- Editorial Board
- Guidance
- Journal Online
- 个人中心
- 退出登录
浏览全部资源
扫码关注微信
- Editorial Board
- Editorial Member
- Youth Member
- Guidance
- Open Access
- Submission Guideline
- Processing Procedure
- Journal Online
- Lasted Issue
- Online First
- Archive
Experimental study on corrosion behaviors of 310S stainless steel under high-temperature ammonia gas
- Low-Carbon Chemistry and Chemical Engineering Vol. 51, Issue 1, Pages: 150-158(2026)
- 作者机构：
1.福州大学 化工学院，福建 福州 350001
2.福大紫金氢能科技股份有限公司，福建 福州 350108
- 作者简介：
- 基金信息：
DOI：10.12434/j.issn.2097-2547.20250260
CLC： TG172Received：05 June 2025，
Revised：2025-07-16，
Published：25 January 2026
- 稿件说明：
移动端阅览
王大彪,田勇,李加庆等.310S不锈钢在高温氨气下腐蚀行为的实验研究[J].低碳化学与化工,2026,51(1):150-158.
WANG Dabiao,TIAN Yong,LI Jiaqing,et al.Experimental study on corrosion behaviors of 310S stainless steel under high-temperature ammonia gas[J].Low-Carbon Chemistry and Chemical Engineering,2026,51(1):150-158.
王大彪,田勇,李加庆等.310S不锈钢在高温氨气下腐蚀行为的实验研究[J].低碳化学与化工,2026,51(1):150-158. DOI： 10.12434/j.issn.2097-2547.20250260.
WANG Dabiao,TIAN Yong,LI Jiaqing,et al.Experimental study on corrosion behaviors of 310S stainless steel under high-temperature ammonia gas[J].Low-Carbon Chemistry and Chemical Engineering,2026,51(1):150-158. DOI： 10.12434/j.issn.2097-2547.20250260.
摘要
氨气因其无碳富氢特性，在工业与新能源领域的应用日益广泛。然而，高温工况下管路系统的氨气腐蚀问题成为制约氨产业发展的关键瓶颈。选取310S不锈钢为研究对象，通过搭建高温氨气腐蚀实验平台模拟实际工况，综合运用SEM、EDS和XRD等表征技术，研究了310S不锈钢在不同时间、不同温度氨气作用下的腐蚀行为，并对比分析了碳化钨（WC）涂层对其耐蚀性能的影响。结果表明，310S不锈钢在腐蚀初期的年腐蚀速率较高，随后逐渐降低；如310S不锈钢在450 ℃下腐蚀80 h和480 h，其年腐蚀速率分别为1.68 mm/a和0.53 mm/a。温度对310S不锈钢的腐蚀行为有显著影响，其中温度为450 ℃时腐蚀最为剧烈，如腐蚀时间为80 h时，450 ℃下310S不锈钢的年腐蚀速率为1.68 mm/a，明显高于其在300 ℃（0.79 mm/a）和490 ℃（1.09 mm/a）下的年腐蚀速率。当温度为450 ℃时，WC涂层能够有效抑制活性N渗入310S不锈钢基体，但在490 ℃下WC涂层会发生局部剥落，反而加剧了基体腐蚀。
Abstract
Due to the carbon-free and hydrogen-rich characteristics
ammonia gas is increasingly widely used in industrial and new energy fields. However
the ammonia gas corrosion problem in pipeline systems under high-temperature working conditions has become a key bottleneck restricting the development of the ammonia industry. 310S stainless steel was selected as the research object and a high-temperature ammonia corrosion experimental platform was built to simulate the actual conditions
and characterization techniques such as SEM
EDS and XRD were comprehensively applied to study the corrosion behaviors of 310S stainless steel under ammonia gas at different time and temperatures. The influence of tungsten carbide (WC) coating on corrosion resistance of 310S stainless steel was compared and analyzed. The results show that the annual corrosion rate of 310S stainless steel is relatively high in the early stage of corrosion and then gradually decreases. For example
when 310S stainless steel is corroded at 450 ℃ for 80 h and 480 h
its annual corrosion rates are 1.68 mm/a and 0.53 mm/a
respectively. The temperature has significant impact on the corrosion behaviors of 310S stainless steel. Among them
the corrosion is most intense at 450 ℃. For instance
when the corrosion time is 80 h
the annual corrosion rate of 310S stainless steel at 450 ℃ is 1.68 mm/a. It is significantly higher than its annual corrosion rate at 300 ℃ (0.79 mm/a) and 490 ℃ (1.09 mm/a). When the temperature is 450 ℃
the WC coating can effectively inhibit the penetration of active N into substrate of 310S stainless steel. However
at 490 ℃
the WC coating can experience local peeling
which can aggravate the corrosion of the substrate.
