Study on catalytic performances of Ce and Mn modified Co/AC for producing low carbon alcohols from syngas

WU Luyao; HAN Chun; XU Yefan; HUANG Wei

doi:10.12434/j.issn.2097-2547.20250151

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Study on catalytic performances of Ce and Mn modified Co/AC for producing low carbon alcohols from syngas

更新时间：2026-02-13

- Study on catalytic performances of Ce and Mn modified Co/AC for producing low carbon alcohols from syngas
- Vol. 51, Issue 2, Pages: 66-74(2026)
- 作者机构：
  
  太原理工大学化学与化工学院省部共建煤基能源清洁高效利用国家重点实验室，山西太原 030024
- 作者简介：
- 基金信息：
- DOI：10.12434/j.issn.2097-2547.20250151
  CLC： TQ426;TQ223.1
- Received：03 April 2025，
  
  Revised：2025-05-12，
  
  Published：25 February 2026
- 稿件说明：
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武璐瑶,韩春,许烨凡等.Ce和Mn改性Co/AC催化合成气制低碳醇性能研究[J].低碳化学与化工,2026,51(2):66-74.

WU Luyao,HAN Chun,XU Yefan,et al.Study on catalytic performances of Ce and Mn modified Co/AC for producing low carbon alcohols from syngas[J].Low-Carbon Chemistry and Chemical Engineering,2026,51(2):66-74.
武璐瑶,韩春,许烨凡等.Ce和Mn改性Co/AC催化合成气制低碳醇性能研究[J].低碳化学与化工,2026,51(2):66-74. DOI： 10.12434/j.issn.2097-2547.20250151.

WU Luyao,HAN Chun,XU Yefan,et al.Study on catalytic performances of Ce and Mn modified Co/AC for producing low carbon alcohols from syngas[J].Low-Carbon Chemistry and Chemical Engineering,2026,51(2):66-74. DOI： 10.12434/j.issn.2097-2547.20250151.

摘要

合成气制低碳醇（C

醇）因其良好的经济性而受到了广泛关注。Co基催化剂是合成气制低碳醇的主要催化剂之一，但该催化剂目前存在低碳醇选择性较低的问题。采用共沉淀法分别制备了Ce、Mn改性Co/AC催化剂（Ce-Co/AC和Mn-Co/AC，Co质量分数为15.0%，Ce、Mn质量分数均为7.5%），使用XRD、N

吸/脱附和H

-TPR等表征了催化剂的结构，并在温度为250 ℃、压力为3.0 MPa和合成气（

(CO) = 2:1）流量为75 mL/min的条件下评价了催化剂的催化合成气制低碳醇性能（以反应7 d后的平均值计）。结果表明，与Co/AC相比，引入助剂Ce、Mn均可提高催化剂表面Co物种的分散性及减小Co

物种的晶粒尺寸。其中，Mn-Co/AC的表面Co

物种含量（物质的量分数）为66.0%。在实验条件下，Ce-Co/AC的CO转化率为2.29%，总醇选择性为32.03%，

(低碳醇)/

(总醇)为68.06%；Mn-Co/AC表现出了更好的催化性能，其CO转化率为3.99%，总醇选择性为33.23%，

(低碳醇)/

(总醇)为79.36%。

Abstract

Producing low-carbon alcohols (C

alcohols) from syngas have received extensive attention due to its excellent economic property. The Co-based catalyst is one of the main catalysts for producing low-carbon alcohols from syngas

but the Co-based catalyst currently has the problem of low selectivity for low-carbon alcohols. Using the co-precipitation method

Ce and Mn modified Co/AC catalysts (Ce-Co/AC a

nd Mn-Co/AC with Co mass fraction of 15.0% and Ce or Mn mass fraction of 7.5%) were prepared

respectively. The structures of the catalysts were characterized by XRD

adsorption/desorption and H

-TPR

and the catalytic performances of catalysts for producing low-carbon alcohols from syngas (calculating by the average values after 7 d of reaction) under the conditions of temperature of 250 ℃

pressure of 3.0 MPa and syngas (

(CO) = 2:1) flow rate of 75 mL/min were evaluated. The results show that compared with Co/AC

the introduction of the additives Ce and Mn both can improve the dispersion of Co species on the catalyst surface and reduce the crystal size of Co

species. Among them

the content (mole fraction) of surface Co

species in Mn-Co/AC is 66.0%. Under the experimental conditions

the CO conversion rate of Ce-Co/AC is 2.29%

and the total alcohol selectivity is 32.03% and

(low-carbon alcohols)/

(total alcohols) is 68.06%. Mn-Co/AC exhibits better catalytic performance with CO conversion rate of 3.99%

total alcohol selectivity of 33.23% and

(low-carbon alcohols)/

(total alcohols) of 79.36%.

