . Enhancing the activity of MoS 2 /SiO 2 -Al 2 O 3 bifunctional catalysts for suspended-bed hydrocracking of heavy oils by doping with Zr atoms [J ] . Chinese Journal of Chemical Engineering , 2021 , 39 : 126 - 134 .

WANG J B , YAN J T , CUI Q Y , et al . Effect of SiO 2 support particle sizes on the performance of FeZn catalysts in VR slurry-phase hydrocracking [J ] . Catalysis Today , 2025 , 449 : 115183 .

RAWAT A , DHAKLA S , MAITY S K , et al . Mechanistic insight into the coke formation tendency during upgradation of crude oil in slurry phase batch reactor using MoS 2 and its various oil soluble catalysts [J ] . Fuel , 2024 , 359 : 130433 .

KANG K H , NGUYEN N T , PHAM D V , et al . Ligand structure effect in oil-soluble phosphorus-containing molybdenum precursors for slurry-phase hydrocracking of heavy oil [J ] . Journal of Catalysis , 2021 , 402 : 194 - 207 .

YANG T , ZHANG S J , ZHU Y H , et al . An oil-soluble precursor with strong feedstock adaptability and excellent product selectivity for heavy oil hydrocracking [J ] . Chemical Engineering Research and Design , 2023 , 19 : 593 - 605 .

ZHANG X N , CHEN B N , WANG J W , et al . Review of molybdenum disulfide research in slurry bed heavy oil hydrogenation [J ] . ACS Omega , 2023 , 8 ( 21 ): 18400 - 18407 .

LIU B , LV H Y , CUI X X , et al . Preparation of presulfided oil-soluble NiMo catalyst for slurry bed hydrocracking of vacuum residue [J ] . Chemical Engineering Journal , 2024 , 498 : 155166 .

HWANG Y H , LEE Y K . Structure and activity of unsupported NiWS 2 catalysts for slurry phase hydrocracking of vacuum residue: XAFS studies [J ] . Journal of Catalysis , 2021 , 403 : 131 - 140 .

LEE D , KIM K D , LEE Y K . Highly active and stable CoWS 2 catalysts in slurry phase hydrocracking of vacuum residue: XAFS studies [J ] . Journal of Catalysis , 2023 , 421 : 145 - 155 .

CHEN Y F , LU Y K , GUAN Z K , et al . Ultrafine Co-MoS 2 monolayer catalyst derived from oil-soluble single-molecule polyoxometalates for slurry phase hydrocracking [J ] . Fuel , 2022 , 315 : 123134 .

RAWAT A , DHAKLA S , MAITY S K , et al . An inclusive experimental and kinetic understanding of the slurry phase hydroprocessing of crude oil with an active dispersed catalyst to obtain refined fuel [J ] . Journal of Analytical and Applied Pyrolysis , 2024 , 184 : 106834 .

WEI W K , HOU H D , ZHAO Y , et al . A novel preparation strategy for an oil-soluble catalyst in slurry phase hydrocracking: Synergistic effect and electronic regulation of Fe on MoS 2 [J ] . Fuel , 2024 , 374 : 132465 .

RAWAT A , DHAKLA S , TYAGI L , et al . Direct slurry-phase hydrocracking of crude oil using trimetallic nanocatalyst [J ] . Fuel , 2022 , 330 : 125448 .

MA Y D , WU W Q , ZHANG J Y , et al . Slurry-phase hydrocracking of heavy oil with bifunctional catalysts in situ generated from oil-soluble ionic liquid and mixed metal oxide [J ] . Industrial & Engineering Chemistry Research , 2023 , 62 ( 38 ): 15459 - 15468 .

NGUYEN M T , NGUYEN N T , CHO J , et al . A review on the oil-soluble dispersed catalyst for slurry-phase hydrocracking of heavy oil [J ] . Journal of Industrial and Engineering Chemistry , 2016 , 43 : 1 - 12 .

ZHANG H B , LIU G G , SHI L , et al . Single-atom catalysts: Emerging multifunctional materials in heterogeneous catalysis [J ] . Advanced Energy Materials , 2018 , 8 ( 1 ): 1701343 .

LIU J Y . Catalysis by supported single metal atoms [J ] . ACS Catalysis , 2017 , 7 ( 1 ): 34 - 59 .

和玉光 , 郝思嘉 , 杨程 . 石墨烯及其复合材料吸油性能研究进展 [J ] . 化学研究 , 2022 , 33 ( 1 ): 9 - 25 .

HE Y G , HAO S J , YANG C . Research progress of graphene and its composites for oil absorption [J ] . Chemical Research , 2022 , 33 ( 1 ): 9 - 25 .

KIM K D , LEE Y K . Beneficial roles of carbon black additives in slurry phase hydrocracking of vacuum residue [J ] . Applied Catalysis A: General , 2020 , 607 : 117837 .

SUN G X , LIU S H , SHI H F , et al . Structural design and electronic regulation of atomically dispersed Mo-S 4 sites by second shell N species reconfiguration for intensifying hydrogen spillover [J ] . Chemical Engineering Journal , 2024 , 500 : 156679 .

TAN H Y , WANG J L , LIN S C , et al . Dynamic coordination structure evolutions of atomically dispersed metal catalysts for electrocatalytic reactions [J ] . Advanced Materials Interfaces , 2023 , 10 ( 4 ): 2202050 .

SUN G X , LIU D Y , LI M , et al . Atomic coordination structural dynamic evolution of single-atom Mo catalyst for promoting H 2 activation in slurry phase hydrocracking [J ] . Science Bulletin , 2023 , 68 ( 5 ): 503 - 515 .

LIU B , LV H Y , TIAN F Y , et al . Fabrication of a single-atom Mo catalyst for significantly enhanced hydrodesulfurization activity of dibenzothiophene [J ] . Chemical Engineering Journal , 2025 , 505 : 159747 .

GU K X , LIN S . Sustained hydrogen spillover on Pt/Cu(111) single-atom alloy: Dynamic insights into gas-induced chemical processes [J ] . Angewandte Chemie International Edition , 2023 , 62 ( 47 ): e202312796 .

SUN G X , LIU D Y , SHI H F , et al . Oxygen-vacancy-induced built-in electric field across MoCo dual-atomic site catalyst for promoting hydrogen spillover in hydrocracking and hydrodesulfurization [J ] . ACS Catalysis , 2024 , 14 ( 5 ): 3208 - 3217 .

CHEN Y F , LU Y K , GUAN Z K . Ultrafine Co-MoS 2 monolayer catalyst derived from oil-soluble single-molecule polyoxometalates for slurry phase hydrocracking [J ] . Fuel , 2022 , 315 : 123134 .

SUN G X , XUE P , YUE C L , et al . Spontaneous generation of an atomically dispersed Mo and MoS 2 coupling catalyst via reaction induction transformation for enhancing local hydrogen concentration in hydrogenation [J ] . EES Catalysis , 2025 , 3 : 1145 - 1154 .

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