关键词
Keywords
references
黎洁 , 杨一方 , 刘建喆 , 等 . 氨能应用现状、挑战与前景分析 [J ] . 克拉玛依学刊 , 2025 , 15 ( 1 ): 27 - 35 .
LI J , YANG Y F , LIU J Z , et al . Technological advances, challenges, and future pathways of ammonia energy utilization [J ] . Journal of Karamay , 2025 , 15 ( 1 ): 27 - 35 .
李卫东 , 李逸龙 , 滕霖 , 等 . “双碳”目标下的氨能技术与经济性研究进展 [J ] . 化工进展 , 2023 , 42 ( 12 ): 6226 - 6238 .
LI W D , LI Y L , TENG L , et al . Research progress on ammonia energy technology and economy under “carbon emission peak” and “carbon neutrality” targets [J ] . Chemical Industry and Engineering Progress , 2023 , 42 ( 12 ): 6226 - 6238 .
白璐畅 . 氨动力能源系统研究进展及展望 [J ] . 中外能源 , 2025 , 30 ( 3 ): 14 - 20 .
BAI L C . Research progress and prospects of ammonia-powered energy systems [J ] . Sino-Global Energy , 2025 , 30 ( 3 ): 14 - 20 .
许焕焕 , 葛一 , 李强 , 等 . 氨燃料及应用技术研究进展 [J ] . 东北电力大学学报 , 2022 , 42 ( 2 ): 1 - 13 .
XU H H , GE Y , LI Q , et al . Research progress of ammonia fuel and application technology [J ] . Journal of Northeast Electric Power University , 2022 , 42 ( 2 ): 1 - 13 .
崔健 , 聂学选 , 毕玉华 , 等 . 氨气-柴油双燃料发动机燃烧与排放特性研究 [J ] . 内燃机工程 , 2025 , 46 ( 2 ): 36 - 43 .
CUI J , NIE X X , BI Y H , et al . Study on combustion and emission characteristics of an ammonia-diesel dual-fuel engine [J ] . Chinese Internal Combustion Engine Engineering , 2025 , 46 ( 2 ): 36 - 43 .
LEE J H , KIM J H , PARK J H , et al . Studies on properties of laminar premixed hydrogen-added ammonia/air flames for hydrogen production [J ] . International Journal of Hydrogen Energy , 2010 , 35 ( 3 ): 1054 - 1064 .
FRIGO S , GENTILI R . Analysis of the behaviour of a 4-stroke Si engine fuelled with ammonia and hydrogen [J ] . International Journal of Hydrogen Energy , 2013 , 38 ( 3 ): 1607 - 1615 .
GUO Y Q , PAN Z F , AN L . Carbon-free sustainable energy technology: Direct ammonia fuel cells [J ] . Journal of Power Sources , 2020 , 476 : 228454 .
方辉煌 , 程金星 , 罗宇 , 等 . 氨电氧化催化剂及其低温直接氨碱性膜燃料电池性能的研究进展 [J ] . 化工学报 , 2022 , 73 ( 9 ): 3802 - 3814 .
