Research progress of Pd-based heterogeneous catalytic system for liquid phase dehydrogenation of formic acid

WANG Yu; LI Hengjie; ZHANG Yantu; LI Xueli

doi:10.12434/j.issn.2097-2547.20240332

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Research progress of Pd-based heterogeneous catalytic system for liquid phase dehydrogenation of formic acid

更新时间：2025-04-27

- Research progress of Pd-based heterogeneous catalytic system for liquid phase dehydrogenation of formic acid
- Vol. 50, Issue 4, Pages: 140-148(2025)
- 作者机构：
  
  1.延安大学化学与化工学院，陕西延安 716000
  2.延安大学先进能源材料与绿色催化技术陕西省高校工程研究中心，陕西延安 716000
- 作者简介：
- 基金信息：
- DOI：10.12434/j.issn.2097-2547.20240332
  CLC： TQ426;O643.3
- Received：10 August 2024，
  
  Revised：2024-09-18，
  
  Published：25 April 2025
- 稿件说明：
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王雨,李恒杰,张琰图等.甲酸液相脱氢用Pd基多相催化体系的研究进展[J].低碳化学与化工,2025,50(04):140-148.

WANG Yu,LI Hengjie,ZHANG Yantu,et al.Research progress of Pd-based heterogeneous catalytic system for liquid phase dehydrogenation of formic acid[J].Low-Carbon Chemistry and Chemical Engineering,2025,50(04):140-148.
王雨,李恒杰,张琰图等.甲酸液相脱氢用Pd基多相催化体系的研究进展[J].低碳化学与化工,2025,50(04):140-148. DOI： 10.12434/j.issn.2097-2547.20240332.

WANG Yu,LI Hengjie,ZHANG Yantu,et al.Research progress of Pd-based heterogeneous catalytic system for liquid phase dehydrogenation of formic acid[J].Low-Carbon Chemistry and Chemical Engineering,2025,50(04):140-148. DOI： 10.12434/j.issn.2097-2547.20240332.

摘要

甲酸无色低毒、便于储运，可由CO

加氢或生物质转化制得，是理想氢载体之一。Pd作为活性金属在甲酸脱氢反应中具有较高催化活性，但Pd基多相催化剂依然面临着催化活性和选择性不高、稳定性差以及价格昂贵等问题，无法满足工业化需求。针对这些问题，综述了近年来Pd基催化体系用于甲酸液相脱氢反应的研究进展，讨论了甲酸液相脱氢的反应机理以及甲酸液相脱氢反应的关键因素（Pd纳米颗粒（Pd NPs）尺寸/微结构、载体结构/表面性质以及反应添加剂）对催化剂的催化活性和稳定性的影响。分析发现，通过合金化、核壳结构、多孔材料孔道限域、载体表面氨基化/氮掺杂改性及金属氧化物缺陷效应等都可以获得较小颗粒尺寸的Pd NPs，进而提高Pd NPs的分散性和稳定性以及减少Pd用量，同时调节优化Pd NPs的微结构，从而提高甲酸脱氢催化剂的催化活性和稳定性，以期为开发新型甲酸高效脱氢Pd基多相催化

体系提供借鉴。

Abstract

Formic acid is colorless

low toxicity

easy to store and transport

and can be produced by CO

hydrogenation and biomass conversion

which is an ideal hydrogen carrier. As an active metal

Pd has high catalytic activity in formic acid dehydrogenation

but the Pd-based heterogeneous catalysts are still facing the problems of low catalytic activity and selectivity

poor stability and expensive

which cannot meet the needs of industrialization. In order to solve these problems

the research progress of Pd-based heterogeneous catalysts for the liquid-phase dehydrogenation of formic acid in recent years was reviewed

and the reaction mechanism of liquid phase dehydrogenation of formic acid was discussed

as well as the effects of key factors of liquid phase dehydrogenation of formic acid (Pd nanoparticles (Pd NPs) size/microstructure

carrier structure/surface properties and reaction additives) on the catalytic activity and stability were discussed. It is found that the alloying

core-shell structure

pore confinement effect of porous materials

amino functionalization/nitrogen doping modification of carrier surface and metal oxide defect effect

etc. could obtain Pd NPs with smaller sizes

then improve the dispersion and stability of Pd NPs and reduce the amount of Pd

and at the same time adjust and optimize the microstructure of Pd NPs

resulting in the improvement of the activity and stability of the catalysts for the dehydrogenation of formic acid

which can provide useful reference for the development of novel Pd-based heterogeneous catalytic systems for the efficient dehydrogenation of formic acid.

关键词

Keywords

references

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Related Author

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Related Institution

College of Chemistry and Chemical Engineering, Yan'an University

Engineering Research Center of Advanced Energy Materials and Green Catalytic Technology, Universities of Shaanxi Province, Yan'an University

青岛科技大学化工学院

山东淄博化工职业学院

青岛科技大学环境与安全工程学院

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