Research progress on solar-driven conversion of natural gas to chemicals

ZHANG Xun; YU Wang; CAO Yuehan; ZHENG Heng; WANG Dajun; ZHOU Ying

doi:10.12434/j.issn.2097-2547.20250035

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Research progress on solar-driven conversion of natural gas to chemicals

更新时间：2025-08-25

- Research progress on solar-driven conversion of natural gas to chemicals
- Vol. 50, Issue 8, Pages: 67-78(2025)
- 作者机构：
  
  1.西南石油大学油气藏地质及开发工程全国重点实验室，四川成都 610500
  2.西南石油大学新能源与材料学院，四川成都 610500
  3.西南化工研究设计院有限公司多孔材料与分离转化全国重点实验室，国家碳一化学工程技术研究中心，四川成都 610225
- 作者简介：
- 基金信息：
- DOI：10.12434/j.issn.2097-2547.20250035
  CLC： TE09
- Received：21 January 2025，
  
  Revised：17 February 2025，
  
  Published：25 August 2025
- 稿件说明：
移动端阅览
张荀,余旺,曹玥晗等.太阳能驱动天然气转化制化学品研究进展[J].低碳化学与化工,2025,50(8):67-78.

ZHANG Xun,YU Wang,CAO Yuehan,et al.Research progress on solar-driven conversion of natural gas to chemicals[J].Low-Carbon Chemistry and Chemical Engineering,2025,50(8):67-78.
张荀,余旺,曹玥晗等.太阳能驱动天然气转化制化学品研究进展[J].低碳化学与化工,2025,50(8):67-78. DOI： 10.12434/j.issn.2097-2547.20250035.

ZHANG Xun,YU Wang,CAO Yuehan,et al.Research progress on solar-driven conversion of natural gas to chemicals[J].Low-Carbon Chemistry and Chemical Engineering,2025,50(8):67-78. DOI： 10.12434/j.issn.2097-2547.20250035.

摘要

在“双碳”目标推动下，能源结构正加速向清洁化、低碳化方向转型。相较于煤炭和石油，天然气具有较低的碳氢比，是最清洁的化石能源之一，广泛应用于制氢及高值含碳化学品的生产，在构建新型能源体系中发挥着关键作用。虽然目前工业广泛采用的天然气蒸汽重整制氢以及两段天然气制甲醇等技术成熟，但普遍存在工艺复杂、能耗高的问题，所导致的碳排放难以契合低碳发展的要求。太阳能因具有资源丰富、清洁低碳和可再生等优势，为天然气转化制化学品的低碳化发展提供了新的解决思路。一方面，可通过太阳能替代传统化石能源作为供能方式，降低生产过程中的碳排放量；另一方面，借助太阳能驱动的反应路径实现反应优化，有望简化传统工艺流程。综述了太阳能间接驱动与直接驱动天然气转化制化学品的最新研究进展，重点阐述了太阳能驱动天然气碳氢联产与太阳能直接驱动天然气转化制化学品等技术的原理与研究现状，并对催化材料与反应系统的设计提出了展望，同时指出太阳能未来亦可与其他新能源形式协同使用，可为天然气转化制化学品的绿色低碳转型提供参考。

Abstract

Under the promotion of the “carbon peaking and carbon neutrality” goals

the energy structure is accelerating its transition towards cleaner and low-carbon alternatives. Compared with coal and oil

natural gas has a lower carbon-to-hydrogen ratio and is considered one of the cleanest fossil fuels. It plays a crucial role in building a new energy system and is widely applied in hydrogen production and the synthesis of high-value carbon-containing chemicals. Although industrially mature technologies such as steam methane reforming and two-stage natural gas-to-methanol synthesis are commonly used

they generally suffer from complex processes and high energy consumption

resulting in carbon emissions that fall short of low-carbon development requirements. Solar energy

characterized by its abundance

cleanliness

low-carbon nature and renewability

offers a novel pathway for the low-carbon development of natural gas-based chemical production. On one hand

solar energy can replace traditional fossil fuels as the energy source

thereby reducing carbon emissions during production. On the other hand

solar-driven reaction pathways can help optimize reactions and simplify traditional processes. Recent research progress on both indirect and direct solar-driven natural gas conversion to chemicals was reviewed

with a particular focus on the principles and current progress on solar-driven carbon-hydrogen co-production and solar-driven chemical production from natural gas. Prospects were also presented for the design of catalytic materials and reaction systems. Simultaneously

it is pointed out that solar energy can also be used in conjunction with other new energy forms in the future

which can provide aims to provide references for the green and low-carbon transformation of natural gas-based chemical production.

关键词

Keywords

references

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