FANG H H , CHENG J X , LUO Y , et al . Recent progress on ammonia oxidation catalysts at anode and their performances in low-temperature direct ammonia alkaline exchange membrane fuel cells [J ] . CIESC Journal , 2022 , 73 ( 9 ): 3802 - 3814 .
赵晓东 , 文婕 , 于明伟 , 等 . 氨能源技术的开发及前景展望 [J ] . 现代化工 , 2023 , 43 ( 4 ): 50 - 53+59 .
ZHAO X D , WEN J , YU M W , et al . Development and prospect of ammonia energy technology [J ] . Modern Chemical Industry , 2023 , 43 ( 4 ): 50 - 53+59 .
王堃旗 , 李树豪 , 席双惠 , 等 . 面向燃气轮机的氨/氢燃料掺混设计及其燃烧特性研究 [J ] . 热能动力工程 , 2024 , 39 ( 7 ): 46 - 53 .
WANG K Q , LI S H , XI S H , et al . Ammonia/hydrogen fuel blending design and its combustion characteristics for gas turbines [J ] . Journal of Engineering for Thermal Energy and Power , 2024 , 39 ( 7 ): 46 - 53 .
IKI N , KURATA O , MATSUNUMA T , et al . Micro gas turbine operation with kerosene and ammonia [C ] //Ammonia Energy Association. Proceedings of the 11th Annual NH3 Fuel Conference . Iowa : Ammonia Energy Association , 2014 : 21 - 24 .
KURATA O , IKI N , INOUE T , et al . Development of a wide range-operable, rich-lean low-NO x combustor for NH 3 fuel gas-turbine power generation [J ] . Proceedings of the Combustion Institute , 2019 , 37 ( 4 ): 4587 - 4595 .
ENGELBRECHT N , CHIUTA S , BESSARABOV D G . A highly efficient autothermal microchannel reactor for ammonia decomposition: Analysis of hydrogen production in transient and steady state regimes [J ] . Journal of Power Sources , 2018 , 386 : 47 - 55 .
GIDDEY S , BADWAL S P S , MUNNINGS C , et al . Ammonia as a renewable energy transportation media [J ] . ACS Sustainable Chemistry & Engineering , 2017 , 5 ( 11 ): 10231 - 10239 .
黎园 , 陈林 , 贾蔚 . 天然气化工副产氢的氢能应用及氢-氨融合发展分析 [J ] . 低碳化学与化工 , 2024 , 49 ( 6 ): 73 - 79+104 .
LI Y , CHEN L , JIA W . Analysis of hydrogen energy application of by-product hydrogen from natural gas chemical industry and development of hydrogen-ammonia fusion [J ] . Low-Carbon Chemistry and Chemical Engineering , 2024 , 49 ( 6 ): 73 - 79+104 .
张润之 , 周家辉 , 徐钢 , 等 . 峰谷电价场景下并网型风光制氢合成氨系统的容量-调度优化分析 [J ] . 动力工程学报 , 2025 , 45 ( 3 ): 443 - 451 .
ZHANG R Z , ZHOU J H , XU G , et al . Capacity-scheduling optimization of grid-connected wind-solar hydrogen production and ammonia synthesis system under peak-to-valley electricity price scenarios [J ] . Journal of Chinese Society of Power Engineering , 2025 , 45 ( 3 ): 443 - 451 .
王龙平 , 林立 , 罗宇 , 等 . 氨的可再生合成与利用研究进展 [J ] . 热能动力工程 , 2024 , 39 ( 10 ): 1 - 9 .
WANG L P , LIN L , LUO Y , et al . Research progress on renewable synthesis and utilization of ammonia [J ] . Journal of Engineering for Thermal Energy and Power , 2024 , 39 ( 10 ): 1 - 9 .
