Study on characteristics and product distributions of waste tire and biomass co-pyrolysis

ZHAO Guangjie; JIN Jianlong; JIN Liang; MAO Yuwei; HUANG Qunxing

doi:10.12434/j.issn.2097-2547.20240389

您当前的位置：

首页 >

文章列表页 >

Study on characteristics and product distributions of waste tire and biomass co-pyrolysis

更新时间：2025-06-23

- Study on characteristics and product distributions of waste tire and biomass co-pyrolysis
- Vol. 50, Issue 6, Pages: 74-80(2025)
- 作者机构：
  
  1.中国联合工程有限公司，浙江杭州 310056
  2.浙江大学热能工程研究所能源高效清洁利用全国重点实验室，浙江杭州 310013
- 作者简介：
- 基金信息：
- DOI：10.12434/j.issn.2097-2547.20240389
  CLC： TQ116;X798;X712
- Received：14 September 2024，
  
  Revised：06 November 2024，
  
  Published：25 June 2025
- 稿件说明：
移动端阅览
赵光杰,金建龙,金亮等.废轮胎与生物质共热解特性及产物分布研究[J].低碳化学与化工,2025,50(06):74-80.

ZHAO Guangjie,JIN Jianlong,JIN Liang,et al.Study on characteristics and product distributions of waste tire and biomass co-pyrolysis[J].Low-Carbon Chemistry and Chemical Engineering,2025,50(06):74-80.
赵光杰,金建龙,金亮等.废轮胎与生物质共热解特性及产物分布研究[J].低碳化学与化工,2025,50(06):74-80. DOI： 10.12434/j.issn.2097-2547.20240389.

ZHAO Guangjie,JIN Jianlong,JIN Liang,et al.Study on characteristics and product distributions of waste tire and biomass co-pyrolysis[J].Low-Carbon Chemistry and Chemical Engineering,2025,50(06):74-80. DOI： 10.12434/j.issn.2097-2547.20240389.

摘要

为了探究不同废轮胎和生物质的共热解转化特性和协同反应机理，实现热解油组分的定向高值化利用，进行了热重分析和固定床热解试验，研究了不同废轮胎和稻壳、秸秆等不同生物质的等质量混合共热解特性，并对热解产物的组成和转化路径进行了比较分析。热重分析结果显示，共热解可有效降低热解反应所需温度，从而减少热解能耗，且小车车胎共热解时的协同作用比大车车胎更加显著。固定床实验结果显示，共热解有助于油中芳香烃向脂肪烃转化、部分含氧类物质向烃类物质转化，但也会促进CO

产生，降低热解气的热值。且共热解炭中的C质量分数明显减小，S也存在从气固相向液相转化的趋势。热解过程中还发现小车轮胎和稻壳灰成分中的大量中性金属氧化物可以促进苯环的羟基化，而大车轮胎和秸秆灰成分中的大量碱性金属氧化物可以促进气化反应。

Abstract

In order to explore the co-pyrolysis transformation characteristics and collaborative reaction mechanism of different waste tires and biomass

and realize the directional high-value utilization of pyrolysis oil components

the pyrolysis behaviors were investigated by thermogravimetric analysis and fixed-bed pyrolysis tests. The composition and transformation path of pyrolysis production were compared and analyzed in different kinds of waste tires and rice husks or straw mixture. Thermogravimetry experiment result shows that co-pyrolysis can effectively decrease the temperature required for the pyrolysis reaction

which can reduce the pyrolysis energy consumption. The synergistic effect is more significant when small tires participate in co-pyrolysis than that of Truck and Bus Radial. The results of fixed bed experiment shows that co-pyrolysis can effectively improve the conversion of aromatic hydrocarbons to aliphatic hydrocarbons and the conversion of oxygen-containing substances to hydrocarbon substances. However

co-pyrolysis will lead to the production of carbon dioxide

which will decrease the calorific value of pyrolysis gas. In addition

the mass fraction of C in co-pyrolysis carbon is significantly decreased

and the S also has a tendency to transform from gas-solid phase to liquid phase. It is also found that large amounts of neutral metal oxides in Passenger Car Radia and rice husk ash can promote the hydroxylation of benzene rings

while large amounts of alkaline metal oxides in Truck and Bus Radial and straw ash can promote the gasification reaction.

关键词

Keywords

references

中国物资再生协会 . 2024中国再生资源回收行业发展报告 [J ] . 资源再生 , 2024 , ( 7 ): 27 - 38 .

China National Resources Recycling Association . 2024 China renewable resource recycling industry development report [J ] . Resource Regeneration (China) , 2024 , ( 7 ): 27 - 38 .

BI R S , ZHANG Y , JIANG X , et al . Simulation and techno-economical analysis on the pyrolysis process of waste tire [J ] . Energy , 2022 , 260 : 125039 .

MENTES D , TOTH C E , NAGY G , et al . Investigation of gaseous and solid pollutants emitted from waste tire combustion at different temperatures [J ] . Waste Management , 2022 , 149 : 302 - 312 .

WADRZYK M , JANUS R , RZADZIK B , et al . Pyrolysis Oil from scrap tires as a source of fuel components: Manufacturin, fractionation, and characterization [J ] . Energy and Fuels , 2020 , 34 ( 5 ): 5917 - 5928 .

MARTINZ J D , VESES A , MASTRAL A M , et al . Co-pyrolysis of biomass with waste tyres: Upgrading of liquid bio-fuel [J ] . Fuel Processing Technology , 2014 , 119 : 263 - 271 .