关键词

Keywords

references

LIU Y J , ZUO Z J , LI C , et al . Effect of preparation method on CuZnAl catalysts for ethanol synthesis from syngas [J ] . Applied Surface Science , 2015 , 356 : 124 - 127 .

XUE X X , WENG Y J , YANG S C , et al . Research progress of catalysts for synthesis of low-carbon alcohols from synthesis gas [J ] . RSC Advances , 2021 , 11 ( 11 ): 6163 - 6172 .

盛海兵 , 孙燕 , 孙启文 . Mn助剂对KFeCuZn催化剂结构及其CO 2 加氢制C 2+ 醇催化性能的影响 [J ] . 低碳化学与化工 , 2025 , 50 ( 5 ): 32 - 39 .

SHENG H B , SUN Y , SUN Q W . Effects of Mn additive on structures of KFeCuZn catalysts and their catalytic performances for CO 2 hydrogenation to C 2+ alcohols [J ] . Low-Carbon Chemistry and Chemical Engineering , 2025 , 50 ( 5 ): 32 - 39 .

高梦迪 , 武璐瑶 , 郝家荣 , 等 . Al组分含量对CuZnAl催化剂CO加氢制乙醇和高级醇性能影响 [J ] . 低碳化学与化工 , 2024 , 49 ( 8 ): 28 - 37+88 .

GAO M D , WU L Y , HAO J R , et al . Effects of Al component contents on performances of CuZnAl catalysts for CO hydrogenation to ethanol and higher alcohols [J ] . Low-Carbon Chemistry and Chemical Engineering , 2024 , 49 ( 8 ): 28 - 37+88 .

刘雷强 , 边仲凯 , 顾尹婷 , 等 . 分步添加AlOOH溶胶对Cu/Zn/Al催化剂催化合成气制乙醇的影响 [J ] . 天然气化工—C1化学与化工 , 2019 , 44 ( 6 ): 34 - 40 .

LIU L Q , BIAN Z K , GU Y T , et al . Effect of two steps addition of AlOOH on CuZnAl catalysts for the synthesis of ethanol from syngas [J ] . Natural Gas Chemical Industry , 2019 , 44 ( 6 ): 34 - 40 .

WANG J C , LIU Z X , ZHANG R G , et al . Ethanol synthesis from syngas on the stepped Rh(211) surface: Effect of surface structure and composition [J ] . The Journal of Physical Chemistry C , 2014 , 118 ( 39 ): 22691 - 22701 .

LIU G B , YANG G H , PENG X B , et al . Recent advances in the routes and catalysts for ethanol synthesis from syngas [J ] . Chemical Society Reviews , 2022 , 51 ( 13 ): 5606 - 5659 .

SURISETTY V R , DALAI A K , KOZINSKI J . Alcohols as alternative fuels: An overview [J ] . Applied Catalysis A: General , 2011 , 404 ( 1/2 ): 1 - 11 .

WANG J M , ZHONG H X , AN K , et al . Co-Ni alloy nanoparticles on La-doped SiO 2 for direct ethanol synthesis from syngas [J ] . Industrial & Engineering Chemistry Research , 2020 , 59 ( 44 ): 19539 - 19552 .

XU X D , DOESBURG E B M , SCHOLTEN J J F . Synthesis of higher alcohols from syngas-recently patented catalysts and tentative ideas on the mechanism [J ] . Catalysis Today , 1987 , 2 ( 1 ): 125 - 170 .

SONG P F , WANG J M , LIU G L , et al . S elf-optimized and renewable Ni-Co alloy@Co-Co 2 C catalyst for higher alcohols synthesis from syngas [J ] . International Journal of Hydrogen Energy , 2022 , 47 ( 38 ): 16933 - 16948 .

