Research progress on biomass-based methyl levulinate synthesis via thermal catalysis by different types of catalysts

ZHOU Haiyang; TAO Jiao; LI Wei; LV Xuebin; ZHANG Rui; XIONG Jian

doi:10.12434/j.issn.2097-2547.20240173

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Research progress on biomass-based methyl levulinate synthesis via thermal catalysis by different types of catalysts

- Research progress on biomass-based methyl levulinate synthesis via thermal catalysis by different types of catalysts
- Vol. 50, Issue 1, Pages: 35-46(2025)
- 作者机构：
  
  1.西藏大学生态环境学院，西藏拉萨 850000
  2.天津城建大学环境与市政工程学院，天津 300384
- 作者简介：
- 基金信息：
- DOI：10.12434/j.issn.2097-2547.20240173
  CLC： TQ35
- Published：25 January 2025，
  
  Received：23 April 2024，
  
  Revised：09 May 2024，
- 稿件说明：
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ZHOU HAIYANG, TAO JIAO, LI WEI, et al. Research progress on biomass-based methyl levulinate synthesis via thermal catalysis by different types of catalysts. [J]. Low-carbon chemistry and chemical engineering, 2025, 50(1): 35-46.
DOI：

ZHOU HAIYANG, TAO JIAO, LI WEI, et al. Research progress on biomass-based methyl levulinate synthesis via thermal catalysis by different types of catalysts. [J]. Low-carbon chemistry and chemical engineering, 2025, 50(1): 35-46. DOI： 10.12434/j.issn.2097-2547.20240173.

摘要

乙酰丙酸甲酯是一种重要的化工产品，在替代燃料、医疗药物和溶剂等领域具有广阔的应用前景。详细分析了乙酰丙酸甲酯的4种制备方法，其中生物质直接催化醇解法更具发展潜力。基于生物质直接催化醇解法及其催化剂类型，综述了近年来国内外制备生物质基乙酰丙酸甲酯的研究现状和趋势，总结了优化反应条件及性能，分析了各催化剂应用特点。最后，指出了制备生物质基乙酰丙酸甲酯的现存问题，并对其未来研究进行了展望：注重研究生物质醇解机理、应用非粮型生物质和开发易工业化的绿色催化剂。

Abstract

Methyl levulinate is an important chemical product with broad application prospects in alternative fuels

pharmaceuticals and solvents. Four preparation methods of methyl levulinate were analyzed in detail

among which the direct catalytic alcoholysis of biomass has more development potential. Based on the biomass direct catalytic alcoholysis method and the types of catalysts

the research status and trend of the preparation of biomass-based methyl levulinate at home and abroad in recent years were summarized. The optimized reaction conditions and performances were summarized

and the application characteristics of each catalyst were analyzed. Finally

the existing problems in the preparation of biomass-based methyl levulinate were pointed out

and the future research was prospected: Focusing on the study of biomass alcoholysis mechanism

applying non-grain biomass

and developing green catalysts which are easy to industrialize.

关键词

乙酰丙酸甲酯生物质催化醇解酸性催化剂

Keywords

methyl levulinatebiomasscatalytic alcoholysisacidic catalysts

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