徐也茗 , 郑传明 , 张韫宏 . 氨能源作为清洁能源的应用前景 [J ] . 化学通报 , 2019 , 82 ( 3 ): 214 - 220 .
XU Y M , ZHENG C M , ZHANG Y H , et al . Application prospect of ammonia energy as clean energy [J ] . Chemistry , 2019 , 82 ( 3 ): 214 - 220 .
刘晓华 , 廖晓玲 , 孙琪 , 等 . 310S不锈钢反应器失效原因分析 [J ] . 当代化工 , 2020 , 49 ( 8 ): 1719 - 1722 .
LIU X H , LIAO X L , SUN Q , et al . Failure analysis of 310S stainless steel reaction vessel [J ] . Contemporary Chemical Industry , 2020 , 49 ( 8 ): 1719 - 1722 .
申鹏 , 杨赛 , 李杰 , 等 . 固溶温度对310S耐热奥氏体不锈钢组织和性能的影响 [J ] . 热加工工艺 , 2019 , 48 ( 24 ): 166 - 169 .
SHEN P , YANG S , LI J , et al . Effects of solution temperature on microstructure and properties of heat-resistant austenitic stainless 310S steel [J ] . Hot Working Technology , 2019 , 48 ( 24 ): 166 - 169 .
YAN J B , GU Y F , SUN F , et al . Evolution of microstructure and mechanical properties of a 25Cr-20Ni heat resistant alloy after long-term service [J ] . Materials Science and Engineering , 2016 , 675 ( 15 ): 289 - 298 ．
常红兵 , 孔君华 , 王志奋 , 等 . 焦炉上升管换热器内筒用310S不锈钢高温腐蚀行为研究 [J ] . 燃料与化工 , 2024 , 55 ( 4 ): 20 - 24 .
CHANG H B , KONG J H , WANG Z F , et al . Research on high-temp. corrosion to 310S stainless steel for inner tube of heat exchanger in standpipe [J ] . Fuel & Chemical Processes , 2024 , 55 ( 4 ): 20 - 24 .
王强 , 赵刚 , 白晓东 , 等 . 澳斯迈特炉喷枪用不锈钢310S镍基合金堆焊涂层抗高温耐腐蚀性能研究 [J ] . 黑龙江科学 , 2023 , 14 ( 22 ): 82 - 84+87 .
WANG Q , ZHAO G , BAI X D , et al . Study on the high temperature and corrosion resistance of 310S nickel-based alloy surfacing coating of stainless steel for ausmet furnace gun [J ] . Heilonghang Science , 2023 , 14 ( 22 ): 82 - 84+87 .
NIKLAS A , ROUCO M , GARCIA D , et al . Failure analysis of an AISI 310 stainless steel beam reinforcement fracture during service in a rolling beam furnace [J ] . Engineering Failure Analysis , 2024 , 161 : 108283 .
白智辉 , 高峰 , 王大峰 , 等 . 不同颗粒度碳化钨的WC-17Co等离子涂层组织及摩擦学特性研究 [J ] . 热喷涂技术 , 2015 , 7 ( 3 ): 48 - 53 .
BAI Z H , GAO F WANG D F , et al . Research on different particle size of tungsten carbide on organization and the tribological characteristics of plasma sprayed WC-17Co coating [J ] . Thermal Spray Technology . 2015 , 7 ( 3 ): 48 - 53 .
SOMERS M A J . Development of the compound layer during nitriding and nitrocarburising of iron and iron-carbon alloys [J ] . Thermochemical Surface Engineering of Steels , 2015 , 341 - 372 .
TINA G , SEIJI K , TAKASHI Y , et al . Position-dependent degradation and damage mechanisms of Inconel 600 in an ammonia gas flow environment at elevated temperatures [J ] . Corrosion Science , 2024 , 240 : 112421 .
靳曾博 , 李杨 , 逯宇暄 , 等 . 310S奥氏体不锈钢的离子渗氮 [J ] . 热处理 , 2022 , 37 ( 5 ): 34 - 38 .
