Study on structure modulation of ALF materials and their CO<sub>2</sub> adsorption performances

HUANG Chen; YUAN Ying; CHEN Yujia; LI Xu; LI Kebing; LU Dehua; WU Yamin; ZHAO Anmin

doi:10.12434/j.issn.2097-2547.20240476

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Study on structure modulation of ALF materials and their CO₂ adsorption performances

更新时间：2025-11-25

- Study on structure modulation of ALF materials and their CO₂ adsorption performances
- Vol. 50, Issue 11, Pages: 121-129(2025)
- 作者机构：
  
  西南化工研究设计院有限公司多孔材料与分离转化全国重点实验室，国家碳一化学工程技术研究中心，四川成都 610225
- 作者简介：
- 基金信息：
- DOI：10.12434/j.issn.2097-2547.20240476
  CLC： TQ028
- Received：03 December 2024，
  
  Revised：2025-01-09，
  
  Published：25 November 2025
- 稿件说明：
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黄晨,袁英,陈禹嘉等.ALF材料结构调变及其CO₂吸附性能研究[J].低碳化学与化工,2025,50(11):121-129.

HUANG Chen,YUAN Ying,CHEN Yujia,et al.Study on structure modulation of ALF materials and their CO₂ adsorption performances[J].Low-Carbon Chemistry and Chemical Engineering,2025,50(11):121-129.
黄晨,袁英,陈禹嘉等.ALF材料结构调变及其CO₂吸附性能研究[J].低碳化学与化工,2025,50(11):121-129. DOI： 10.12434/j.issn.2097-2547.20240476.

HUANG Chen,YUAN Ying,CHEN Yujia,et al.Study on structure modulation of ALF materials and their CO₂ adsorption performances[J].Low-Carbon Chemistry and Chemical Engineering,2025,50(11):121-129. DOI： 10.12434/j.issn.2097-2547.20240476.

摘要

烟道气中的CO

捕集是一种有效应对气候变化并实现“碳中和”的方法，开发具有大CO

吸附量、优异选择性、能快速吸/脱附和再生简便的吸附剂，是实现低能耗捕集CO

的关键。金属有机框架材料（MOFs）虽然具有较大的饱和CO

吸附量，但存在吸附速率较慢的问题。在Al(HCOO)

MOFs（ALF）基础上，通过掺杂Mg合成改性吸附剂，并对其合成工艺进行了探究。结果表明，在以Mg(OH)

为Mg源掺杂改性吸附剂合成工艺探究中，合成温度和合成时间对吸附剂的晶型结构和晶粒尺寸都有较大影响，在合成温度100

℃、合成时间24 h条件下，AMHF-2 在3 min时的CO

吸附量比ALF增大了14.3 mL/g。AMHF-2与ALF具有相同主体结构，与ALF相比，AMHF-2有更小的晶粒尺寸且晶粒分散度更高，在短时间内对CO

具有更快的吸附速率和更大的吸附量，因此，将其应用于大规模变压吸附法烟道气脱碳成为可能。

Abstract

capture from flue gas is an effective method to improve the climate change and achieve “carbon neutral”. The development of adsorbents with large CO

adsorption capacity

excellent selectivity

rapid adsorption/desorption and simple regeneration is the key to achieving low energy consumption CO

capture. Although metal-organic framework materials (MOFs) have a high saturation CO

adsorption capacity

they suffer from slow adsorption rates. On the basis of Al(HCOO)

MOFs (ALF)

the modified adsorbents were synthesized by doping Mg

and their synthesis process were explored. The results show that the synthesis temperature and synthesis time have a great influence on the crystal structure and grain size of the adsorbents in the study of synthesis process of Mg(OH)

doped modified adsorbents. Under synthesis temperature of 100 ℃ and synthesis time of 24 h

the CO

adsorption capacity of AMHF-2 is 14.3 mL/g higher than that of ALF within 3 min. AMHF-2 and ALF have the same main structure. Compared with ALF

AMHF-2 has smaller crystallite size and higher crystallite dispersion

and has a faster adsorption rate and higher CO

adsorption capacity in a short period of time. Therefore it becomes possible to apply to large-scale pressure swing adsorption flue gas decarbonization.

