Research progress on modification of CdS photocatalyst for photocatalytic splitting of water to hydrogen

LIU Jiaru; LIU Zhe; YANG Chunwei

doi:10.12434/j.issn.2097-2547.20240347

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Research progress on modification of CdS photocatalyst for photocatalytic splitting of water to hydrogen

更新时间：2025-07-30

- Research progress on modification of CdS photocatalyst for photocatalytic splitting of water to hydrogen
- Vol. 50, Issue 7, Pages: 118-124(2025)
- 作者机构：
  
  1.吉林师范大学工程学院，吉林四平 136000
  2.吉林师范大学吉林省高校环境材料与污染控制重点实验室，吉林四平 136000
- 作者简介：
- 基金信息：
- DOI：10.12434/j.issn.2097-2547.20240347
  CLC： TQ136
- Received：21 August 2024，
  
  Revised：10 September 2024，
  
  Published：25 July 2025
- 稿件说明：
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刘家如,刘喆,杨春维.光催化分解水产氢用CdS光催化剂改性研究进展[J].低碳化学与化工,2025,50(07):118-124.

LIU Jiaru,LIU Zhe,YANG Chunwei.Research progress on modification of CdS photocatalyst for photocatalytic splitting of water to hydrogen[J].Low-Carbon Chemistry and Chemical Engineering,2025,50(07):118-124.
刘家如,刘喆,杨春维.光催化分解水产氢用CdS光催化剂改性研究进展[J].低碳化学与化工,2025,50(07):118-124. DOI： 10.12434/j.issn.2097-2547.20240347.

LIU Jiaru,LIU Zhe,YANG Chunwei.Research progress on modification of CdS photocatalyst for photocatalytic splitting of water to hydrogen[J].Low-Carbon Chemistry and Chemical Engineering,2025,50(07):118-124. DOI： 10.12434/j.issn.2097-2547.20240347.

摘要

氢能作为清洁二次能源，可为解决我国能源问题提供参考。光解水产氢技术因其可以直接利用太阳光把水分解成H

和O

而备受关注，寻找合适的光催化剂是光解水产氢技术的关键。CdS具有良好的光催化活性，但仍存在能带结构有待进一步优化、光腐蚀及光生载流子复合率高等问题。对CdS光催化剂用于光解水产氢的机理进行了总结，针对CdS光催化剂现存的问题给出了具有参考性的解决方案。采用元素掺杂法可使催化剂获得合理的能带结构，通过设计保护层和去除O

可提高催化剂光腐蚀抗性，通过构建内建电场、设计活性位点和形貌调控技术可提高光生载流子迁移效率。

Abstract

As a clean secondary energy source

hydrogen energy can provide a reference for solving China’s energy problems. Photolysis of water to hydrogen has attracted much attention because it can directly use sunlight to split water to H

and O

. Finding suitable photocatalyst is the key to photolysis of water to produce hydrogen. CdS has good photocatalytic activity

however

there are still some problems

such as the need for further optimization of the band structure

photocorrosion and high photogenerated carrier recombination rate. The mechanism of CdS photocatalyst for hydrogen production by photolysis of water was summarized

and a reference

solution to the existing problems of CdS photocatalyst was gived. The reasonable band structure of the catalyst can be obtained by element doping

and the photocorrosion resistance can be improved by designing the protective layer and removing O

and the photogenerated carrier migration efficiency can be increased by constructing the built-in electric field

designing the active site and morphology control technology.

关键词

Keywords

references

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