Research progress on in situ reconstruction of p-block metal-based catalysts for electrocatalytic CO<sub>2</sub> reduction to formic acid

DONG Zhiwei; JIA Yaling; LI Wenying

doi:10.12434/j.issn.2097-2547.20250089

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Research progress on in situ reconstruction of p-block metal-based catalysts for electrocatalytic CO₂ reduction to formic acid

更新时间：2025-12-25

- Research progress on in situ reconstruction of p-block metal-based catalysts for electrocatalytic CO₂ reduction to formic acid
- Vol. 50, Issue 12, Pages: 1-10(2025)
- 作者机构：
  
  太原理工大学省部共建煤基能源清洁高效利用国家重点实验室，山西太原 030024
- 作者简介：
- 基金信息：
- DOI：10.12434/j.issn.2097-2547.20250089
  CLC： TQ426
- Received：07 March 2025，
  
  Revised：2025-03-25，
  
  Published：25 December 2025
- 稿件说明：
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董志伟,加亚玲,李文英.电催化CO₂还原制甲酸p区金属基催化剂原位重构的研究进展[J].低碳化学与化工,2025,50(12):1-10.

DONG Zhiwei,JIA Yaling,LI Wenying.Research progress on in situ reconstruction of p-block metal-based catalysts for electrocatalytic CO₂ reduction to formic acid[J].Low-Carbon Chemistry and Chemical Engineering,2025,50(12):1-10.
董志伟,加亚玲,李文英.电催化CO₂还原制甲酸p区金属基催化剂原位重构的研究进展[J].低碳化学与化工,2025,50(12):1-10. DOI： 10.12434/j.issn.2097-2547.20250089.

DONG Zhiwei,JIA Yaling,LI Wenying.Research progress on in situ reconstruction of p-block metal-based catalysts for electrocatalytic CO₂ reduction to formic acid[J].Low-Carbon Chemistry and Chemical Engineering,2025,50(12):1-10. DOI： 10.12434/j.issn.2097-2547.20250089.

摘要

通过电催化CO

还原反应（ECO

RR）制备高附加值化学品和燃料，是实现“双碳”目标的有效途径，其中甲酸（HCOOH）是极具经济价值的产物之一。然而，CO

分子的热力学稳定性及ECO

RR中的多质子耦合电子转移过程使反应活性与产物选择性受限。p区金属（如Bi、In和Sn等）基催化剂凭借适宜的中间体OCHO*吸附强度，在ECO

RR制HCOOH中表现出较大的潜力。在电化学工作条件下，催化剂表面会因电场诱导、界面反应及化学环境改变而发生重构，这种结构演变使得揭示催化剂的结构与催化性能关系较为困难。鉴于此，聚焦于p区金属基催化剂在ECO

RR过程中的原位重构行为，系统分析了催化剂重构影响因素、重构类型以及表征技术，深入探讨了催化剂在动态工况下的构效关系，总结了在ECO

RR制HCOOH过程中p区金属基催化剂差异化的重构路径与活性位点演化规律，提出了构建“理论计算-机器学习-原位实验”体系的建议，可为设计高稳定性、高产物选择性的重构催化剂提供参考。

Abstract

Electrocatalytic CO

reduction reaction (ECO

RR) for producing high value-added chemicals and fuels is an effective approach to achieving “dual carbon” goals

with formic acid (HCOOH) being one of the most economically valuable products. However

the thermodynamic stability of CO

molecules and the multi-proton-electron coupling processes during ECO

RR limit the reaction activity and product selectivity. p-block metal-based (such as Bi

etc.) catalysts show significant potential in ECO

RR to HCOOH

owing to their appropriate key formic acid intermediate OCHO* adsorption capability. Under electrochemical operating conditions

the catalyst surface undergoes reconstruction induced by electric fields

interfacial reactions and changes of chemical environments. This reconstruction makes it difficult to reveal the relationship between the stru

cture and catalytic performance of catalysts. In light of this

focusing on the in situ reconstruction behavior of p-block metal-based catalysts during ECO

the influencing factors

reconstruction types and characterization techniques were systematically analyzed

and the structure-performance relationships of catalysts under dynamic operating conditions were explored

and different reconstruction pathways and evolution laws of active sites of p-block metal-based catalysts during ECO

RR to HCOOH were summarized. A suggestion was put forward to construct a “theoretical calculation-machine learning-in situ experiment” system

providing a reference for designing reconstructed catalysts with high stability and product selectivity.

关键词

Keywords

references

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Research progress on in situ reconstruction of p-block metal-based catalysts for electrocatalytic CO2 reduction to formic acid

DOI：10.12434/j.issn.2097-2547.20250089

摘要

Abstract

关键词

Keywords

references

Research progress on in situ reconstruction of p-block metal-based catalysts for electrocatalytic CO₂ reduction to formic acid