Influence of ZSM-5 after hydrophobic modification on catalytic performances of NaFe/ZSM-5 for CO<sub>2</sub> hydrogenation to sustainable aviation fuels

XUE Haoqiang; LI Wenhui; LIU Bingyu; LIU Min; GUO Xinwen

doi:10.12434/j.issn.2097-2547.20250148

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Influence of ZSM-5 after hydrophobic modification on catalytic performances of NaFe/ZSM-5 for CO₂ hydrogenation to sustainable aviation fuels

更新时间：2026-02-02

- Influence of ZSM-5 after hydrophobic modification on catalytic performances of NaFe/ZSM-5 for CO₂ hydrogenation to sustainable aviation fuels
- Vol. 51, Issue 1, Pages: 16-23(2026)
- 作者机构：
  
  大连理工大学化工学院，精细化工全国重点实验室，辽宁大连 116024
- 作者简介：
- 基金信息：
- DOI：10.12434/j.issn.2097-2547.20250148
  CLC： TQ426
- Received：01 April 2025，
  
  Revised：2025-04-11，
  
  Published：25 January 2026
- 稿件说明：
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薛浩强,李文慧,刘炳昱等.疏水改性ZSM-5对双功能催化剂NaFe/ZSM-5催化CO₂加氢制绿色航空煤油性能的影响[J].低碳化学与化工,2026,51(1):16-23.

XUE Haoqiang,LI Wenhui,LIU Bingyu,et al.Influence of ZSM-5 after hydrophobic modification on catalytic performances of NaFe/ZSM-5 for CO₂ hydrogenation to sustainable aviation fuels[J].Low-Carbon Chemistry and Chemical Engineering,2026,51(1):16-23.
薛浩强,李文慧,刘炳昱等.疏水改性ZSM-5对双功能催化剂NaFe/ZSM-5催化CO₂加氢制绿色航空煤油性能的影响[J].低碳化学与化工,2026,51(1):16-23. DOI： 10.12434/j.issn.2097-2547.20250148.

XUE Haoqiang,LI Wenhui,LIU Bingyu,et al.Influence of ZSM-5 after hydrophobic modification on catalytic performances of NaFe/ZSM-5 for CO₂ hydrogenation to sustainable aviation fuels[J].Low-Carbon Chemistry and Chemical Engineering,2026,51(1):16-23. DOI： 10.12434/j.issn.2097-2547.20250148.

摘要

加氢制绿色航空煤油不仅可以助力实现 “碳中和”，也有利于航空业的可持续发展。但CO

为惰性小分子难以活化、C—C耦合定向生成绿色航空煤油组分（C

烃类）难度较高等问题，给催化剂设计带来了较大挑战。采用丙基三甲氧基硅烷（PTMS）对ZSM-5分子筛进行了疏水改性，成功制备了具有不同水接触角的疏水改性ZSM-5分子筛，并将其与Na-Fe

组合构筑了双功能催化剂用于CO

加氢反应。结果表明，丙基三甲氧基硅烷改性不仅能够提高ZSM-5分子筛的疏水性，还可以通过疏水基团对ZSM-5分子筛外表面酸性位点的覆盖作用，抑制长链烃产物在分子筛表面的裂解，提升产物中绿色航空煤油组分选择性。在320 ℃、3 MPa以及

(CO

) = 3:1反应条件下，NaFe/Z5-0.5PTMS在CO

加氢反应中催化性能最佳，CO

转化率为32.6%，CO选择性仅为9.9%，绿色航空煤油组分选择性为38.8%。

Abstract

hydrogenat

ion to sustainable aviation fuels can not only help achieve “carbon neutrality”

but also support the sustainable development of the aviation industry. However

due to the difficulty in activating CO

as an inert molecule and the difficulty in generating sustainable aviation fuels (C

hydrocarbons) by C—C coupling

catalyst design has faced significant challenges. Propyl trimethoxysilane (PTMS) was used to modify ZSM-5 zeolites

and ZSM-5 zeolites with varying water contact angles were successfully prepared after hydrophobic modification. They were combined with Na-Fe

to construct bifunctional catalysts for CO

hydrogenation. The results show that propyl trimethoxysilane modification can not only enhance the hydrophobicity of ZSM-5 zeolites

but also inhibit the cracking of long-chain hydrocarbons on the surface of ZSM-5 zeolites to improve the sustainable aviation fuels selectivity by the acidic sites coverage on the outer surface of ZSM-5 zeolites with hydrophobic groups. Under the reaction conditions of 320 ℃

3 MPa and

(CO

) = 3:1

NaFe/Z5-0.5PTMS has the best catalytic performance for CO

hydrogenation

with the CO

conversion rate of 32.6%

CO selectivity of 9.9% and sustainable aviation fuels selectivity of 38.8%.

关键词

Keywords

references

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Influence of ZSM-5 after hydrophobic modification on catalytic performances of NaFe/ZSM-5 for CO2 hydrogenation to sustainable aviation fuels

DOI：10.12434/j.issn.2097-2547.20250148

摘要

Abstract

关键词

Keywords

references

Influence of ZSM-5 after hydrophobic modification on catalytic performances of NaFe/ZSM-5 for CO₂ hydrogenation to sustainable aviation fuels