Study on preparation and properties of Ru-FeOOH@NiFe LDH nanosheets for electrocatalytic hydrogen evolution

YANG Miao; LI Pan; YANG Hong; SHAO Shengjuan; WANG Feng; NIU Yulan

doi:10.12434/j.issn.2097-2547.20240311

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Study on preparation and properties of Ru-FeOOH@NiFe LDH nanosheets for electrocatalytic hydrogen evolution

- Study on preparation and properties of Ru-FeOOH@NiFe LDH nanosheets for electrocatalytic hydrogen evolution
- Vol. 49, Issue 12, Pages: 121-126(2024)
- 作者机构：
  
  1.太原工业学院化学与化工系，山西太原 030008
  2.太原工业学院环境与安全工程系，山西太原 030008
- 作者简介：
- 基金信息：
- DOI：10.12434/j.issn.2097-2547.20240311
  CLC： TQ151;O65
- Published：25 December 2024，
  
  Received：24 July 2024，
  
  Revised：04 September 2024，
- 稿件说明：
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杨苗,李攀,杨红等.Ru-FeOOH@NiFe LDH纳米片制备及其电解水析氢性能研究[J].低碳化学与化工,2024,49(12):121-126.

YANG Miao,LI Pan,YANG Hong,et al.Study on preparation and properties of Ru-FeOOH@NiFe LDH nanosheets for electrocatalytic hydrogen evolution[J].Low-carbon Chemistry and Chemical Engineering,2024,49(12):121-126.
杨苗,李攀,杨红等.Ru-FeOOH@NiFe LDH纳米片制备及其电解水析氢性能研究[J].低碳化学与化工,2024,49(12):121-126. DOI： 10.12434/j.issn.2097-2547.20240311.

YANG Miao,LI Pan,YANG Hong,et al.Study on preparation and properties of Ru-FeOOH@NiFe LDH nanosheets for electrocatalytic hydrogen evolution[J].Low-carbon Chemistry and Chemical Engineering,2024,49(12):121-126. DOI： 10.12434/j.issn.2097-2547.20240311.

摘要

电解水制氢技术的开发对于促进低碳发展具有重要意义，设计高效稳定的催化剂至关重要。通过一步水热法在泡沫镍基底上合成了Ru-FeOOH@NiFe LDH催化剂，用于电催化水分解制氢。通过SEM、TEM、XRD和XPS对催化剂进行了表征分析。结果表明，钌的引入可以调节催化剂的电子结构，增强金属-载体相互作用，使得Ru-FeOOH@NiFe L

DH表现出良好的电催化性能。当电流密度为10 mA/cm

时，Ru-FeOOH@NiFe LDH所需过电位为95 mV，Tafel斜率为80.6 mV/dec，其电催化性能明显优于FeOOH@NiFe LDH。在相同反应条件下，Ru-FeOOH@NiFe LDH可稳定运行15 h。

Abstract

The development of hydrogen production technology by electrolytic water is important to promote the low-carbon development

among which the design of efficient and stable catalysts is essential. Ru-FeOOH@NiFe LDH catalyst was synthesized on nickel foam substrate by one-step hydrothermal method and characterized by SEM

TEM

XRD and XPS. The results show that the introduction of Ru can adjust the electronic structure of the catalyst

improve the interaction between metal and supports

and the catalyst shows better electrocatalytic performance. The required overpotential of Ru-FeOOH@NiFe LDH is 95 mV at the current density of 10 mA/cm

with a low Tafel slope of 80.6 mV/dec

which indicates that the electrocatalytic performance of Ru-FeOOH@NiFe LDH is better than that of FeOOH@NiFe LDH. Ru-FeOOH@NiFe LDH can catalyze the reaction stably for 15 h under the same reaction conditions.

关键词

电解水析氢反应电催化剂NiFe层状双金属氢氧化物

Keywords

water electrolysishydrogen evolution reactionelectrocatalystNiFe layered double hydroxide

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