Research progress of metal oxide/zeolite catalysts for propane dehydrogenation to propylene

DAI Yi; WANG Kaijie; ZHANG Yaoyuan; WU Qin; SHI Daxin; CHEN Kangcheng; YANG Yanpeng; LI Hansheng

doi:10.12434/j.issn.2097-2547.20250108

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Research progress of metal oxide/zeolite catalysts for propane dehydrogenation to propylene

更新时间：2025-08-25

- Research progress of metal oxide/zeolite catalysts for propane dehydrogenation to propylene
- Vol. 50, Issue 8, Pages: 106-122(2025)
- 作者机构：
  
  1.北京理工大学化学与化工学院，北京 100018
  2.中石化石油化工科学研究院有限公司，北京 100083
- 作者简介：
- 基金信息：
- DOI：10.12434/j.issn.2097-2547.20250108
  CLC： TQ032.4;O643.3
- Received：17 March 2025，
  
  Revised：10 April 2025，
  
  Published：25 August 2025
- 稿件说明：
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代怡,王凯杰,张耀远等.丙烷脱氢制丙烯用金属氧化物/分子筛催化剂研究进展[J].低碳化学与化工,2025,50(8):106-122.

DAI Yi,WANG Kaijie,ZHANG Yaoyuan,et al.Research progress of metal oxide/zeolite catalysts for propane dehydrogenation to propylene[J].Low-Carbon Chemistry and Chemical Engineering,2025,50(8):106-122.
代怡,王凯杰,张耀远等.丙烷脱氢制丙烯用金属氧化物/分子筛催化剂研究进展[J].低碳化学与化工,2025,50(8):106-122. DOI： 10.12434/j.issn.2097-2547.20250108.

DAI Yi,WANG Kaijie,ZHANG Yaoyuan,et al.Research progress of metal oxide/zeolite catalysts for propane dehydrogenation to propylene[J].Low-Carbon Chemistry and Chemical Engineering,2025,50(8):106-122. DOI： 10.12434/j.issn.2097-2547.20250108.

摘要

丙烷脱氢制丙烯反应具有原料来源丰富、产物组成简单且易分离等优点，是最具前景的丙烯生产方法之一。传统的Pt基催化剂存在成本高、易烧结等问题。近年来，分子筛因其有序的孔道结构、较大的比表面积、良好的热稳定性，以及酸性可调等特点，被视为负载金属氧化物活性物种的理想载体之一。总结了金属（Cr、Ga和Zn等）氧化物催化剂的活性位点的结构调控策略，并从不同拓扑结构出发详细介绍了常见分子筛在丙烷脱氢制丙烯反应中的应用。最后，对金属氧化物/分子筛催化剂的未来发展方向进行了展望。

Abstract

The reaction of propane dehydrogenation to propylene has the advantages of abundant raw material sources

simple product compositions and easy separation. It is one of the most promising methods for propylene production. Traditional Pt-based catalysts have problems such as high cost and easy sintering. In recent years

molecular sieves have been considered as one of the ideal carriers for loading active species of metal oxides due to their ordered pore structures

high specific surface areas

good thermal stabilities and adjustable acidities. The structural regulation strategies of the active sites of metal (such as Cr

Ga and Zn) oxide catalysts were summarized

and the applications of common molecular sieves in propane dehydrogenation to propylene were introduced in detail starting from different topological structures. Finally

the future development directions of metal oxide/molecular sieve catalysts were prospected.

关键词

Keywords

references

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