Current status of dry reforming of methane and carbon dioxide technology and research progress of catalysts

LI Xueqin; WANG Gengyi; WEI Xiao; LIU Peng; WANG Zhiwei; LEI Tingzhou

doi:10.12434/j.issn.2097-2547.20240489

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Current status of dry reforming of methane and carbon dioxide technology and research progress of catalysts

更新时间：2025-05-29

- Current status of dry reforming of methane and carbon dioxide technology and research progress of catalysts
- Vol. 50, Issue 5, Pages: 69-76(2025)
- 作者机构：
  
  1.河南工业大学环境工程学院，河南郑州 450001
  2.河南工业大学碳中和研究院，河南郑州 450001
  3.常州大学城乡矿山研究院常州市生物质绿色安全高值利用技术重点实验室江苏常州 213164
  4.哈尔滨工业大学郑州研究院，河南郑州 450000
- 作者简介：
- 基金信息：
- DOI：10.12434/j.issn.2097-2547.20240489
  CLC： TQ426
- Received：10 December 2024，
  
  Revised：16 January 2025，
  
  Published：25 May 2025
- 稿件说明：
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李学琴,王庚益,魏潇等.催化甲烷-二氧化碳干重整技术现状及催化剂研究进展[J].低碳化学与化工,2025,50(05):69-76.

LI Xueqin,WANG Gengyi,WEI Xiao,et al.Current status of dry reforming of methane and carbon dioxide technology and research progress of catalysts[J].Low-Carbon Chemistry and Chemical Engineering,2025,50(05):69-76.
李学琴,王庚益,魏潇等.催化甲烷-二氧化碳干重整技术现状及催化剂研究进展[J].低碳化学与化工,2025,50(05):69-76. DOI： 10.12434/j.issn.2097-2547.20240489.

LI Xueqin,WANG Gengyi,WEI Xiao,et al.Current status of dry reforming of methane and carbon dioxide technology and research progress of catalysts[J].Low-Carbon Chemistry and Chemical Engineering,2025,50(05):69-76. DOI： 10.12434/j.issn.2097-2547.20240489.

摘要

为应对全球气候变化和推动可持续发展，甲烷（CH

）-二氧化碳（CO

）干重整（DRM）具有环保和经济效益高的特点，成为化工产业的重要发展方向。该技术不仅能够有效减少温室气体排放，还能将CH

与CO

转化为高价值的化工原料，为费托合成等工业应用提供优质的合成气，在环境保护与资源利用方面具有重要的实际意义。统计了国内外关于DRM发文情况，探讨了DRM反应机理及其反应热力学，从添加金属助剂和控制载体间的相互作用等方面综述了DRM催化剂的类型及研究进展，分析了DRM技术存在的问题，并针对现存的问题提出了相应的改进措施。从2000年起，与DRM相关的文献数量逐年增大，近两年稍有所回落，研究内容和方向更加深入和多元化。现有DRM催化剂存在成本高、易积炭和烧结等问题，可通过添加合适的助剂、氮掺杂和活性炭改性等方式得以优化。但是DRM反应需要在较高温度下进行，能耗较大，对设备要求较高，并且反应过程中气体的流速、压力和

(CH

(CO

)对反应效率有显著影响。今后的研究中，应更加注重绿色、可持续和高性能DRM催化剂及反应器的开发和优化。

Abstract

In order to cope with global climate change and promote sustainable development

the dry reforming of methane (CH

) and carbon dioxide (CO

) (DRM) has become an important development direction of chemical industry because of its unique environmental protection and economic benefits. This technology can not only effectively reduce greenhouse gas emissions

but also transform CH

and CO

into high-value chemical raw materials

providing high-quality synthesis gas for industrial applications such as Fischer-Tropsch synthesis

which has important practical s

ignificance in environmental protection and resource utilization. The related literatures about DRM at home and abroad were counted

and the reaction mechanism and thermodynamics of DRM were discussed. The types and research progress on DRM catalysts were summarized from the aspects of adding metal additives and controlling the interaction between carriers

and the existing problems of DRM technology were analyzed and corresponding improvement measures were put forward in view of the existing problems. It is found that the number of literatures related to DRM has increased year by year since 2000

with a slight decline in recent two years

and the research content and direction are more in-depth and diversified. The existing catalysts have some problems such as high cost

easy carbon deposition and sintering

which can be optimized by adding appropriate additives

nitrogen doping

activated carbon modification and so on. However

DRM reaction needs high temperature to be carried out effectively

which increases the energy consumption and needs strict equipment requirements

and the gas flow rate

pressure and

(CH

(CO

) in the reaction process have a significant impact on the reaction efficiency. In future research

more attention should be paid to development and optimization of green

sustainable and high-performance DRM catalysts and reactors.

关键词

Keywords

references

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C1 Chemistry, Southwest Institute of Chemical Co., Ltd.

School of Chemical Engineering, Sichuan University

四川大学化工学院四川成都610065

College of Chemistry and Chemical Engineering,Key Laboratory of Oil and Gas Fine Chemicals of Ministry of Education and Xinjiang Uyghur Autonomous Region,Xinjiang University

School of Chemistry and Chemical Engineering, Guizhou University

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