畅志兵 , 王楚楚 , 王依宁 , 等 . 桦甸油页岩和废轮胎的共热解反应行为及协同效应 [J ] . 矿业科学学报 , 2023 , 8 ( 2 ): 213 - 221 .

CHANG Z B , WANG C C , WANG Y N , et al . Reaction behaviors and synergistic effects for co-pyrolysis of Huadian oil shale and waste tire [J ] . Journal of Mining Science and Technology , 2023 , 8 ( 2 ): 213 - 221 .

WANG J , HU W , CHEN M , et al . Co-pyrolysis of biomass and waste rubber tire powder for obtaining pyrolytic oil [J ] . International Conference on Environmental Technology and Knowledge Transfer , 2010 : 132 - 134 .

ALVAREZ J , AMUTIO M , LOPEZ G , et al . Improving bio-oil properties through the fast co-pyrolysis of lignocellulosic biomass and waste tyres [J ] . Waste Management , 2019 , 85 : 385 - 395 .

WANG Z W , WU M G , CHEN G F , et al . Co-pyrolysis characteristics of waste tire and maize stalk using TGA, FTIR and Py-GC/MS analysis [J ] . Fuel , 2023 , 337 : 127206 .

马光路 , 刘岗 , 曹青 , 等 . 不同物种生物质与废轮胎共热解对热解油的影响 [J ] . 现代化工 , 2007 , ( S2 ): 249 - 252 .

MA G L , LIU G , CAO Q , et al . Influence of co-pyrolysis of different species biomass with waste tires on oil properties [J ] . Modern Chemical Industry , 2007 , ( S2 ): 249 - 252 .

MASFURI I , AMRULLAH A , FAROBIE O , et al . Temperature effects on chemical reactions and product yields in the Co-pyrolysis of wood sawdust and waste tires: An experimental investigation [J ] . Results in Engineering , 2024 , 23 : 102638 .

吴昭回 , 林诚乾 , 徐俊等 . 废轮胎颗粒热解膨胀特性研究 [J ] . 环境工程 , 2023 , 41 ( S2 ): 504 - 510 .

WU Z H , LIN C Q , XU J , et al . Expansion charactristics of single waste tire grain during pyrolysis [J ] . Environmental Engineering , 2023 , 41 ( S2 ): 504 - 510 .

孙云娟 , 蒋剑春 , 王燕杰 , 等 . Coats-Redfern积分法研究生物质与煤单独热解和共热解动力学特性 [J ] . 林产化学与工业 , 2014 , 34 ( 5 ): 8 - 14 .

SUN Y J , JIANG J C , WANG Y J , et al . Kinetic analysis of biomass and coal mono-pyrolysis as well as co-pyrolysis by coats-redfern [J ] . Chemistry and Industry of Forest Products , 2014 , 34 ( 5 ): 8 - 14 .

DAI C Y , HU E F , YANG Y , et al . Fast co-pyrolysis behaviors and synergistic effects of corn stover and polyethylene via rapid infrared heating [J ] . Waste Management , 2023 , 169 : 147 - 156 .

夏勇 , 阳宇 , 朱聪 , 等 . 废轮胎热解过程中的动力学与热力学特性及热解油组分分析 [J ] . 低碳化学与化工 , 2023 , 48 ( 4 ): 36 - 45 .

XIA Y , YANG Y , ZHU C , et al . Kinetic and thermodynamic characteristics in scrap tyres pyrolysis process and components analysis of pyrolysis oil [J ] . Low-Carbon Chemistry and Chemical Engineering , 2023 , 48 ( 4 ): 36 - 45 .

KHAN S R , ZEESHAN M , MASOOD A . Enhancement of hydrocarbons production through co-pyrolysis of acid-treated biomass and waste tire in a fixed bed reactor [J ] . Waste Management , 2020 , 106 : 21 - 31 .

JIANG X Y , LIU Q , HU B , et al . Effects of alkali metals on pyrolysis mechanism of lignin dimer [J ] . Journal of Engineering Thermophysics , 2017 , 38 ( 5 ): 1117 - 1121 .

Views

下载量

CNKI被引量

Alert me when the article has been cited

提交

Tools

Publicity Resources

Research progress of low rank coal microwave pyrolysis technology

Research progress on preparation of nitrogen-doped carbon materials from biomass and its application as catalyst carrier in hydrogenation field

Research progress on biomass torrefaction pre-conditioning and optimization of pyrolysis product quality

Research progress on biomass-based methyl levulinate synthesis via thermal catalysis by different types of catalysts

Related Author

ZHAO Guangjie

HUANG Qunxing

ZHANG Tao

LI Lijuan

GAO Dongfang

XUE Jinxue

ZHAO Wenqiang

ZOU Sheng

Related Institution

School of Mechatronics Engineering, Henan University of Science and Technology

School of Geology and Mining Engineering, Henan Geology Mineral College

Xinjiang Blue Ridge Tunhe Sci. & Tech. Co., Ltd.

School of Chemistry and Chemical Engineering, Shihezi University

University of Chinese Academy of Sciences

Postal code：610225
Tel：028-85964717 Email：dthxyhg@swchem.com
Technical support is provided by Beijing Founder electronics co., LTD 蜀ICP备12008600号-10 蜀公网安备51012202001533
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.
Total Visits：232592 Visits Today：425

⁰