关键词

Keywords

references

EVANS J D , SUMBY C J , DOONAN C J . Post-synthetic metalation of metal-organic frameworks [J ] . Chemical Society Reviews , 2014 , 43 ( 16 ): 5933 - 5951 .

SNOECKX R , BOGERTS A . Plasma technology—A novel solution for CO 2 conversion? [J ] . Chemical Society Reviews , 2017 , 46 ( 19 ): 5805 - 5863 .

BEN-MANSOUR R , QASEM N A A . An efficient temperature swing adsorption (TSA) process for separating CO 2 from CO 2 /N 2 mixture using Mg-MOF-74 [J ] . Energy Conversion and Management , 2018 , 156 : 10 - 24 .

白雪 . 改性MIP-202混合基质复合膜的合成及其CO 2 /N 2 分离性能 [D ] . 太原 : 太原理工大学 , 2023 .

BAI X . The preparation of mixed matrix composite membranes based on modified MIP-202 and its CO 2 /N 2 separation performance [D ] . Taiyuan : Taiyuan University of Technology , 2023 .

KUMAR S , MONDAL M K . Selection of efficient absorbent for CO 2 capture from gases containing low CO 2 [J ] . Korean Journal of Chemical Engineering , 2020 , 37 ( 2 ): 231 - 239 .

NANDAKISHORA Y , SAHOO R K , MURUGAN S . A comparative study of modified Linde and cryogenic cooling for CO 2 separation [J ] . International Journal of Energy Research , 2022 , 46 ( 3 ): 2840 - 2857 .

袁英 , 陈禹嘉 , 贺安平 , 等 . 变压吸附分离CH 4 /N 2 用碳分子筛的合成及其分离性能研究 [J ] . 低碳化学与化工 , 2023 , 48 ( 5 ): 155 - 162 .

YUAN Y , CHENG Y J , HE A P , et al . Study on preparation of carbon molecular sieves for pressure swing adsorption separation of CH 4 /N 2 and their separation performance [J ] . Low-Carbon Chemistry and Chemical Engineering , 2023 , 48 ( 5 ): 155 - 162 .

DUARTE G S , SCHÜRER B , VOSS C , et al . Adsorptive separation of CO 2 from flue gas by temperature swing adsorption processes [J ] . ChemBioEng Reviews , 2017 , 4 ( 5 ): 277 - 288 .

SHIRLEY A I . Comments on “concentration and recovery of CO 2 from flue gas by pressure swing adsorption” [J ] . Industrial & Engineering Chemistry Research , 1994 , 33 ( 11 ): 2879 - 2880 .

吕道飞 . 几种高稳定性MOFs的合成及其对小分子气体的吸附分离性能 [D ] . 广州 : 华南理工大学 , 2020 .

LV D F . The synthesis of several highly stable MOFs and their adsorptive separation performance for small gaseous molecules [D ] . Guangzhou : South China University of Technology , 2020 .

SHAN B H , YU J H , ARMSTRONG M R , et al . A cobalt metal-organic framework with small pore size for adsorptive separation of CO 2 over N 2 and CH 4 [J ] . AIChE Journal , 2017 , 63 ( 10 ): 4532 - 4540 .

CHEN B , WEN H , LIAO C , et al . A metal-organic framework with suitable pore size and dual functionalities for highly efficient post-combustion CO 2 capture [J ] . Journal Materials Chemistry A , 2013 , 7 ( 7 ): 3128 - 3134 .

HU Y Q , CHEN Y X , YANG W L , et al . Efficient carbon dioxide capture from flue gas and natural gas by a robust metal-organic framework with record selectivity and excellent granulation performance [J ] . Separation and Purification Technology , 2024 , 343 : 127099 .

KADI M W , SALAM H M A E , ZAKI T , et al . Adsorption of carbon dioxide on Cu x Mg y (BTC) 2 MOFs: Influence of Cu/Mg ratio [J ] . Journal of Nanoparticle Research , 2020 , 22 ( 6 ): 143 - 153 .