JIN Z B , LI Y , LU Y X , et al . Ion nitriding of 310S austenitic stainless steel [J ] . Heat Treatment , 2022 , 37 ( 5 ): 34 - 38 .
兰晔峰 , 王创造 , 胡秋晨 , 等 . 奥氏体不锈钢离子渗N组织及性能 [J ] . 兰州理工大学学报 , 2020 , 46 ( 1 ): 7 - 12 .
LAN Y F , WANG C Z , HU Q C , et al . Microstructure and performance of austenitic stainlesssteel with ionic permeation of N [J ] . Journal of Lanzhou University of Technology , 2020 , 46 ( 1 ): 7 - 12 .
陈嘉砚 , 杨卓越 , 杨武 , 等 . 双相不锈钢中 σ 相的形成特点及其对性能的影响 [J ] . 钢铁研究学报 , 2006 , ( 8 ): 1 - 4 .
CHEN J Y , YANG Z Y , YANG W , et al . Characteristic of phase σ precipitation and its effects on behavior in duplex stainless steel [J ] . Journal of Iron and Steel Rescarch , 2006 , ( 8 ): 1 - 4 .
陈蓉 , 华浩 , 吴安如 , 等 . 铬含量对00Cr25Ni7Mo3N双相不锈钢力学性能及耐腐蚀性能的影响 [J ] . 机械工程材料 , 2016 , 40 ( 2 ): 26 - 28 .
CHEN R , HUA H , WU A R , et al . Effects of chromium content on mechanical properties and corrosion resistance of 00Cr25Ni7Mo3N duplex stainless steel [J ] . Materials for Mechanical Engineering , 2016 , 40 ( 2 ): 26 - 28 .
CHE H L , YANG X , LEI M K , et al . Co-existence of γ ’ N phase and γ N phase on nitrided austenitic Fe-Cr-Ni alloys. III. An investigation of the evolution of long-range ordered domains [J ] . Acta Materialia , 2023 , 253 : 118971 ．
梁飞龙 , 李凯玥 , 师文庆 , 等 . 预热与重熔处理对激光熔覆Ni基/WC涂层的影响 [J ] . 中国激光 , 2024 , 51 ( 20 ): 110 - 123 .
LIANG F L , LI K Y , SHI W Q , et al . Effect of preheating and laser remelting on laser cladding of Ni-based/WC coating [J ] . Chinese Journal of Lasers , 2024 , 51 ( 20 ): 110 - 123 .
李加庆 , 胡磊 , 刘子涵 , 等 . 高温氨腐蚀行为、评价与防护技术研究进展 [J/OL ] . 化工进展 , 1 - 15 [ 2025-07-09 ] . DOI: 10.16085/j.issn.1000-6613.2025-0238 http://dx.doi.org/10.16085/j.issn.1000-6613.2025-0238 .
LI J Q , HU L , LIU Z H , et al . High-temperature ammonia corrosion behavior, evaluation andprotection technology [J/OL ] . Chemical Industry and Engineering Progress , 1 - 15 [ 2025-07-09 ] . DOI: 10.16085/j.issn.1000-6613.2025-0238 http://dx.doi.org/10.16085/j.issn.1000-6613.2025-0238 .
0
Views
0
下载量
0
CNKI被引量
- L-PDFDownload
- XMLDownload
- Meta-XMLDownload
- BibTeXDownload
- EndnoteDownload
- RefMan Download
- NoteExpressDownload
- NoteFirstDownload
Publicity Resources
Related Articles
Related Author
Related Institution
- Postal code：610225
- Tel：028-85964717 Email：236764603@qq.com
- Technical support is provided by Beijing Founder electronics co., LTD 蜀ICP备12008600号-10
蜀公网安备51012202001533 - It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
- Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.
- Total Visits：373197 Visits Today：20