CUI W G , LI Y T , ZHANG H B , et al . In situ encapsulated Co/MnO x nanoparticles inside quasi-MOF-74 for the higher alcohols synthesis from syngas [J ] . Applied Catalysis B: Environmental , 2020 , 278 : 119262 .

GUO S X , LIU G L , ZHANG Y , et al . Oxygen vacancies boosted Co-Co 2 C catalysts for higher alcohols synthesis from syngas [J ] . Applied Surface Science , 2022 , 576 : 151846 .

DU H , ZHU H J , LIU T , et al . Higher alcohols synthesis via CO hydrogenation on Fe-promoted Co/AC catalysts [J ] . Catalysis Today , 2017 , 281 : 549 - 558 .

HAN C , LI L , LIU J , et al . Novel designing concept of CoCu catalyst with limited methanol formation in higher alcohol synthesis from syngas [J ] . International Journal of Hydrogen Energy , 2024 , 73 : 373 - 380 .

PEI Y P , JIAN S P , CHEN Y Y , et al . Synthesis of higher alcohols by the Fischer-Tropsch reaction over activated carbon supported CoCuMn catalysts [J ] . RSC Advances , 2015 , 5 ( 93 ): 76330 - 76336 .

GAO S , LIU N , LIU J , et al . Synthesis of higher alcohols by CO hydrogenation over catalysts derived from LaCo 1- x Mn x O 3 perovskites: Effect of the partial substitution of Co by Mn [J ] . Fuel , 2020 , 261 : 116415 .

BAI K Y , HUANG J H , TIAN M , et al . Cerium doped Co/AC catalysts for higher alcohols synthesis from syngas [J ] . Molecular Catalysis , 2023 , 546 : 113270 .

GUO D Y , CAI B , KANG R , et al . Selective hydrodeoxygenation of guaiacol to cyclohexanol over Ni x Co y Al z catalysts under mild conditions [J ] . Journal of Analytical and Applied Pyrolysis , 2023 , 170 : 105876 .

GE F , XIA H H , LI J , et al . Selective hydrodeoxygenation of guaiacol to cyclohexanol over core-shell Co x @C@Ni catalysts under mild condition [J ] . Fuel Processing Technology , 2023 , 245 : 107729 .

DENG S Y , CHU W , XU H Y , et al . Effects of impregnation sequence on the microstructure and performances of Cu-Co based catalysts for the synthesis of higher alcohols [J ] . Journal of Natural Gas Chemistry , 2008 , 17 ( 4 ): 369 - 373 .

SMITH M L , KUMAR N , SPIVEY J J . CO adsorption behavior of Cu/SiO 2 , Co/SiO 2 , and CuCo/SiO 2 catalysts studied by in situ DRIFTS [J ] . The Journal of Physical Chemistry C , 2012 , 116 ( 14 ): 7931 - 7939 .

KOVANDA F , ROJKA T , DOBEŠOVÁ J , et al . Mixed oxides obtained from Co and Mn containing layered double hydroxides: Preparation, characterization, and catalytic properties [J ] . Journal of Solid State Chemistry , 2006 , 179 ( 3 ): 812 - 823 .

DU H , ZHU H J , CHEN X K , et al . Study on CaO-promoted Co/AC catalysts for synthesis of higher alcohols from syngas [J ] . Fuel , 2016 , 182 : 42 - 49 .

ARNOLDY P , MOULIJN J A . Temperature-programmed reduction of CoOAl 2 O 3 catalysts [J ] . Journal of Catalysis , 1985 , 93 ( 1 ): 38 - 54 .

ZHAO L , DUAN J N , ZHANG Q L , et al . Preparation, structural characteristics, and catalytic performance of Cu-Co alloy supported on Mn-Al oxide for higher alcohol synthesis via syngas [J ] . Industrial & Engineering Chemistry Research , 2018 , 57 ( 44 ): 14957 - 14966 .

XIAO K , QI X Z , BAO Z H , et al . CuFe, CuCo and CuNi nanoparticles as catalysts for higher alcohol synthesis from syngas: A comparative study [J ] . Catalysis Science & Technology , 2013 , 3 ( 6 ): 1591 - 1602 .

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