Research progress on reaction pathways and catalysts for CO<sub>2</sub> hydrogenation to aromatics

HE Shuisen; WANG Li; WANG Hanlu; LIN Cunhui; SHAN Shufeng; FAN Qinzhen; ZENG Xingye

doi:10.12434/j.issn.2097-2547.20250096

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Research progress on reaction pathways and catalysts for CO₂ hydrogenation to aromatics

更新时间：2026-02-02

- Research progress on reaction pathways and catalysts for CO₂ hydrogenation to aromatics
- Vol. 51, Issue 1, Pages: 1-15(2026)
- 作者机构：
  
  广东石油化工学院化学工程学院，广东茂名 525000
- 作者简介：
- 基金信息：
- DOI：10.12434/j.issn.2097-2547.20250096
  CLC： TQ241.1
- Received：11 March 2025，
  
  Revised：2025-04-10，
  
  Published：25 January 2026
- 稿件说明：
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何水森,王丽,王寒露等.CO₂加氢制芳烃反应路径与催化剂研究进展[J].低碳化学与化工,2026,51(1):1-15.

HE Shuisen,WANG Li,WANG Hanlu,et al.Research progress on reaction pathways and catalysts for CO₂ hydrogenation to aromatics[J].Low-Carbon Chemistry and Chemical Engineering,2026,51(1):1-15.
何水森,王丽,王寒露等.CO₂加氢制芳烃反应路径与催化剂研究进展[J].低碳化学与化工,2026,51(1):1-15. DOI： 10.12434/j.issn.2097-2547.20250096.

HE Shuisen,WANG Li,WANG Hanlu,et al.Research progress on reaction pathways and catalysts for CO₂ hydrogenation to aromatics[J].Low-Carbon Chemistry and Chemical Engineering,2026,51(1):1-15. DOI： 10.12434/j.issn.2097-2547.20250096.

摘要

在全球气候变暖与化石能源枯竭的双重挑战下，CO

加氢制芳烃为碳资源循环利用提供了绿色途径。CO

加氢制芳烃主要聚焦于CO

改性费托合成（CO

-FTS）和甲醇介导两种路径。概述了CO

-FTS和甲醇介导的反应机理和关键中间产物，总结了催化剂结构设计与优化方面的最新进展。重点介绍了双功能催化剂的助剂类型、载体结构、沸石分子筛的酸性与结构调控以及双功能催化剂中活性组分距离对催化性能的影响，指出CO

加氢与芳构化反应的协同作用以及加氢中间产物的形成是影响催化剂性能的关键因素。最后对CO

加氢制芳烃催化剂的应用前景进行了展望，以期为推动绿色化工技术的发展提供参考。

Abstract

Under the dual challenges of global warming and fossil energy depletion

hydrogenation to aromatics provides a green pathway for carbon resource recycling. CO

hydrogenation to aromatics mainly focuses on two reaction pathways: CO

-modified Fischer-Tropsch synthesis (CO

-FTS) and methanol-mediated pathway. The reaction mechanisms and key intermediates of CO

-FTS and methanol-mediated pathways for the production of aromatics were reviewed

and the recent progress on catalyst structure design and optimization was summarized. The effects of additive type

support structure

acidity and structure modulation of zeolite molecular sieves

and the distance of active components in the bifunctional catalysts on the catalytic performance of CO

hydrogenation to aromatics were highlighted. The synergistic effect of CO

hydrogenation and arylation reaction as well as the formation of hydrogenation intermediates are the key factors influencing the performance of the catalysts. Finally

the application prospects of the catalysts for CO

hydrogenation to aromatics were discussed

providing a reference for promoting the development in green chemical technology.

关键词

Keywords

references

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Research progress on reaction pathways and catalysts for CO2 hydrogenation to aromatics

DOI：10.12434/j.issn.2097-2547.20250096

摘要

Abstract

关键词

Keywords

references

Research progress on reaction pathways and catalysts for CO₂ hydrogenation to aromatics