Research progress on alkali promoters modified iron-based catalysts for Fischer-Tropsch synthesis reaction

ZHANG Tong; HE Fugui; KONG Xiangbin; SUN Xiunan; HE Yurong; GAO Xinhua; ZHANG Jianli; ZHAO Tiansheng

doi:10.12434/j.issn.2097-2547.20240090

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Research progress on alkali promoters modified iron-based catalysts for Fischer-Tropsch synthesis reaction

- Research progress on alkali promoters modified iron-based catalysts for Fischer-Tropsch synthesis reaction
- Vol. 49, Issue 12, Pages: 1-11(2024)
- 作者机构：
  
  1.宁夏大学化学化工学院省部共建煤炭高效利用与绿色化工国家重点实验室，宁夏银川 750021
  2.国家能源集团宁夏煤业有限责任公司煤炭化学工业技术研究院，宁夏银川 750411
- 作者简介：
- 基金信息：
- DOI：10.12434/j.issn.2097-2547.20240090
  CLC： TQ426;TQ53
- Published：25 December 2024，
  
  Received：07 March 2024，
  
  Revised：29 April 2024，
- 稿件说明：
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张曈,何富贵,孔祥斌等.碱助剂改性铁基费托合成反应催化剂的研究进展[J].低碳化学与化工,2024,49(12):1-11.

ZHANG Tong,HE Fugui,KONG Xiangbin,et al.Research progress on alkali promoters modified iron-based catalysts for Fischer-Tropsch synthesis reaction[J].Low-carbon Chemistry and Chemical Engineering,2024,49(12):1-11.
张曈,何富贵,孔祥斌等.碱助剂改性铁基费托合成反应催化剂的研究进展[J].低碳化学与化工,2024,49(12):1-11. DOI： 10.12434/j.issn.2097-2547.20240090.

ZHANG Tong,HE Fugui,KONG Xiangbin,et al.Research progress on alkali promoters modified iron-based catalysts for Fischer-Tropsch synthesis reaction[J].Low-carbon Chemistry and Chemical Engineering,2024,49(12):1-11. DOI： 10.12434/j.issn.2097-2547.20240090.

摘要

由于费托合成反应复杂的反应机理和表征方法的限制，宏观实验结果与微观尺度变化的联系存在较大困难，需要理论计算为实验研究提供理论支撑。考虑到铁基催化剂在费托合成反应中的广泛应用，以及碱金属助剂（简称“碱助剂”）在铁基费托合成反应催化剂中的重要作用，对碱助剂改性铁基费托合成反应催化剂的研究进展进行了综述。首先总结了铁基费托合成反应催化剂的活性相，以及碳化过程中碱助剂在该催化剂表相和体相的迁移。然后分析了碱助剂对铁基费托合成反应催化剂结构的影响，介绍了碱助剂促进铁基催化剂的理论计算成果（催化剂结构设计、反应路径分布、反应物分子吸附和产物分布等），进而总结了碱助剂的作用机理。最后对未来相关领域的发展进行了展望。

Abstract

Due to the complex reaction mechanisms of Fischer-Tropsch synthesis reaction and the limitation of characterization methods

it is difficult to connect the macroscopic experimental results with the microscale changes

so theoretical calculations are needed to provide theoretical support for experimental research. In view of the extensive application of iron-based catalysts in Fischer-Tropsch synthesis reaction and the important role of alkali metal promoters (“alkali promoters” for short) in iron-based catalysts for Fischer-Tropsch synthesis reaction

the research progress on alkali promoters modified iron-based catalysts for Fischer-Tropsch synthesis reaction was reviewed. At first

the active phases of iron-based catalysts for Fischer-Tropsch synthesis reaction and the migration of alkali promoters in the surface phase and bulk phase of the catalysts during carbonization were summarized. Then the effects of alkali promoters on the structures of iron-based catalysts for Fischer-Tropsch synthesis reaction was analyzed

and the theoretical calculation results of promoting effects of alkali promoters on iron-based catalysts for Fischer-Tropsch synthesis reaction (catalyst structure design

reaction path distribution

reactant molecular adsorption and product distribution

etc.) were introduced. Finally

the future development of related fields was prospected.

关键词

费托合成铁基催化剂碱助剂理论计算

Keywords

Fischer-Tropsch synthesisiron-based catalystsalkali promoterstheoretical calculation

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