LAU C H , BABARAO R , HILL M R . A route to drastic increase of CO 2 uptake in Zr metal organic framework UiO-66 [J ] . Chemical Communications , 2013 , 49 ( 35 ): 3634 - 3636 .

LEI L , CHENG Y , CHEN C W , et al . Taming structure and modulating carbon dioxide (CO 2 ) adsorption isosteric heat of nickel-based metal organic framework (MOF-74(Ni)) for remarkable CO 2 capture [J ] . Journal of Colloid and Interface Science , 2022 , 612 : 132 - 145 .

EVANS H A , MULLANJI D , DENG Z Y , et al . Aluminum formate, Al(HCOO) 3 : An earth-abundant, scalable, and highly selective material for CO 2 capture [J ] . Science Advances , 2022 , 8 ( 44 ): 1 - 11 .

CUI P , LI J J , DONG J , et al . Modulating CO 2 adsorption in metal-organic frameworks via metal-ion doping [J ] . Inorganic Chemistry , 2018 , 57 ( 10 ): 6135 - 6141 .

卜显和 . 配位聚合物化学 [M ] . 北京 : 科学出版社 , 2019 : 208 - 216 .

BU X H . The chemistry of coordination polymer [M ] . Beijing : Science Press , 2019 : 208 - 216 .

ROOD J A , NOLL B C , HENDERSON K W . Synthesis, structural characterization, gas sorption and guest-exchange studies of the lightweight, porous metal-organic framework α -[Mg 3 (O 2 CH) 6 ] [J ] . Inorganic Chemistry , 2006 , 45 ( 14 ): 5521 - 5528 .

WANG Z M , ZHANG B , ZHANG Y J , et al . A family of porous magnets, [M 3 (HCOO) 6 ] (M = Mn, Fe, Co and Ni) [J ] . Polyhedron , 2007 , 26 ( 9/11 ): 2207 - 2215 .

高胜利 . 化学元素周期表 [M ] . 第2版 . 北京 : 科学出版社 , 2007 : 1 - 108 .

GAO S L . Periodic table of chemical elements [M ] . 2nd ed . Beijing : Science Press , 2007 : 1 - 108 .

LIAO J W , JIN B , ZHAO Y L , et al . Highly efficient and durable metal-organic framework material derived Ca-based solid sorbents for CO 2 capture [J ] . Chemical Engineering Journal , 2019 , 372 : 1028 - 1037 .

TIAN Y Q , ZHAO Y M , XU H J , et al . CO 2 template synthesis of metal formates with a ReO 3 net [J ] . Inorganic Chemistry , 2007 , 46 ( 5 ): 1612 - 1626 .

LIU Q , YANG J M , JIN L N , et al . Metal ion induced porous HKUST-1 nano/microcrystals with controllable morphology and size [J ] . CrystEngComm , 2016 , 18 ( 22 ): 4127 - 413 .

ŁUCZAK J , KROCZEWSKA M , BALUK M , et al . Morphology control through the synthesis of metal-organic frameworks [J ] . Advances in Colloid and Interface Science , 2023 , 314 : 102864 .

TAYLOR K M L , JIN A , LIN W B . Surfactant-assisted synthesis of nanoscale gadolinium metal-organic frameworks for potential multimodal imaging [J ] . Angewandte Chemie International Edition , 2008 , 47 ( 40 ): 7722 - 7725 .

BIEMMI E , CHRISTAIN S , STOCK N , et al . High-throughput screening of synthesis parameters in the formation of the metal-organic frameworks MOF-5 and HKUST-1 [J ] . Microporous and Mesoporous Materials , 2009 , 117 ( 1/2 ): 111 - 117 .

崔雪 . 金属有机骨架材料合成条件影响探究及二氧化碳吸附性能研究 [D ] . 北京 : 中国石油大学 , 2023 .

CUI X . Scale-up synthesis and carbon dioxide adsorption of metal-organic skeleton materials [D ] . Beijing : China University of Petroleum , 2023 .

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Study on structure modulation of ALF materials and their CO2 adsorption performances

DOI：10.12434/j.issn.2097-2547.20240476

摘要

Abstract

关键词

Keywords

references

Study on structure modulation of ALF materials and their CO₂ adsorption performances